Sharif Digital Repository

Selective oxidation of H2S to elemental sulfur in a fixed bed reactor over seven nanocatalysts has been investigated and compared to commercial claus catalyst. Among them, Al2O3-supported sodium oxide nanocatalyst prepared with wet chemical technique and Al2O3 nanocatalyst prepared with spray pyrolysis method were the most active catalysts for selective oxidation of H2S to elemental sulfur. The remaining nanocatalysts were deactivated, mainly due to the interaction with H2S and conversion into sulfides. For synthesis of Al2O3 with spray pyrolysis method we use statistical design of experiments (box-behnken design) in order to screen the effects of significant synthesizing parameters  

In this study, the influence of multi wall carbon nanotube on the thermal properties and microstructure of open cell flexible polyurethane (PU) foam was investigated. To do this untreated CNT (named here n-CNT) along with three different highly functionalized CNTs having carboxyl, hydroxyl and amide functional groups, abbreviated here by CNT-COOH, CNT-OH and CNT-NH-COR, respectively, were employed. A series of PU foam with and without CNTs (both treated and untreated ones) were prepared by cast molding. Prior molding, the CNTs (0.1 wt% loading) were first dispersed into the polyol (Mw = 3000 g/mol and OH No. 56) and then the mixture was subsequently added to the isocynate (TDI). The SEM... 

In this research a novel palladium nanocatalyst was synthesized over single-wall carbon nanotube (SWNT) support and then applied in the selective hydrogenation of acetylene in an ethylene rich-flow stream. This nanocatalyst displayed a very promising selectivity toward ethylene production upon rising of the temperature, as well as suppressing oligomer formation during acetylene hydrogenation. It was rationalized that the overwhelming governing mechanism for the acetylene hydrogenation over the 0.48 wt% Pd/SWNT was the hydrogen transfer. Furthermore, new operating conditions for selective hydrogenation of acetylene in ethylene rich-flow were introduced through which the selective... 

The major obstacle in using natural gas as a clean and abundant fuel in transportation industries is the low density of energy obtained from its combustion. Adsorbed Natural Gas (ANG) is a useful method to increase the energy density and store the natural gas. The lower cost and higher safety have made it different from the other storage technologies. In addition, ANG can be useful to solve the lack of gas in the peak of consumption. Among all adsorbents, Activated Carbon (AC) has shown the highest adsorption capacity of natural gas. In the present project, walnut shell has been used as the precursor in the chemical synthesise of AC. The main effective factors in chemical activation, such as... 

A series of V2O5 catalysts supported on multiwall carbon nanotube (MWCNT), single wall carbon nanotube (SWCNT) and graphene were synthesized by hydrothermal and reflux methods for oxidative dehydrogenation of propane (ODHP) to propylene. The catalysts were characterized by techniques including the BET surface area measurements, XRD, FTIR, H2-TPR, NH3-TPD, FESEM and UV-vis diffuse reflectance. The performance of the catalysts and the supports were subsequently examined in a fixed bed reactor. The vanadium catalyst supported on graphene with C/V molar ratio of 1:1 synthesized through the hydrothermal method had the best performance under the reactor test conditions of 450°C, feed C3H8/Air... 

Oil/water separation is an important field, not only for scientific research, but also for environmental, economic, and social issues. On the one hand, oily wastewater, resulting from industries such as steel, aluminum, food, textile, leather, petrochemical and metal finishing, has become the most common pollutant all over the world. On the other hand, frequent oil spill accidents are of great concern since the discharge can lead not only to serious environmental pollution, but also a great loss of energy.
In crude oil removing water is necessary due to reducing corrosion, increasing thermal values of fuels obtained from crude oil, preventing catalists from destruction by water and... 

Optimization of energy consumption is generally important in mobile networks and in particular in automotive networks. One of the challenges of installing roadside units in automotive case networks is to provide energy to the equipment assigned to these units. In some cases, power is easily available, but in many places, the cost of energy is very high and does not have economic justification. Therefore, optimization of energy consumption in roadside unit is of great importance. Typically, vehicles limitations in terms of energy consumption for communications are far lower than that of a roadside unit. In this dissertation, part of roadside communication to vehicles is shifted to the... 

Delay-tolerant networks refer to the networks that lack stable end-to-end paths due to the high mobility of nodes. In order to tackle the intermittent connections, nodes of delay-tolerant networks store the data packets and carry them. Nodes forward data packets according to routing protocols once they enter each other's communication range. In order to increase the probability of delivery, several or many copies of a packet can be disseminated in the network. Over the past years, various routing protocols have been proposed for delay-tolerant networks. These protocols differ from each other in the number of copies that are disseminated in the network or the information used to make routing... 

Magnetron is one of the microwave-generating devices that operates based on the microwave-electron flow interaction in the active region of the tube, which is affected by the resonant cavities and It is used in a wide range of power (from kW range at home microwave ovens to several GW in relativistic high power magnetrons and the frequencies from the order of few too MHz to tens of GHz). Although nowday's low-power generators based on transistors have replaced microwave generating tubes and even MW radio transmitters are made based on the combination of semiconductor microwave generators, but in the production of RF pulses at higher frequencies and powers, the electron tubes are the main... 

CO2 as a green house gas plays a significant role in the global warming and weather changes. Absorption by means of amine solutions is the main industrial technique for separating of CO2 from gas mixtures. Hazards associated with high temperature during solvent recovery, large size of equipment, corrosion, solvent degradation, and other reasons has made researchers to look for alternative processes such as adsorption. The aim of this study was to synthesis and modify the nano adsorbent for CO2 capture. To fulfill this purpose, various nano silica structures were synthesized and the amount of adsorption of each sample was determined. To investigate the performance capability nano_adsorbents,... 

Financial distress can propagate through different channels such as bank run, deposit interbank market,networks and asset prices. In this paper, with the assumption of deposit insurance, no linkages between banks, no deposit interbank market and fixed asset prices, we show that asset-side shocks might propagate through both loan interbank market and deposit market. However, when there is aggregate liquidity surplus in the banking system, loan interbank market results in the first best allocation. In contrast, aggregate liquidity shortage does not result in optimum allocation. In the presence of deposit and loan interbank market, not only shocks propagate but also they are magnified with the... 

With the rapid advances in microwave semiconductor devices and systems, the demand for implementation of nonlinear transmission lines (NLTLs) is rapidly increased. NLTLs support short pulses and wide band-widths. These networks provide cutoff frequencies over hundreds of GHz and picosecond rise times. Among all of the applications of NLTLs, the most attention has been paid to their application in the generation of high power RF pulses. In this application, a high power rectangular pulse is injected to the line, gradually evolved to an oscillatory pulse while propagating through the network, and finally, in the form of a high power RF pulse, is delivered to the load. NLTLs are the most... 

An injector is one of the most important components of the two components chemical propulsion system used in satellite control. The design of an injector is a complicated and time-consuming process and is largely dependent on laboratory data. In this study, the spray characteristics obtained from a small scale swirl injector under different operating conditions have been experimentally measured in a laboratory environment, such as the injector discharge coefficient, spray cone angle, and the distribution of droplets in the field. To calculate the discharge coefficient, the flow rate of the injector has been measured for different operating pressures. The shooting method and image processing... 

Due to the potential risk of sulfur compounds in fossil fuels and according to today’s regulations, sulfur content should be kept as low as possible, e.g., below 5 ppm. Mercaptans are one of the sulfur components in natural gas. Scope of this research defined as catalytic removal of ethyl mercaptan from the gas stream. For this purpose, two microreactor systems placed in series. In the first microreactor, catalytic decomposition of ethyl mercaptan has been investigated. In the first step of this survey, a microreactor with 24 microchannels with a newly designed distributor has been developed with a computational fluid dynamic technique. in comparison to the conventional triangular... 

Dominance over the seismic behavior of structures leads to proper design and the cost reduction of structures according to the structures demand performance. In this regard, the issue of performance-based seismic design of structures has been proposed in which the nonlinear behavior of structures is the basis for the design and evaluation of structures during earthquakes. Moreover, regarding of soil under the structures will change the elastic and inelastic behavior of structures; also, the effects of soil-structure interaction on the seismic performance of structures should be considered to achieve the real behavior of structures. Hence, the purpose of this study is to evaluate the... 

In this thesis, elliptical liquid jet breakup in crossflow has been investigated. To do this, two elliptical nozzle with different aspect ratio were built. First, the effective and important dimensionless numbers were extracted. Then, the physical aspect of the question was analyzed. All the experiments have been done in atmospheric conditions with water fluid, air as the liquid jet, and gas crossflow respectively.To create crossflow, a square cross section channel and one blower which are set in the beginning of the channel were made use of. Water is injected into air crossflow by the injector installed under the channel. The system used in revealing the crossflow is shadowgraphy system.... 

Flow analysis in and out of the pressure-swirl injector in supercritical condition is investigated in this thesis. These injectors widely are used in different industries such gas turbine combustion chamber and liquid fuel rockets. Flow simulation in these injectors is so complex because of existence of gas core in axial region and high swirl and axial speeds in injectors. Unlike subcritical condition, droplet and ligament don’t form in supercritical condition so injector performance represents with two parameters including liquid film thickness in vortex chamber and liquid spreading angle. Mass flow, geometric constant, length and the distance between tangential inlet and injector head, are...