Sharif Digital Repository

In this article, the novel concept of using magnetic nanofluidic electrolyte for redox flow batteries is demonstrated for the first time. In this regard, the stable magnetic nanofluidic electrolytes are prepared by dispersing magnetic modified multiwalled carbon nanotubes (MMWCNTs) in the positive electrolyte of a polysulfide-iodide redox flow battery at mass concentrations of less than 0.3 g L−1. The electrochemical behavior of magnetic nanofluidic electrolyte was examined using cyclic voltammetry at different mass concentrations of MMWCNTs with a carbon felt electrode. Higher and stable peak current densities were observed at larger mass concentrations of MMWCNTs. A polysulfide-iodide... 

In dual-beam optical tweezers, the accuracy of position and force measurements is often compromised by crosstalk between the two detected signals, this crosstalk leading to systematic and significant errors on the measured forces and distances. This is true both for dual-beam optical traps where the splitting of the two traps is done by polarization optics and for dual optical traps constructed by other methods, e.g., holographic tweezers. If the two traps are orthogonally polarized, most often crosstalk is minimized by inserting polarization optics in front of the detector; however, this method is not perfect because of the de-polarization of the trapping beam introduced by the required... 

In dual-beam optical traps, the precision of position/force measurements is often compromised by crosstalk, i.e. imperfect separation of the two signals. We devise a simple yet very efficient method to perform crosstalk eliminating spatial filtering  

A novel approach named a magnetic flowable electrode (MFE) is proposed for the first time to enable enhancement of redox flow batteries (RFBs) performance. This approach enables the formation of a high active surface area electrode from magnetic nanomaterials, without the need to fabricate a self-supporting three-dimensional electrode structure. To form a simple MFE, magnetic modified carbon nanotubes are dispersed in the electrolyte, and permanent magnets are embedded behind the current feeder to apply a magnetic field across the flow cell channels. With circulating electrolyte, magnetic carbon nanotubes are aggregated on the graphite bipolar plate to form a well-structured nanoscale... 

Membrane nanotubes, ubiquitous in cellular systems, adopt a spectrum of curvatures and shapes that are dictated by their intrinsic physical characteristics as well as their interactions with the local cellular environment. A high bending flexibility is needed in the crowded cytoplasm where tubes often need to bend significantly in the axial direction at sub-micron length scales. We find the stiffness of spontaneously formed membrane nanotubes by measuring the persistence length of reconstituted membrane nanotubes freely suspended in solution and imaged by fluorescence microscopy. By quantifying the tube diameter we demonstrate for the first time that the persistence length scales linearly... 

Hough transform based object detectors divide an object into a number of patches and combine them using a shape model. For efficient combination of patches into the shape model, the individual patches are assumed to be independent of one another. Although this independence assumption is key for fast inference, it requires the individual patches to have a high discriminative power in predicting the class and location of objects. In this paper, we argue that the sparsity of the appearance of a patch in its neighborhood can be a very powerful measure to increase the discriminative power of a local patch and incorporate it as a sparsity potential for object detection. Further, we show that this... 

A thorough understanding of determining factors in angiogenesis is a necessary step to control the development of new blood vessels. Extracellular matrix density is known to have a significant influence on cellular behaviors and consequently can regulate vessel formation. The utilization of experimental platforms in combination with numerical models can be a powerful method to explore the mechanisms of new capillary sprout formation. In this study, using an integrative method, the interplay between the matrix density and angiogenesis was investigated. Owing the fact that the extracellular matrix density is a global parameter that can affect other parameters such as pore size, stiffness,... 

Background: Over the last two decades, breast cancer remains the main cause of cancer deaths in women. To treat this type of cancer, radiation therapy (RT) has proved to be efficient. RT for breast cancer is, however, challenged by intrafractional motion caused by respiration. The problem is more severe for the left-sided breast cancer due to the proximity to the heart as an organ-at-risk. While particle therapy results in superior dose characteristics than conventional RT, due to the physics of particle interactions in the body, particle therapy is more sensitive to target motion. Conclusions: This review highlights current and emerging strategies for the management of intrafractional... 

Microbial fuel cells (MFCs) have been a potential green energy source for a long time but one of the problems is that either the technology must be used on a large scale or special equipment have been necessary to keep the fuel cells running such as syringe pumps. Paper-based microbial fuel cells do not need to have a syringe pump to run and can run entirely by themselves when placed in contact with the fluids that are necessary for it to run. Paper-based microbial fuel cells are also more compact than traditional MFCs since the device doesn't need any external equipment to run. The goal of this paper is to develop a microbial fuel cell that does not require a syringe pump to function. This... 

With the success of in vitro single-molecule force measurements obtained in recent years, the next step is to perform quantitative force measurements inside a living cell. Optical traps have proven excellent tools for manipulation, also in vivo, where they can be essentially non-invasive under correct wavelength and exposure conditions. It is a pre-requisite for in vivo quantitative force measurements that a precise and reliable force calibration of the tweezers is performed. There are well-established calibration protocols in purely viscous environments; however, as the cellular cytoplasm is viscoelastic, it would be incorrect to use a calibration procedure relying on a viscous environment.... 

Polyethylene oxide (PEO)/chitosan (CS)/graphene oxide (GO) electrospun nanofibrous scaffolds were successfully developed via electrospinning process for controlled release of doxorubicin (DOX). The SEM analysis of nanofibrous scaffolds with different contents of GO (0.1, 0.2, 0.5 and 0.7 wt.%) indicated that the minimum diameter of nanofibers was found to be 85 nm for PEO/CS/GO 0.5% nanofibers. The π-π stacking interaction between DOX and GO with fine pores of nanofibrous scaffolds exhibited higher drug loading (98%) and controlled release of the DOX loaded PEO/CS/GO nanofibers. The results of DOX release from nanofibrous scaffolds at pH 5.3 and 7.4 indicated strong pH dependence. The... 

A new innovative 'universal' structural joint with multiple applications was devised. The two major conceived contexts for the use of this joint are 'joining beams to columns, ' and 'joining diagonal braces to horizontal ones. ' The main features of this joint are its high rotational capacity, its high shear deformation capacity, its high energy-dissipation capacity, its ability to contain damage, and its repalceability. Due to its geometry, it can well lend itself to protection measures against fire, normally practiced by the involving industries. This makes it a good candidate for being used in structures related to oil and gas industry, offshore or onshore. Through numerical modelling of... 

Abstract: Surface-nanostructured TiO2 nanorods were synthesized hydrothermally at 180 °C. Such nanorods have ‘crack-like’ surfaces that resemble burnt charcoal. Compared to nanorods with relatively smoother surfaces, the charcoal-like nanorods have higher-specific surface areas. By using the nanorods as a light-scattering layer in double-layered dye-sensitized solar cells, the cells based on the charcoal-like nanorods have 20 % higher dye loading and also higher diffuse reflectance compared with cells utilizing ‘smooth’ nanorods. The efficiency of a screen-printed double-layer dye-sensitized solar cell based on the charcoal-like nanorods is higher at 7.29 %. Electrochemical... 

This article presents an overview of the mechanical design and fabrication of a Rescue Robot (CEDRA) for operation in unstructured environments. In order to obtain an appropriate mechanism for climbing the stairs, a novel method has been developed. In this kinematics-based approach we don't need to perform any dynamic analysis which is highly complicated and time consuming for most rovers. According to the essential characteristics needed for rovers, two objective functions were defined. We have shown that the new mechanism performs better on rough terrains than the previous well-known mechanism widely used in the Mars rovers. Moreover the design parameters are optimized by means of Genetic... 

In this paper a novel approach to dynamic formulation of rovers has been presented. The complexity of these multi-body systems especially on rough terrain, challenged us to use the Kane's method which has been preferred to others in these cases. As an example, symbolic equations of a six-wheeled rover, named CEDRA Rescue Robot which uses a shrimp like mechanism, have been derived and a simulation of forward and inverse dynamics has been presented. Due to the clear form of equations, each term defines a physical meaning which represents the effect of each parameter, resulting in a frame-work for performance comparison of rovers. Although the method has been described for a 2-D non-slipping... 

This article presents an overview of the mechanical design features, fabrication and control of a Rescue Robot (CEDRA) for operation in unstructured environments. As a preliminary step, the essential characteristics of a robot in damaged and unstable situations have been established. According to these features and kinematical equations of the robot, design parameters are optimized by means of Genetic Algorithm. Optimum parameters are then utilized in construction. Upon fabrication, this unit has been tested in clean laboratory environment, as well as, ill-conditioned arenas similar to earthquake zones. The obtained results have been satisfactory in all aspects, and improvements are... 

This paper proposes an efficient mechanism that mitigates crosstalk faults in Network-on-Chips (NoCs). This is done by using a Packet Manipulating mechanism called PAM for reliable data transfer of NoCs. PAM investigates the transitions of a packet to minimize the forbidden transition patterns appearing during the flit traversal in NoCs. To do this, the content of a packet is manipulated using three different manipulating mechanisms. In other words, PAM manipulates the content of packet in three manipulating modes including: vertical, horizontal and diagonal modes. Then, comparing the transitions of these manipulating mechanisms, a packet with minimum numbers of transitions is selected to be... 

A long-term antibacterial activity of implants without compromising their biocompatibility is highly desirable to minimize the biomaterial-associated infections. Although tantalum oxide nanotubes (Ta2O5 NTs) are promising coating materials for orthodontics and orthopedics applications, their insufficient antibacterial activity retains vulnerability to post-implantation infections. This study aimed to endow antibacterial characteristics to the Ta2O5 NTs-coated Ti6Al4V substrates by decoration of silver oxide nanoparticles (Ag2O NPs). The well-adherent Ta2O5 NTs were grown via anodization of a pure tantalum (Ta) layer coated by physical vapor deposition (PVD) on the Ti6Al4V substrates. The... 

Heteropoly acids efficiently catalyzed the one-pot, three-component Mannich reaction of ketones with aromatic aldehydes and different amines in water at ambient temperature and afforded the corresponding β-amino carbonyl compounds in good to excellent yields and with moderate diastereoselectivity. This method provides a novel and improved modification of the three-component Mannich reaction in terms of mild reaction conditions and clean reaction profiles, using very a small quantity of catalyst and a simple workup procedure  

LncRNAs are involved in the modulation of several signaling pathways which have a crucial effect in the differentiation of periodontal ligament cells and the induction of cementum regeneration. Autophagy and Wnt signaling are two important pathways with a wide range of interrelationships associated with periodontitis. We chose four lncRNAs based on their potential interaction with these two pathways. We examined the expression of FOXD2-AS1, NNT-AS1, GAS8-AS1, and CCAT1 lncRNAs in tissues and blood specimens of patients with periodontitis and unaffected controls using qRT-PCR. Expression amounts of FOXD2-AS1 were lower in blood of cases compared with controls (relative expression (RE) = 0.08,...