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rastgar-kafshgarkolaei--shokoufeh
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Chemically Modified Electrode Based on Carbon Nanostructures and Metal Nanoparticles: Preparation, Characterization and Application in Determination of the Pharmaceutical and Biological Compounds and Oxygen Reduction at Soft Interfaces Catalyzed by in Situ Generated Reduced Graphene Oxide
, Ph.D. Dissertation Sharif University of Technology ; Shahrokhian, Saeed (Supervisor)
Abstract
In the first part, the preparation of metallic, bi-metallic (alloy or mixtures) and metallic oxide nanoparticles on the substrate of carbon nanostructures (carbon nanotube and graphene based nanosheets) has been performed using chemical and electrochemical procedures. Then, the prepared nanostructures were characterized by electron microscopy, spectroscopy and electrochemical techniques. Finally, the nanofilms have been evaluated for sensing applications as a modifier on the electrode surface for accurate determination of trace amounts of some important pharmaceutical and biological compounds. In the first work, multi-walled carbon nanotubes decorated with Fe3O4 nanoparticles...
Nickel hydroxide nanoparticles-reduced graphene oxide nanosheets film: Layer-by-layer electrochemical preparation, characterization and rifampicin sensory application
, Article Talanta ; Vol. 119 , 2014 , pp. 156-163 ; ISSN: 00399140 ; Shahrokhian, S ; Sharif University of Technology
2014
Abstract
Electrochemical deposition, as a well-controlled synthesis procedure, has been used for subsequently layer-by-layer preparation of nickel hydroxide nanoparticle-reduced graphene oxide nanosheets (Ni(OH)2-RGO) on a graphene oxide (GO) film pre-cast on a glassy carbon electrode surface. The surface morphology and nature of the nano-hybrid film (Ni(OH)2-RGO) was thoroughly characterized by scanning electron and atomic force microscopy, spectroscopy and electrochemical techniques. The modified electrode appeared as an effective electro-catalytic model for analysis of rifampicin (RIF) by using linear sweep voltammetry (LSV). The prepared modified electrode exhibited a distinctly higher activity...
Graph-based Decomposition of Multi Input Nonlinear Dynamical Systems
, M.Sc. Thesis Sharif University of Technology ; Haeri, Mohammad (Supervisor)
Abstract
In this thesis, partitioning of multi inputs nonlinear dynamical systems into distinct subsystems with the goal of designing decentralized, distributed, and cooperative predictive controllers for reducing the computational load and time in practical implementations has been studied. At first, the concept of dynamical systems graph is introduced and the problem of decomposing nonlinear dynamical systems into distinct subsystems has been converted to the problem of decomposing dynamical systems graph into separate subgraphs. The proposed method for decomposition of the dynamical system graph is represented as a linear integer optimization programing where the separated subgraphs is obtained by...
Pd-Au nanoparticle decorated carbon nanotube as a sensing layer on the surface of glassy carbon electrode for electrochemical determination of ceftazidime
, Article Materials Science and Engineering C ; Vol. 34, issue. 1 , 2014 , pp. 318-325 ; ISSN: 09284931 ; Salimian, R ; Rastgar, S ; Sharif University of Technology
2014
Abstract
A simple electrodeposition method is employed to construct a thin film modifier of palladium-gold nanoparticles (Pd-AuNPs) decorated multi-walled carbon nanotube (MWCNT) on the surface of glassy carbon electrode (GCE). Morphology and property of Pd-AuNPs-MWCNT have been examined by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). Electrochemical performance of Pd-AuNPs-MWCNT/GCE for detection of ceftazidime (CFZ) has been investigated by cyclic voltammetry (CV). This nanostructured film modified electrode effectively exhibited enhanced properties for detection of ceftazidime (CFZ). The effects of various experimental variables such as, the amount of casted MWCNT,...
Improving Transient Response in Data-Driven Control Systems
, M.Sc. Thesis Sharif University of Technology ; Tavazoei, Mohammad Saleh (Supervisor)
Abstract
The term "data-driven" was first introduced in computer science and has entered the vocabulary of controlled engineering in recent years. So far, several classes of data-driven-control (DDC) methods have been introduced, which are identified by different names in the literature such as data-driven control, data-based control, modeless control, model-free adoptive control, iterative feedback tuning and virtual reference feedback tuning.Data-driven control includes all control theories and methods in which the controller directly and using the input-output data of the control system or knowing the processed data and without explicit knowledge of the mathematical model of the system (unlike...
Galois Representation
, M.Sc. Thesis Sharif University of Technology ; Rastgar, Arash (Supervisor) ; Rajaei, Ali (Supervisor)
Abstract
Let K, k be two fields and GK be the Galois group of separable closure of K. By a Galois representation of dimension n of GK we mean a homomorphism ρ : GK → GLn(k) of topological groups. In this thesis we want to introduce the theory of Galois representations according to the Taylor’s paper [20] which has written based on his speech in international mathematical conference (ICM 2004). In general we want to build a suitable background for the reader who wants to read the Taylor’s paper with presenting the concepts related to Galois representations such as p-adic and l-adic representations, geometric representations, modular forms, L-function of a Galois representation, Weil-Deligne...
Spectrophotometric Determination of Ametryn Herbicide in Drainage Water Based on Aggregation of Gold Nanoparticles Capped with Citrate
, M.Sc. Thesis Sharif University of Technology ; Hormozi-Nezhad, Mohammad Reza (Supervisor) ; Torkian, A (Supervisor)
Abstract
Due to vast use of Ametryn herbicide in agricultural and even non-agricultural activities and the possibility of contamination of carp and natural water sources by this herbicide, determination of this herbicide in surface and ground water sources is very important. Therefor introducing simple and sensitive method for determination of Ametryn is critical.
This study demonstrate a simple and sensitive colorimetric method for the detection and determination of Ametryn based on aggregation of citrate capped AuNPs. Studied method relies upon shape and distance dependent AuNPs surface plasmon resonance. By replacing the sulfide containing Ametryn herbicide with citrate molecules on AuNPs...
This study demonstrate a simple and sensitive colorimetric method for the detection and determination of Ametryn based on aggregation of citrate capped AuNPs. Studied method relies upon shape and distance dependent AuNPs surface plasmon resonance. By replacing the sulfide containing Ametryn herbicide with citrate molecules on AuNPs...
Large scale inkjet-printing of carbon nanotubes electrodes for antioxidant assays in blood bags
, Article Journal of Electroanalytical Chemistry ; Vol. 717-718 , 2014 , Pages 61-68 ; ISSN: 15726657 ; Cortes Salazar, F ; Prudent, M ; Delobel, J ; Rastgar, S ; Lion, N ; Tissot J. D ; Tacchini, P ; Girault, H. H ; Sharif University of Technology
2014
Abstract
Herein, we present the large scale fabrication of carbon nanotubes (CNT) electrodes supported on flexible polymeric sheets by subsequent multilayer inkjet printing of a silver layer for electrical connection, CNT layers as active electrode material and an insulation layer to define a stand-alone CNT active electrode area with high accuracy. Optical and electrochemical characterization using several redox mediators demonstrates the reproducibility of the electrode surfaces and their functionality even with a single inkjet printed CNT layer. These electrodes are targeted to the clinical sector for the determination of the antioxidant power (AOP) of biologically relevant fluids by...