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Water treatment using stimuli-responsive polymers
, Article Polymer Chemistry ; Volume 13, Issue 42 , 2022 , Pages 5940-5964 ; 17599954 (ISSN) ; Roghani Mamaqani, H ; Riazi, H ; Abousalman Rezvani, O ; Sharif University of Technology
Royal Society of Chemistry
2022
Abstract
Water treatment is a process used to eliminate or reduce chemical and biological contaminants that are potentially harmful to the water supply for human use. Stimuli-responsive polymers are a new category of smart materials used in water treatment via a stimuli-induced purification process and subsequent regeneration of the polymers. Stimuli-responsive polymers dynamically change their physico-chemical properties upon environmental changes. They can undergo shrinkage or expansion, alter their optical properties, and change their electrical characteristics depending on the applied stimuli. In this context, various stimuli-responsive polymer systems such as self-assembled nanostructures,...
Control of Hiv-1 Infection Using Artificial Intelligence Methods
, M.Sc. Thesis Sharif University of Technology ; Shahrokhi, Mohammd (Supervisor)
Abstract
This project presents algorithms for intelligent control of the viral load in a HIV-1 infection model. The first part of thesis was dedicated to the study of the three states model adopted to describe the HIV-1 infection. A sensitivity analysis of the model parameters was described and computer simulations were provided to show the influence of the parameters explicitly. Then, an internal model control based on neural networks was implemented on the introduced infection model with including the RTIs and PIs drugs efficacies as control input. A stable adaptive neuro-control approach was presented for affine in the control nonlinear dynamical systems, whose nonlinearities were assumed to be...
Electrospinning of Core-shell Nanofibers for Extraction and Determination of Pesticide Residues from Aquatic Media
, M.Sc. Thesis Sharif University of Technology ; Bagheri, Habib (Supervisor)
Abstract
Porosity and high surface area is a profound concept for creating advance materials. Nanofibers are an important class of nano materials which would be used as novel sorbents because of their high surface to volume ratio as a result of long lengths and nano-to-micro-scale diameters. Electrospining is a simple method for producing fine nanofibers from different meterials such as, polymers, composites and ceramics to prepare highly efficient sorbents. Moreover, electrospining has been developed for fabricating nanofibers with core-shell structures. These structures in compared with conventional fibers have gained higher attentions due to their high aspect ratios and flexiblity in surface...
Web Application Attack Pattern Extraction using Deep Learning
, M.Sc. Thesis Sharif University of Technology ; Jalili, Rasool (Supervisor)
Abstract
One of the most important requirements in deploying a security system is to ensure the effectiveness and absence of bypass patterns. This is especially important for attack-based detection systems. One of the systems that has recently attracted the attention of network administrators is Web Application Firewall (WAF). The purpose of this thesis is to propose a deep learning approach to identify the pattern of SQL Injection (SQLi) attacks which could potentially bypass a WAF. We delve into the problem of detecting SQLi attacks among a very large dataset of existing SQL queries. To this end, we use one of the latest implementation of Recurrent Neural Network (RNN) called Long Short-Term Memory...
Optimal Coherent Control of Quantum Dynamics: Process-Based Approach
, Ph.D. Dissertation Sharif University of Technology ; Rezakhani, Ali (Supervisor)
Abstract
One of the main tools of the developing quantum technology is making the desired quantum gates and processes in the presence of the environmental noises. In this thesis, we first derive a Markovian master equation which defines purely the time evolution of the dynamics (process matrix) of the open system rather than its state (density matrix). This master equation indeed describes the time evolution of the Choi-Jamiolkowsli matrix which is independent of the state of the system at all times including the initial state. The n, by using this master equation we provide a scheme to manipulate optimally and locally the dynamics of the open system by external coherent agents. Such scheme...
Coherent dynamical control of quantum processes
, Article Physical Review A ; Volume 104, Issue 1 , 2021 ; 24699926 (ISSN) ; Rezakhani, A. T ; Sharif University of Technology
American Physical Society
2021
Abstract
Manipulation of a quantum system requires the knowledge of how it evolves. To impose that the dynamics of a system becomes a particular target operation (for any preparation of the system), it may be more useful to have an equation of motion for the dynamics itself, rather than the state. Here we develop a Markovian master equation for the process matrix of an open system interacting with a reservoir, which resembles the Lindblad Markovian master equation. We employ this equation to introduce a scheme for optimal local coherent process control at target times and extend the Krotov technique to obtain optimal control. We illustrate utility of this framework through several quantum...
Simulation of Thermal Barrier Coatings under Thermo-Mechanical and Low Cycle Fatigue Loadings
, M.Sc. Thesis Sharif University of Technology ; Farrahi, Gholamhossein (Supervisor)
Abstract
The main purpose in this thesis is the finite element simulation of thermal barrier coatings (TBC), subjected to residual stresses due to the coating process followed by thermo-mechanical fatigue loadings. This finite element modeling is performed in the ABAQUS software. In order to consider the actual condition of thermal barrier coating, models are defined based on a SEM image including real roughness and porosity of coating layers using image processing technique.
Two-step residual stress taking into account both coating process of bond coat and top coat layer is performed. Pre- heating of substrate and bond coat in order to reach comperessive stresses in coating layers has been...
Two-step residual stress taking into account both coating process of bond coat and top coat layer is performed. Pre- heating of substrate and bond coat in order to reach comperessive stresses in coating layers has been...
Three-dimensional nanofiber scaffolds are superior to two-dimensional mats in micro-oriented extraction of chlorobenzenes
, Article Microchimica Acta ; Volume 185, Issue 7 , 2018 ; 00263672 (ISSN) ; Manshaei, F ; Rezvani, O ; Sharif University of Technology
Springer-Verlag Wien
2018
Abstract
Three-dimensional (3D) polyamide scaffolds were fabricated by applying a solvent bath as the collecting element. Electrospun nanofibers were immersed into the solvent bath to give a material with a laminated 3D texture. In parallel, 2D nanofibers were synthesized and utilized as microextractive phases in a needle trap device to compare the capabilities of 2D and 3D materials in terms of headspace extraction of various chlorobenzenes (chlorobenzene, 1,2-dichlorobenzene, 1,4-dichlorobenzene, 1,2,4-trichlorobenzene and 1,2,3,4-tetrachlorobenzene). The results demonstrate the superiority of 3D nanofibrous scaffolds over 2D mats. The porosity, morphology, and thermal stability of the 3D scaffolds...
Design and Implementation of Phase Noise Meter in Digital Method
, M.Sc. Thesis Sharif University of Technology ; Banai, Ali (Supervisor)
Abstract
Phase noise is one of the important parameters in telecommunication systems and its measurement has always been considered. Digital phase noise measurement methods have a simpler implementation and calibration than analog types. Also, in digital methods, amplitude noise and phase noise can be separated and measured both at the same time. Comparing the phase noise of two oscillators with different frequencies is another major advantage of digital methods. The sensitivity of digital methods is limited to the noise of their analog-to-digital converters. Cross-correlation technique is used to reduce the minimum measurable level of phase noise. This method reduces the internal noise of the...
Toward higher extraction and enrichment factors via a double-reservoirs microfluidic device as a micro-extractive platform
, Article Journal of Separation Science ; Volume 42, Issue 18 , 2019 , Pages 2985-2992 ; 16159306 (ISSN) ; Baraazandeh, M ; Bagheri, H ; Sharif University of Technology
Wiley-VCH Verlag
2019
Abstract
In this study, firstly, a double-reservoir and switchable prototype of a micro-chip along with the respective holders were fabricated. A cyclic desorption process using microliter volume of organic solvent was adopted to prevent any outdoor contamination. As extractive phases, two identical sheets of electrospun polyamide/polypyrrole/titania nanofibers were synthesized using core–shell electro-spinning technique and utilized for determination of memantine in plasma samples. Field emission scanning electron microscopy images showed a high degree of porosity and homogeneity throughout the sheet structure. Also, energy dispersive X-ray analysis confirmed the presence of titania, while the...
Voltammetric studies of propylthiouracil at a carbon-paste electrode modified with cobalt(II)-4-chlorosalophen: Application to voltammetric determination in pharmaceutical and clinical preparations
, Article Microchimica Acta ; Volume 151, Issue 1-2 , 2005 , Pages 73-79 ; 00263672 (ISSN) ; Jannat Rezvani, M. J ; Sharif University of Technology
2005
Abstract
A carbon-paste electrode chemically modified with a Schiff-base complex of cobalt (cobalt(II)-4-chlorosalophen, CoClSal) is utilized to investigate the voltammetric response of propylthiouracil (PTU). The mechanism of electrocatalytic oxidation of the compound is investigated by means of cyclic voltammetric studies applying various pHs to the buffered solutions. The modified electrode exhibits effective catalytic properties that lower the anodic overpotential and enhance the rate of electron transfer for the electrochemical oxidation of PTU. The results of the cyclic voltammetric (CV) and differential pulse voltammetric (DPV) techniques showed that the modified electrode exhibits good...
Are the Components of the Assessment Center of the Relevant Company Sufficiently Valid? The Case Study of a Public Company
, M.Sc. Thesis Sharif University of Technology ; Tasavori, Misagh (Supervisor)
Abstract
The evaluation and selection of human resources is one of the most important management issues in organizations, and the importance of this issue increases when the evaluation and selection is related to managerial positions. Among the many methods that exist for evaluating and selecting human resources; The assessment center method is more useful for selecting candidates for management positions. The assessment center includes behavioral simulation exercises and competency where trained assessors observe and record behaviors and score competencies. The purpose of this research is to analyze and examine the fit of the model and the internal structure of the evaluation center in a government...
Optimisation of anti-resonance vehicle configuration for vibration Attenuation of railway bridges
, Article International Journal of Vehicle Structures and Systems ; Volume 5, Issue 2 , 2013 , Pages 63-67 ; 09753060 (ISSN) ; Kolagar, M ; Rezvani, M. A ; Sharif University of Technology
MechAero Found. for Techn. Res. and Educ. Excellence
2013
Abstract
Movements of the wheel loads and their sequential entry onto the bridges are known as the two root causes for the vibrations of the railway bridges. It is possible to reduce the levels of the unwanted bridge deck oscillations by introducing one or more size adjusted wagon(s) in the train configuration. The added wagon(s) are of different size(s) compared with the other cars in the train configuration. This can disturb the periodicity in the wheel loading. Consequently, it can interfere with the resonance phenomena and prevent the bridge from excessive vibrations. The purpose of this research is to calculate proper sizes for the anti-resonance rail vehicles. Such vehicles need to fulfil the...
Polyamide/titania hollow nanofibers prepared by core–shell electrospinning as a microextractive phase in a fabricated sandwiched format microfluidic device
, Article Journal of Chromatography A ; Volume 1528 , 2017 , Pages 1-9 ; 00219673 (ISSN) ; Hashemi Hedeshi, M ; Bagheri, H ; Sharif University of Technology
2017
Abstract
In this study, a low–cost microfluidic device from polymethyl methacrylate was fabricated by laser engraving technique. The device is consisted of a central chip unit with an aligned microchannel. Both sides of the engraved microchannel were sandwiched by two synthesized sheets from polyamide/titania (PA/TiO2) hollow nanofibers as extractive phases. The inlet and outlet of the device were connected to the polyether ether ketone tubes, while a peristaltic pump was used to deliver both sample and desorbing solvent through the microchannel. The recorded scanning electron microscopy images from the surface of the synthesized PA/TiO2 nanofibers, exhibit a good degree of homogeneity and porosity...
Immobilization of synthesized phenyl-enriched magnetic nanoparticles in a fabricated Y–Y shaped micro-channel containing microscaled hedges as a microextraction platform
, Article Analytica Chimica Acta ; Volume 1136 , 2020 , Pages 51-61 ; Hedeshi, M. H ; Bagheri, H ; Sharif University of Technology
Elsevier B.V
2020
Abstract
In this survey, a reliable and applicable Y–Y shaped micro–channel in a microfluidic device was designed and manufactured. A number of micro–scaled hedges were precisely fabricated inside the micro–channel to facilitate the immobilization of synthesized core–shell Fe3O4@SiO2 magnetic nanoparticles (MNPs), functionalized by triethoxyphenylsilane (TEPS) by sol-gel technique. Both sample and reagents were introduced into the microfluidic device by a syringe pump to perform the extraction and desorption steps. The functionalized MNPs were characterized by transmission electron microscopy, X-ray diffraction spectroscopy and Fourier transform infrared spectroscopy. By adopting the strategy of...
A novel dual-band transmission line with equal-phase responses
, Article IEEE Transactions on Microwave Theory and Techniques ; Volume 69, Issue 2 , 2021 , Pages 1265-1272 ; 00189480 (ISSN) ; Tajik, A ; Fakharzadeh, M ; Sharif University of Technology
Institute of Electrical and Electronics Engineers Inc
2021
Abstract
This article presents a novel dual-band transmission line (TL), consisting of a multibranch stub, which can provide equal unwrapped phases at two different frequencies. The frequency ratio can be close to one without any significant degradation in the device performance. Besides, the bandwidth of the proposed line can be manipulated at both frequencies by adjusting the design parameters. The behavior of the structure over the frequency bands is investigated theoretically, and the design procedure and relations are derived. The simulation and measurement results of a quarter-wavelength open-ended stub and a branch-line coupler (BLC) are presented and compared to verify the performance of the...
Image-based cell profiling enhancement via data cleaning methods
, Article PLoS ONE ; Volume 17, Issue 5 May , 2022 ; 19326203 (ISSN) ; Bigverdi, M ; Rohban, M. H ; Sharif University of Technology
Public Library of Science
2022
Abstract
With the advent of high-throughput assays, a large number of biological experiments can be carried out. Image-based assays are among the most accessible and inexpensive technologies for this purpose. Indeed, these assays have proved to be effective in characterizing unknown functions of genes and small molecules. Image analysis pipelines have a pivotal role in translating raw images that are captured in such assays into useful and compact representation, also known as measurements. CellProfiler is a popular and commonly used tool for this purpose through providing readily available modules for the cell/nuclei segmentation, and making various measurements, or features, for each cell/nuclei....
Design of an Active Exoskeleton Robot to Assist Human Knee Motion
, M.Sc. Thesis Sharif University of Technology ; Zohoor, Hassan (Supervisor)
Abstract
Nowadays nearly 1% of the world population depends on wheelchairs for walking and movement. Due to harmful changes in human lifestyle, different diseases like stroke and problems in musculoskeletal system are increasing noticeably. Despite the fact that wheelchairs have recently been improved they have faced big problems like forcing people not to move and just sit for a long period of time. Wearable robots not only help these patients to rehabilitate their disabled organ and walk, but also have a significant mental effect on them.
The analysis of an exoskeletal orthosis designed for patients who have pain in one of their knees is presented. A mechanism for knee exoskeleton is analyzed...
The analysis of an exoskeletal orthosis designed for patients who have pain in one of their knees is presented. A mechanism for knee exoskeleton is analyzed...
Preparation and Application of NiFe2O4 Nanoparticles in the Synthesis of Pyrroles and Sonogashira Reaction
, M.Sc. Thesis Sharif University of Technology ; Matloubi Moghaddam, Firouz (Supervisor)
Abstract
In the first chapter, high substituted pyrrole derivaitives were synthesized through a one pot four compounent reaction using carbonyl and amin compounds at the presence of magnetic nanoparticles of superparamagnetic ferrospinel NiFe2O4nanoparticles as catalyst.In the second chapter, NiFe2O4magnetic nanoparticles were employed in the Sonogashira reactions using phenyl acetylene as coupling partner with different types of aryle and alkyl halides in water as a green solvent. The results of these reactions were considered comprehensively
A copper-free Sonogashira reaction using nickel ferrite as catalyst in water
, Article Catalysis Communications ; Volume 60 , 2014 , Pages 82-87 ; 15667367 (ISSN) ; Tavakoli, G ; Rezvani, H. R ; Sharif University of Technology
2014
Abstract
The Sonogashira reaction using nickel ferrite nanoparticles as catalyst and under copper-free conditions was investigated in water as a green solvent. Various types of aryl and alkyl halides were successfully coupled with phenyl acetylene under the optimized reaction conditions with very good to excellent yields at a short time. The catalyst is easily recoverable and can be reused for several runs with a good turnover number