Sharif Digital Repository

Graphene oxide nanowalls with extremely sharp edges and preferred vertical orientation were deposited on a graphite electrode by using electrophoretic deposition in an Mg 2+-GO electrolyte. Using differential pulse voltammetry (DPV), reduced graphene nanowalls (RGNWs) were applied for the first time, in developing an ultra-high-resolution electrochemical biosensor for detection of the four bases of DNA (G, A, T, and C) by monitoring the oxidation signals of the individual nucleotide bases. The extremely enhanced electrochemical reactivity of the four free bases of DNA, single-stranded DNA, and double-stranded DNA (dsDNA) at the surface of the RGNW electrode was compared to electrochemical... 

Mg2+-charged spongy graphene electrodes (SGEs) were fabricated by using electrophoretic deposition of chemically exfoliated graphene oxide sheets on graphite rods. The SGEs were able to present two distinguishable signals (originated from electrochemical oxidation of guanine) in differential pulse voltammetry (DPV) of leukemia and normal blood cells, in contrast to glassy carbon electrodes giving only one overlapped peak. Hence, the SGEs were applied in fast (60 min) and ultra sensitive detection of leukemia (single abnormal cells in ∼109 normal cells) in a blood serum. The sensitivity obtained by the SGEs was three orders of magnitude better than that of the best available and current... 

Graphene oxide nanoplatelets (GONPs) with extremely sharp edges (lateral dimensions ∼20-200 nm and thicknesses <2 nm) were applied in extraction of the overexpressed guanine synthesized in the cytoplasm of leukemia cells. The blood serums containing the extracted guanine were used in differential pulse voltammetry (DPV) with reduced graphene oxide nanowall (rGONW) electrodes to develop fast and ultra-sensitive electrochemical detection of leukemia cells at leukemia fractions (LFs) of ∼10-11 (as the lower detection limit). The stability of the DPV signals obtained by oxidation of the extracted guanine on the rGONWs was studied after 20 cycles. Without the guanine extraction, the DPV peaks... 

In this work, graphene oxide (GO) aqueous suspensions prepared by a chemical exfoliation method showed a fluorescence peak at ∼615 nm. Photoluminescence spectroscopy determined that functionalization of the GO sheets by 3-(2-Aminoethylamino) propyltrimethoxysilane molecules significantly quench the fluorescence property of the GO sheets. Fourier transform infrared spectroscopy confirmed proper functionalization of the GO sheets. Curcumin was applied as a fluorescent natural material with an emission peak at ∼550 nm wavelength for green fluorescent labeling of the functionalized-GO sheets. The curcumin-labeled functionalized-GO sheets showed an intense emission band fluorescent property with... 

Multi-component nanocomposite thin films (composed of cellulose nanofiber (CNF), alginate, bioglass nanoparticles (BG NPs) and gentamicin) were prepared by using cathodic electrophoretic deposition (EPD) under different isostatic pressures of 10−2 mbar (LP), atmospheric (AP), and 5 bar (HP). According to thermal gravity analysis, larger amounts of CNF and alginate could be deposited on the surface at the AP condition in comparison with the LP and HP conditions. On the other hand, higher amounts of the BG NPs could be deposited at the LP condition as compared to the other conditions. The drug (gentamicin) loading/releasing of the samples prepared at the HP condition was found to be higher... 

In this paper, a fuzzy random minimum cost flow problem is presented. In this problem, cost parameters and decision variables are fuzzy random variables and fuzzy numbers respectively. The object of the problem is to find optimal flows of a capacitated network. Then, two algorithms are developed to solve the problem based on Er-expected value of fuzzy random variables and chance-constrained programming. Furthermore, the results of two algorithms will be compared. An illustrative example is also provided to clarify the concept  

In this paper, we will discuss two special classes of mathematical programming models with fuzzy random variables. In the first model, a linear programming problem with fuzzy decision variables and fuzzy random coefficients is introduced. Then an algorithm is developed to solve the model based on fuzzy optimization method and fuzzy ranking method. In the second model, a fuzzy random quadratic spanning tree problem is presented. Then the proposed problem is formulated and solved by using the scalar expected value of fuzzy random variables. Furthermore, illustrative numerical examples are also given to clarify the methods discussed in this paper  

In this paper, a fuzzy approach is applied to special classes of integer programming problems with all diierent constraints. In the rst model, a fuzzy integer programming model is developed to represent the all-diierent constraints in mathematical programming. In order to solve the proposed model, a new branching scheme for the Branch and Bound algorithm is also presented. In the second model, a special class of large-scale multi-objective fuzzy integer programming problems with all-diierent constraints is introduced. A solution method for the proposed model is also developed by using the decomposition technique, weighting method and Branch and Bound algorithm. An illustrative numerical... 

In this paper, a fuzzy random minimum cost flow problem is presented. In this problem, cost parameters and decision variables are fuzzy random variables and fuzzy numbers respectively. The object of the problem is to find optimal flows of a capacitated network. Then, two algorithms are developed to solve the problem based on Er-expected value of fuzzy random variables and chance-constrained programming. Furthermore, the results of two algorithms will be compared. An illustrative example is also provided to clarify the concept  

Graphene oxide foam (GOF) layers with thicknesses of ∼15-50 μm and density of ∼10 graphene oxide (GO) sheets/μm were fabricated by precipitation of chemically exfoliated GO sheets in an aqueous suspension at ∼80 °C under UV irradiation. Then, rolled GOFs with desirable scales were developed as electrically conductive 3D-scaffolds and applied in directional growth of neural fibers, through differentiation of human neural stem cells (hNSCs) into neurons under an electrical stimulation. X-ray photoelectron spectroscopy indicated that the UV irradiation resulted in partial deoxygenation of the layers. Scanning electron microscopy and Raman spectroscopy confirmed the presence of multilayer GO... 

Graphene nanoplatelets with lateral dimensions of ∼50-200 nm and thicknesses <2 nm were utilized for the extraction of nucleic acids (NAs) from eukaryotic and prokaryotic cells. The graphene nanoplatelets (both chemically exfoliated graphene oxide nanoplatelets and hydrazine-reduced graphene oxide nanoplatelets) successfully extracted plasmid DNA (pDNA) from Escherichia coli bacteria, comparable to a conventional phenol-chloroform (PC) method. Furthermore, it was found that the yield of graphene nanoplatelets in genomic DNA (gDNA) and RNA extractions from embryonic stem cells (ESCs) was also comparable to the yield of the conventional methods. The effects of the graphene nanoplatelets on... 

In the last two decades, quantum dots nanomaterials have garnered a great deal of scientific interest because of their unique properties. Quantum dots (QDs) are inorganic fluorescent nanocrystals in the size range between 1 and 20 nm. Due to their structural properties, they possess distinctive properties and behave in different way from crystals in macro scale, in many branches of human life. Cadmium telluride quantum dots (CdTe QDs) were labeled with 68Ga radio nuclide for fast in vivo targeting and coincidence imaging of tumors. Using instant paper chromatography, the physicochemical properties of the Cadmium telluride quantum dots labeled with 68Ga NPs (68Ga@ CdTe QDs) were found high... 

Graphene oxide-polyvinyl chloride composite was prepared using tetrahydrofuran solvent-assisted dispersion of characterized nano flakes of graphene oxide in polymer matrix. Electrical percolation threshold of GO/PVC nanocomposite was determined via a finite element simulation method with a 2D model and compared with experimental results. A conductive cell with two silver coated walls was designed and fabricated for exploring dosimetric properties of the composite. Some characteristics of the new nanocomposite such as linearity of dose response, repeatability, sensitivity and angular dependence are investigated. According to 2D proposed method, obtained data associated to electrical... 

This research reports the preparation and examination of Cadmium Telluride (CdTe) Quantum Dots and doping CdTe QDs with Europium (Eu), Gadolinium (Gd), and Manganese (Mn) prepared in aqueous solution using TGA as a capping agent. Magnetic QDs (MQDs) are important agents for fluorescence (FL) /magnetic resonance (MR) dual-modal imaging due to their excellent optical and magnetic properties. Herein, the chemical bonds, structural, fluorescence, and magnetized properties of CdTe QDs and effect of Mn, Eu, and Gd ions doping on their properties were examined by X-ray powder diffraction (XRD), high-resolution transmission electron microscopy (HRTM), Energy-dispersive X-ray spectroscopy (EDX),... 

Two-dimensional (2D) transition metal dichalcogenides are promising candidates of photodetectors where they are commonly grown parallel to the substrate due to their 2D characteristics in micrometer scales from exfoliation of bulk crystals or through high temperature chemical vapor deposition (CVD) methods. In this study, semi-hexagonal vertical nanosheets of SnS2 layered have been fabricated on FTO substrate without using Sn source through CVD method at relatively low temperature (500 °C). Due to exceptional band alignment of triple cation lead perovskite (TCLP) with semi-hexagonal SnS2 nanosheets, an improved photodetector has been fabricated. This type of photodetectors fabricated through... 

A temperature-induced degenerate p-type graphene nanopore/reduced graphene oxide (GNP/rGO) heterojunction-based nanodevice was prepared and studied for the first time, showing a robust negative differential resistance (NDR) feature. In this regard, cellulose-based perforated graphene foams (PGFs), containing numerous nanopores (with an average size of ∼2 nm surrounded by nearly six-layer rGO walls) were synthesized using bagasse as a green starting material. The PGFs with an essential p-type semiconducting property showed a band gap energy of ∼1.8 eV. The observed two-terminal NDR peak could present stable and reversible features at high temperatures of 586-592 K. It was demonstrated that...