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Synthesize and Characterization of 2D WS2 Nano-layers for Next Generation Optoelectronic Devices
, M.Sc. Thesis Sharif University of Technology ; Simchi, Abdolreza (Supervisor)
Abstract
Transition Metal Dichalcogenids (TMD) are types of 2D materials that exibit wide range of electronic, optical, mechanical, chemical, and thermal properties. These materials with MX2 general formula, have atract attentions with respect to their unusual properties because of their very limited dimensions. Their tunable properties and materials availibility make them attractive for wide range of applications. In recent years, chemical vapor deposition (CVD) methods are promising in preparing high quality TMD with scalable size, controllable thickness, and very excellent electronic properties. Also, chalenges are remaining in synthesis and transfering of TMD are difficulty for most of...
Seedless growth of two-dimensional disc-shaped WS2 layers by chemical vapor deposition
, Article Materials Chemistry and Physics ; Volume 257 , 2021 ; 02540584 (ISSN) ; Ghanbari, H ; Simchi, A ; Maghsoumi, A ; Sharif University of Technology
Elsevier Ltd
2021
Abstract
Chemical processing of two-dimensional (2D) transition metal dichalcogenides has attracted immense attention due to their unique optical, electrical, and catalytic properties. In this paper, we show that under special conditions during seedless chemical vapor deposition (CVD), it is possible to grow large-area 2D WS2 layers with disc-shaped morphology, which has been scarcely reported. Detailed characterizations of the CVD-grown layers by Raman spectroscopy, atomic force microscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy have revealed that a gradient in the precursor concentration in the gas phase and strain energy in the deposited hexagonal clusters favor...
Developing seedless growth of atomically thin semiconductor layers: Application to transition metal dichalcogenides
, Article Ceramics International ; Volume 44, Issue 13 , 2018 , Pages 15795-15803 ; 02728842 (ISSN) ; Sovizi, S ; Ghanbari, H ; Simchi, A ; Aboudzadeh, N ; Sharif University of Technology
Elsevier Ltd
2018
Abstract
Controlled growth of atomic monolayers of IV-VII transition metal dichalcogenides (TMDs) has provided unprecedented opportunities to fabricate modern optoelectronic nanodevices. However, synthesis of large-area and high quality two-dimensional TMDs is still challenging. We have synthesized WS2 and MoS2 nanosheets by atmospheric pressure chemical vapor deposition (APCVD) at wide-range of processing conditions. The nanostructures were analyzed by optical and confocal microscopy, atomic force microscopy, Raman spectroscopy, and X-ray diffraction to determine the thickness, lateral size and structure of the deposits. Through designing and performing of a set of controlled experiments as well as...
Physicomechanical properties of spark plasma sintered carbon nanotube-containing ceramic matrix nanocomposites
, Article Nanoscale ; Volume 9, Issue 35 , 2017 , Pages 12779-12820 ; 20403364 (ISSN) ; Sovizi, S ; Azarniya, A ; Rahmani Taji Boyuk, M. R ; Varol, T ; Nithyadharseni, P ; Madaah Hosseini, H. R ; Ramakrishna, S ; Reddy, M. V ; Sharif University of Technology
2017
Abstract
Recently, a wide variety of research works have focused on carbon nanotube (CNT)-ceramic matrix nanocomposites. In many cases, these novel materials are produced through conventional powder metallurgy methods including hot pressing, conventional sintering, and hot isostatic pressing. However, spark plasma sintering (SPS) as a novel and efficient consolidation technique is exploited for the full densification of high-temperature ceramic systems. In these binary nanocomposites, CNTs are added to ceramic matrices to noticeably modify their inferior properties and SPS is employed to produce fully dense compacts. In this review, a broad overview of these systems is provided and the potential...
, M.Sc. Thesis Sharif University of Technology ; Gholami, Mohammad Reza (Supervisor)
Abstract
Nanosized CdS coupled TiO2 nanocrystals were prepared by a microemulsion-mediated Hydrothermal method at relatively low temperatures. Modification of this nanocomposite with Tyrosine,Phenylalanine,Glysine and Glutamate ,especially Tyrosine resulted in enhanced photocatalytic degradation rate of Nitrobenzene( NB ) compared to using CdS-TiO2 under visible light irradiation. The prepared samples were characterized by BET,SEM, XRD, UV–Vis spectroscopy ,FTIR .It was found which have high surface area about 470 m2 g−1 and mesoporous character with the average pore diameter of 2.8 nm.The results showed this nanocomposite consisted of uniform anatase TiO2 with highly dispersed cubic phase CdS...
Simulation of Proteins at Constant pH
, M.Sc. Thesis Sharif University of Technology ; Ejtehadi, Mohammad Reza (Supervisor)
Abstract
Proteins are of fundamental importance for life on Earth and participate in virtually every process within cells. The function of a protein depends on its three dimensional structure. If this is disrupted, the protein loses its biological activity. In addition to temperature, pressure and ionic strength, pH is also an important factor that affects the configuration of proteins. Proteins contain acidic and basic residues. Variations in pH lead to changes in distribution of atomic charge, which in turn affect the stability and function of proteins. Protein folding occurs in a specific pH range, a deviation from which may facilitate misfolding or Amyloid aggregation. It is therefore necessary...
Temperature-responsive smart nanocarriers for delivery of therapeutic agents: applications and recent advances
, Article ACS Applied Materials and Interfaces ; Volume 8, Issue 33 , 2016 , Pages 21107-21133 ; 19448244 (ISSN) ; Sahandi Zangabad, P ; Ghasemi, A ; Amiri, M ; Bahrami, M ; Malekzad, H ; Ghahramanzadeh Asl, H ; Mahdieh, Z ; Bozorgomid, M ; Ghasemi, A ; Rahmani Taji Boyuk, M. R ; Hamblin, M. R ; Sharif University of Technology
American Chemical Society
2016
Abstract
Smart drug delivery systems (DDSs) have attracted the attention of many scientists, as carriers that can be stimulated by changes in environmental parameters such as temperature, pH, light, electromagnetic fields, mechanical forces, etc. These smart nanocarriers can release their cargo on demand when their target is reached and the stimulus is applied. Using the techniques of nanotechnology, these nanocarriers can be tailored to be target-specific, and exhibit delayed or controlled release of drugs. Temperature-responsive nanocarriers are one of most important groups of smart nanoparticles (NPs) that have been investigated during the past decades. Temperature can either act as an external...
The Effect of Soli-Structure Interaction on Dynamic Characteristics of Structures with Embedded Fondation
, M.Sc. Thesis Sharif University of Technology ; Ghannad, Mohammad Ali (Supervisor)
Abstract
Soil-structure interaction has significant effect on dynamic behavior of the super structure. This effect is usually investigated in two separate parts, i.e., the Kinematic Interaction effect and the Inertial Interaction effect. The first modifies the input ground motion to the foundation as a result of difference in soil and foundation stiffness. The later, i.e., the II effect, introduces the effect of soil flexibility and radiation of waves into the supporting medium on the response of the structure. These effects are usually considered by introducing a replacement oscillator with modified natural period and damping ratio subjected...
A misbehavior‐tolerant multipath routing protocol for wireless Ad hoc networks [electronic resource]
, Article International Journal of Research in Wireless Systems (IJRWS) ; Vol. 2, Issue 9, pp. , Sep. 2013 ; Pakravan, Mohammad Reza ; Aref, Mohammad Reza ; Sharif University of Technology
Abstract
Secure routing is a major key to service maintenance in ad hoc networks. Ad hoc nature exposes the network to several types of node misbehavior or attacks. As a result of the resource limitations in such networks nodes may have a tendency to behave selfishly. Selfish behavior can have drastic impacts on network performance. We have proposed a Misbehavior-Tolerant Multipath Routing protocol (MTMR) which detects and punishes all types of misbehavior such as selfish behavior, wormhole, sinkhole and grey-hole attacks. The protocol utilizes a proactive approach to enforce cooperation. In addition, it uses a novel data redirection method to mitigate the impact of node misbehavior on network...
Designi an Adaptive Beamforming Algorithm, Robust Against Direction-of-Arrival Mismatch
, M.Sc. Thesis Sharif University of Technology ; Bastani, Mohammad Hasan (Supervisor)
Abstract
Adaptive beamforming performance is very sensitive to any mismatch between actual and presumed steering vectors of desired signal. In addition to this sensitivity, presence of desired signal in training snapshots dramatically reduces the convergence rate, as compared to the case that signal-free training snapshots are available.
The present work is aimed at proposing a new adaptive beamformer that is robust against direction-of-arrival (DOA) mismatch and has high convergence rate. This method is based on desired signal elimination from training snapshots and sub-array beamforming technique. To this end, a Blocking matrix that converts primary data to desired signal free data is...
The present work is aimed at proposing a new adaptive beamformer that is robust against direction-of-arrival (DOA) mismatch and has high convergence rate. This method is based on desired signal elimination from training snapshots and sub-array beamforming technique. To this end, a Blocking matrix that converts primary data to desired signal free data is...
Numerical Analysis of Tunnel under Seismic Loads in Sandy Soils
, M.Sc. Thesis Sharif University of Technology ; Ahmadi, Mohammad Mahdi (Supervisor)
Abstract
In this research with Finite Element Method in ABAQUS, a Number of Numerical modeling has done in two-dimensions, which can be used to determic the effect of different factors on the seismic vulnerability of tunnels. Also, varios factor such as Geotechnical conditions, tunnel depth, tunnel thickness and ground water is considered in this study.One of the parameters considered in designing tunnels is the ability of the tunnel’s lining to withstand the seismic and geotechnical loads. Each section of the tunnels are designed according to the maximum stress witch created due to the earthquake. this stress’s created in tunnels can be devided in to 3 category : the axial force,the Shear force and...
Modeling of Water-energy Cycle and Water Particle Pathways in the Gadarchay Subbasin of the Lake Urmia Basin
, M.Sc. Thesis Sharif University of Technology ; Danesh Yazdi, Mohammad (Supervisor)
Abstract
The water level of Lake Urmia has experienced a drop of 7.83 meters, from 1995 to 2017. According to previous studies, the uncontrolled development of agriculture, high consumption cultivation pattern, overuse of water resources for agricultural use and high water loss due to low irrigation efficiency, are the most important factors in the drying of Lake Urmia. Since agricultural sector is the largest water consumer (approximately 90%), the Lake Urmia Restoration Program has decided to study and implement the 40% reduction of water consumption in agricultural sector plans.Due to the inherent complexity of the Urmia Lake basin, accurate and realistic evaluation of the effectiveness of the...
Numerical Investigation of the Effects of Different Geotechnical Parameters and Train Speed on the Train-Induced Vibrations
, M.Sc. Thesis Sharif University of Technology ; Ahmadi, Mohammad Mehdi (Supervisor)
Abstract
Train-induced vibrations may become a source of annoyance to the residential environments and disturb the vibration-sensitive instruments. This paper aims to numerically study train-induced vibrations and affecting parameters such as foundation of the building adjacent to the railway, soil stiffness value and its variation pattern in depth and the train speed. To this end, a plane strain model was developed using finite difference program, FLAC2D. In order to simulate possible material damping of soil subjected to dynamic loading, hysteretic damping is incorporated into the model. The results of analyses performed in this study showed that increasing the train speed may not lead to an...
To Make the Membrane for Drug Retard Release by Supercritical System
, M.Sc. Thesis Sharif University of Technology ; Goodarznia, Iraj (Supervisor)
Abstract
In this study the main goal is to prepare a membrane to perform delayed drug release and absorbtion in the human body. To do so the supercritical method was used. A well-known biodegradable polymer was used. These kinds of polymers are used in drug delivery, wound dressing or scaffolding for cell culture. A membrane produced out of these kin of polymers is expected to have a good accordance with the goals.Ploy Vinyl alcohol, having very good bio degradable characteristics was used as the main polymer and Poly Ethylene Glycol (PEG) was used as an additive to make changes in the membrane structure. Also Dimethyl Sulfoxide, a polar solvent having the capability of solving both polymers is used....
Estimating Price Elasticity of Gasoline Demand Using Transaction-Level Data
, M.Sc. Thesis Sharif University of Technology ; Vesal, Mohammad (Supervisor) ; Rahmati, Mohammad Hossein (Supervisor)
Abstract
One of the most widely discussed parameters in energy economics is the price elasticity of gasoline demand due to its substantial implications for taxation, energy efficiency, and environmental policies. This paper aims to estimate the price elasticity of gasoline demand using a novel source of data. The data is from Iran, in the early months of 2014. Vehicles get a quota of 60 liters per month as subsidized gasoline at a lower price. The quota is transferable to the next months if it has not been consumed. All of the information about each pumping transaction is gathered in a centralized database, assigning a unique fuel card to each vehicle. Consequently, the structure of the market provides...
Observer-Based Controller Design for Nonlinear Fractional Order Systems
, M.Sc. Thesis Sharif University of Technology ; Shahrokhi, Mohammad (Supervisor)
Abstract
In this study, an adaptive controller design for nonlinear fractional order systems in the strict-feedback form has been investigated. The system is subject to unknown dynamics, unmeasured state variables, quantized input and output, and input nonlinearity. A linear observer is used to solve the problem of unmeasured state variables. The fuzzy logic system is used to estimate the unknown functions, and instead of updating all the regressor weights, only the upper bound of their norms is updated, which significantly reduces the computational load. In the controller design, limitations due to the bandwidth of data transmission have been considered by applying quantizers in the input and output...
Analysis and Improvement of Intrusion Detection Methods in Data Network Routers
, M.Sc. Thesis Sharif University of Technology ; Aref, Mohammad Reza (Supervisor) ; Pakravan, Mohammad Reza (Co-Advisor)
Abstract
High-quality online services demand reliable and fast packet delivery at the network layer. However, clear evidence documents the existence of compromised routers in the ISP and enterprise networks, threatening network availability and reliability. A compromised router can stealthily drop, modify, inject, or delay packets in the forwarding path to launch Denial-of-Service, surveillance, man-in-the-middle attacks, etc. So researches tried to create intrusion detection methods to identify adversarial routers and switches. To this end, data-plane fault localization (FL) aims to identify faulty links and is an effective means of achieving high network availability. FL protocols use...
Topological Defects in Confined Nematics by Planar Anchoring
, M.Sc. Thesis Sharif University of Technology ; Ejtehadi, Mohammad Reza (Supervisor) ; Mozaffari, Mohammad Reza (Supervisor)
Abstract
Confining nematic liquid crystal between two curved boundary conditions while the nematic molecules have a degenerate planar anchoring leads to complex and beautiful textures of molecular disparagement(defect) in the bulk and on the surfaces. Such the liquid crystal shells are made with double-emulsion techniques in microfluidic devices have provided applications for micro-scale colloidal linkers.In this work, we have numerically minimized the elastic energy in one-constant approximation in present of Fournier’s degenerate surface potential with finite element method. The nematic shell is confined between two spherical surfaces that we have studied the final energies and their related...
Improving the Performance of Transport Layer Protocols in Cognitive Radio Networks
, M.Sc. Thesis Sharif University of Technology ; Hemmatyar, Ali Mohammad Afshin (Supervisor)
Abstract
The abstract is the most important section of the thesis because many readers limit most of their reading to abstracts, saving in-depth reading for specific theses. It should give the reader a "preview" of what's to come. The abstract should emphasize new and important aspects of the study or observations. The purpose of the abstract is to allow researchers to decide whether or not to read the whole thesis. The abstract is what researchers read first to decide if the thesis is important, interesting, and it allows them to assess the relevance of a thesis to their own research, without having to read the entire thesis. Thus, it is crucial that the abstract both summarize succinctly the key...
Experimental investigation of operating conditions for preparation of PVA-PEG blend membranes using supercritical CO2
, Article Journal of Supercritical Fluids ; Vol. 95 , November , 2014 , pp. 603-609 ; ISSN: 08968446 ; Nejad-Sadeghi, M ; Goodarznia, I ; Sharif University of Technology
2014
Abstract
Poly(vinyl alcohol)-polyethylene glycol, PVA-PEG, blended membrane were prepared using supercritical fluid assisted phase-inversion method, in which scCO2 was used as the anti-solvent. Poly(vinyl alcohol) was utilized as the main polymer, polyethylene glycol as the additive, and dimethyl sulfoxide (DMSO) as the solvent of these polymers. Taguchi method was used to investigate the effect of some operating parameters on the morphology of the membranes. The L16 orthogonal array was selected under the following conditions: pressure (100, 135, 165 and 200 bar), temperature (40, 45, 50 and 55°C) and PEG weight percent (0, 0.33, 0.66, and 1%). Total polymer concentration of solutions in all...