Sharif Digital Repository

This study has concentrated on preparation of mixed matrix membranes (MMMs) in order to improve the separation performance of the neat poly(amide-12-b-ethylene oxide)(Pebax1074) membrane. Pebax1074 and zeolite SAPO-34 were used to fabricate MMM for the first time. Micro-size SAPO-34 was added to polymer matrix up to 35wt% based on polymer weight; even though at this high loading percentage the prepared membranes were not stable enough to be tested for characterization and gas permeation. The obtained results showed more than 30% increment in CO2 permeability, along with slight growth and reduction in N2 and CH4 permeabilities, respectively for 30wt% zeolite content membranes. Permeability... 

With the advancement of GPUs and the availability of massive datasets, the main reasons behind the emergence of large language models, human life has been profoundly impacted. Large language models, due to their numerous applications and their increasing development, have influenced various aspects of human life, and this influence continues to grow. As a result, large language models are being used to solve a wide range of problems. However, using these models for problem-solving requires appropriate training data and significant computational resources. Because deep models can be attacked, leading to the extraction of their training data, preserving the privacy of training data in the... 

The growing use of the Internet has led to the creation of new businesses around it. Traditional businesses have to use the Internet in order to maintain their competitive conditions. One of the most important strategies for developing sales on the Internet is the proper use of recommendation systems.With the advent of businesses in cyberspace, the way has been paved for the use of recommendation systems in this space.Recommendation systems should exploit their knowledge about users’ preferences and explore their new preferences simultaneously. Establish a balance between exploring users’ new interests and exploiting known interests is key to build a good recommendation system. Existing data... 

In this study, membrane distillation process was used for treatment of high salinity waters. The focus of this study is to simulate and build a setup of membrane distillation process. Since the membrane distillation process is based on the driving force of the temperature difference, the required temperature is provided by both the use of heaters and the use of solar energy. To increase the feed temperature by solar energy, a black polymer coating on the main membrane is used. The main membrane used in this process is PVDF polymer and the polymer coated on the surface is the PAN polymer. After simulating and constructing the laboratory setup, the influence of a variety of parameters on the... 

FGM sheets with component or grain size gradient in their thickness direction provide mechanical and physical gradient properties through ND direction. FGMs are fabricated by various methods including centrifugal casting, powder metallurgy, PVD and CVD,all of which suffer from some shortcomings such as porosity of the products, low rate and high cost of production and restrictions on mass production. In this study, 2 and 4 layered Al matrix FGM sheets containing SiC and Al2O3 powders were fabricated by laminating method of Accumulative Roll Bonding(ARB). Two approaches of stacking were chosen as accumulative coupled roll bonding (ACRB) and (ASRB) for initial roll bonding and subsequent... 

One of the main objectives in operating a power system is to maintain the system voltage properly to avoid equipment damage and transfer power efficiently. Automatic control of transmission network voltage provides significant improvements in security, quality and efficiency of power system operation. This thesis investigates coordinated voltage control of power systems in normal, alert and emergency states. The aim is to propose a comprehensive framework for real-time operation of practical power systems, ensuring secure operation of the system in the normal state and after occurrence of sever contingencies.
At the first, a new coordinated voltage control scheme is proposed to ensure... 

Production scheduling is such a key issue that directly influences on the performance of the machines and efficiency of production line. This category of problems is to find simultaneously the lot sizes and their sequence over a finite set of planning periods.
In this Thesis a multi objective production planning and job shop scheduling problem is investigated. The objectives are minimization of the production cost and minimization of production time smoothness in consecutive periods. As the problem is shown to be NP-hard, two multi-objectives genetic algorithms with two approaches in selection of parents and crowding distance index are proposed to solve this problem. In these two meta... 

In this study, the emission and detection of secondary particles such as gamma and neutron along the beam path was investigated to evaluate proton range during treatment. Simulations and detections were performed by Geant4 toolkit that was developed base on Monte Carlo method. First, a mono-energetic proton beams irradiated a homogeneous water phantom. Then the factors influencing the accuracy of beam range estimation have been investigated and finally proton beam range was evaluated by simulation the human eye phantom. According to the results, the accuracy of range verification by prompt gamma is very high, about 1 mm. In phantoms with more oxygen in their composition, the percentage of... 

In this dissertation, an attempt has been made to prepare a library from most of the inorganic and organic compounds in order to strengthen the use of nanosystems for the purpose of controlled delivery and release of drugs and genetic material. In this regard, a complete set of compounds based on metal nanoparticles, layered double hydroxides, metal-organic frameworks, graphene oxide and carbon nanotubes were designed, synthesized and characterized, and nanocomposites and hybrids of them based on palladium, zinc, copper and nickel were designed as well. The nano-stable system is designed with positive surface potential, very low cytotoxicity, biodegradability and acceptable environment as...