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    Chemical kinetic modeling of i-butane and n-butane catalytic cracking reactions over HZSM-5 zeolite

    , Article AIChE Journal ; Volume 58, Issue 8 , 2012 , Pages 2456-2465 ; 00011541 (ISSN) Roohollahi, G ; Kazemeini, M ; Mohammadrezaee, A ; Golhosseini, R ; Sharif University of Technology
    2012
    Abstract
    A chemical kinetic model for i-butane and n-butane catalytic cracking over synthesized HZSM-5 zeolite, with SiO 2/Al 2O 3 = 484, and in a plug flow reactor under various operating conditions, has been developed. To estimate the kinetic parameters of catalytic cracking reactions of i-butane and n-butane, a lump kinetic model consisting of six reaction steps and five lumped components is proposed. This kinetic model is based on mechanistic aspects of catalytic cracking of paraffins into olefins. Furthermore, our model takes into account the effects of both protolytic and bimolecular mechanisms. The Levenberg-Marquardt algorithm was used to estimate kinetic parameters. Results from statistical... 

    Application of a simple lumped kinetic model for the catalytic cracking of normal butane over an HZSM-5 zeolite

    , Article CHISA 2012 - 20th International Congress of Chemical and Process Engineering and PRES 2012 - 15th Conference PRES ; 2012 Roohollahi, G ; Kazemeini, M ; Mohammadrezaee, A ; Golhosseinir, R ; Sharif University of Technology
    2012
    Abstract
    A simple lumped kinetic model was developed and applied in n-butane catalytic cracking over synthesized HZSM-5 zeolite with a SiO2/Al2 O3. Five lumped compounds, including n-butane, olefins, paraffins, methane, and heavy components were considered. Significance test and variance analysis were performed to check the validity of the kinetic model. The experimental data and calculated values as a function of n-butane contact time very satisfactorily. This is an abstract of a paper presented at the CHISA 2012 - 20th International Congress of Chemical and Process Engineering and PRES 2012 - 15th Conference PRES (Prague, Czech Republic 8/25-29/2012)  

    The joint reaction of methanol and i-butane over the HZSM-5 zeolite

    , Article Journal of Industrial and Engineering Chemistry ; Volume 19, Issue 3 , May , 2013 , Pages 915-919 ; 1226086X (ISSN) Roohollahi, G ; Kazemeini, M ; Mohammadrezaee, A ; Golhosseini, R ; Sharif University of Technology
    2013
    Abstract
    The effects of i-butane addition to methanol in MTP reaction were investigated over an in-house prepared HZSM-5 catalyst. It was observed that, propylene yield would be enhanced when i-butane fed to the reactor along with methanol. The rising growth of the propylene yield continued to peak on till the balance in thermal condition established. Similar trends have been observed when water was added to the mixture. The effect of WHSV with fixed water composition on product distribution was also studied. The optimum point where the highest amount of propylene yielded was shown to be high depended upon the temperature and residence time  

    Synthesis and Experimental Study of Nano-Carbon Adsorbent for Natural Gas Storage

    , M.Sc. Thesis Sharif University of Technology Roohollahi, Hossein (Author) ; Soltanieh, Mohammad (Supervisor) ; Rashidi, Ali Morad (Co-Advisor)
    Abstract
    The major obstacle in using natural gas as a clean and abundant fuel in transportation industries is the low density of energy obtained from its combustion. Adsorbed Natural Gas (ANG) is a useful method to increase the energy density and store the natural gas. The lower cost and higher safety have made it different from the other storage technologies. In addition, ANG can be useful to solve the lack of gas in the peak of consumption. Among all adsorbents, Activated Carbon (AC) has shown the highest adsorption capacity of natural gas. In the present project, walnut shell has been used as the precursor in the chemical synthesise of AC. The main effective factors in chemical activation, such as... 

    Modeling and Kinetic Study of the Transformation of C6- Paraffins Over Methanol to Olefin Catalyst

    , M.Sc. Thesis Sharif University of Technology Roohollahi, Gholamreza (Author) ; Kazemeini, Mohammad (Supervisor) ; Mohammad Rezaie, Alireza (Co-Advisor)
    Abstract
    Catalytic cracking of iso and normal butane over HZSM-5 at several temperatures and a variety of contact time and different partial pressures of hydrocarbon feed was conducted. Experiments indicate that the operating conditions have considerable effects on final product distribution and feed conversion. Results show that high temperatures, low contact time and partial pressure of paraffin feed favor the light olefin production, particularly propylene production. Results obtained for iso-butane show a similar conversion values in comparison to n-butane but a higher olefin and propylene selectivity. Finally kinetic modeling of both iso and normal butane cracking was performed based on a lump... 

    Calculation of the Energy Release Rate of Nano-Cracks in FCC Materials Via the Many Body Atomic Scale FEM

    , M.Sc. Thesis Sharif University of Technology Ostad Hossein, Alireza (Author) ; Mohammadi Shodja, Hossein (Supervisor)
    Abstract
    Since the classical continuum theory fails to deal with the problems associated with defects, stress concentrators, and relevant deformation phenomena in solids, alternative approaches that can detect the atomistic nature of materials' fracture are required. The deficiency of the capture the size effect which yields delusively high values for some components of the stress field right on the edge of the stress concentrators, and its weakness in describing the complex interaction between small inhomogeneities, cracks and the like when they are only a few nanometers apart, are among some of the disadvantages of the classical approach. In recent years, however, atomistic methods are emerging to... 

    Semisolid Stir Joining of As-Cast Silicon-Aluminum Bronze

    , M.Sc. Thesis Sharif University of Technology Ferasat, Keyvan (Author) ; Kokabi, Amir Hossein (Supervisor) ; Ashuri, Hossein (Supervisor)
    Abstract
    Aluminum Bronzes have many applications in marine environments. These alloys suffer from both hot cracking and cold cracking. In order to overcome the hot cracking and cold cracking, Semisolid Stir Joining method and a proper thermal cycle was used respectively. Effects of temperature, stirring rate, and tool type were investigated in Semisolid Stir joining method. In this method, butt joint design was used in order to place specimens, and the specimens were heated up to specific temperatures (920, 925, 930°C). A stirrer (Cylindrical and Grooved tool) with three rotational speeds (800, 1200, 1600 RPM) was introduced into the stir weld seam. Welded specimens were cooled to the 900°C... 

    The Study of Eliminating Gender Gap in Iran Labor Market on Participation Rate of Married Urban Women

    , M.Sc. Thesis Sharif University of Technology Asghari, Fatemeh (Author) ; Rahmati, Mohammad Hossein (Supervisor) ; Joshaghani, Hossein (Supervisor)
    Abstract
    The low female labor force participation rate in the Iranian labor market relative to the global average and even to countries that do not differ significantly from the socio-economic characteristics of our country is one of the important questions of the Iranian labor market. In this study, we seek to answer the question of whether the economic participation rate of married women will increase if the gender gaps in wages, job findings and job losses among women and men are eliminated in the Iranian labor market. To answer this question using household expenditure and income data and labor force data, we show that between the two categories of occupations, in terms of the share of women's... 

    Graph homomorphisms through random walks [electronic resource]

    , Article Journal of Graph Theory ; 2003, Volume 44, Issue 1, pages 15–38 Daneshgar, A. (Amir) ; Hajiabolhassan, Hossein ; Sharif University of Technology
    Abstract
    In this paper we introduce some general necessary conditions for the existence of graph homomorphisms, which hold in both directed and undirected cases. Our method is a combination of Diaconis and Saloff–Coste comparison technique for Markov chains and a generalization of Haemers interlacing theorem. As some applications, we obtain a necessary condition for the spanning subgraph problem, which also provides a generalization of a theorem of Mohar (1992) as a necessary condition for Hamiltonicity. In particular, in the case that the range is a Cayley graph or an edge-transitive graph, we obtain theorems with a corollary about the existence of homomorphisms to cycles. This, specially, provides... 

    Unique list-colourability and the fixing chromatic number of graphs [electronic resource]

    , Article Discrete Applied Mathematics ; Volume 152, Issues 1–3, 1 November 2005, Pages 123–138 Daneshgar, A. (Amir) ; Hajiabolhassan, Hossein ; Sharif University of Technology
    Abstract
    In this paper we introduce a chromatic parameter, called the fixing chromatic number, which is related to unique colourability of graphs, in the sense that it measures how one can embed the given graph G in G∪Kt by adding edges between G and Kt to make the whole graph uniquely t-colourable. We study some basic properties of this parameter as well as its relationships to some other well-known chromatic numbers as the acyclic chromatic number. We compute the fixing chromatic number of some graph products by applying a modified version of the exponential graph construction  

    Circular colouring and algebraic no-homomorphism theorems

    , Article European Journal of Combinatorics ; Volume 28, Issue 6, August 2007, Pages 1843–1853 Daneshgar, A. (Amir) ; Hajiabolhassan, Hossein ; Sharif University of Technology
    Abstract
    In this paper, we apply some new algebraic no-homomorphism theorems in conjunction with some new chromatic parameters to estimate the circular chromatic number of graphs. To show the applicability of the general results, as a couple of examples, we generalize a well known inequality for the fractional chromatic number of graphs and we also show that the circular chromatic number of the graph obtained from the Petersen graph by excluding one vertex is equal to 3. Also, we focus on the Johnson–Holroyd–Stahl conjecture about the circular chromatic number of Kneser graphs and we propose an approach to this conjecture. In this regard, we introduce a new related conjecture on Kneser graphs and we... 

    Density and power graphs in graph homomorphism problem

    , Article Discrete Mathematics ; Volume 308, Issue 17, 6 September 2008, Pages 4027–4030 Daneshgar, A. (Amir) ; Hajiabolhassan, Hossein ; Sharif University of Technology
    Abstract
    We introduce two necessary conditions for the existence of graph homomorphisms based on the concepts of density and power graph. As corollaries, we obtain a lower bound for the fractional chromatic number, and we set forward elementary proofs of the facts that the circular chromatic number of the Petersen graph is equal to three and the fact that the Coxeter graph is a core  

    Temperature dependence study of nonocontact AFM images using molecular dynamics simulations [electronic resource]

    , Article Int. Journal of Modern Physics ; 2012, Vol. 5, pp. 418-432 Nejat Pishkenari, H. (Hossein) ; Meghdar, Ali ; Sharif University of Technology
    Abstract
    The effect of temperature on the noncontact atomic force microscopy (NC-AFM) surface imaging is investigated with the aid of molecular dynamics (MD) analysis based on the Sutton-Chen (SC) interatomic potential. Particular attention is devoted to the tip and sample flexibility at different temperatures. When a gold coated probe is brought close to the Au (001) surface at high temperatures, the tip and surface atoms are pulled together and their distance becomes smaller. The tip and sample atoms displacement varies in the different environment temperatures and this leads to the different interaction forces. Along this line, to study the effect of temperature on the resulting images, we have... 

    Developing an Analytical Model for Predicting the Residual Stresses Induced by Shot Peening with Considering the Effect of Initial Surface Treatment

    , Ph.D. Dissertation Sharif University of Technology Sherafatnia, Khalil (Author) ; Farrahi, Gholam Hossein (Supervisor) ; Mahmoudi, Amir Hossein (Co-Supervisor)
    Abstract
    Shot peening is a cold-working process commonly used in industry to improve the fatigue performance, stress corrosion resistance and surface nano-crystallization of metallic parts. This process extends fatigue life via two mechanisms: Preventing the crack growth due to compressive residual stresses and, preventing the crack initiation because of increased material hardness. These mechanisms are the results of the bombardment of the component's surface with small spherical particles. In this research, an analytical model is developed for estimating the residual stress distribution induced by shot peening process. The modifications of the developed analytical model are related to... 

    Evaluating Reliability of SSDs Against Power Outage

    , M.Sc. Thesis Sharif University of Technology (Author) ; Asadi, Hossein (Supervisor)
    Abstract
    Solid-State Drives (SSDs) provide high performance, low power consumption, and hence are widely used in the I/O cache of enterprise storage systems and high performance servers. Although employing high performance SSDs in the I/O cache of storage systems significantly improves system performance, it comes with significant reliability threats for write operations upon power failures. In order to provide high level of reliability, storage architectures employ SSDs in I/O cache with RAID-1 configuration, however, such configuration only partially mitigates the reliability issues of the SSDs. In this thesis, we analyze the reliability of SSD-based I/O caches against power outage and high... 

    On the isoperimetric spectrum of graphs and its approximations [electronic resource]

    , Article Journal of Combinatorial Theory, Series B ; Volume 100, Issue 4, July 2010, Pages 390–412 Daneshgar, A. (Amir) ; Hajiabolhassan, Hossein ; Javadi, Ramin ; Sharif University of Technology
    Abstract
    In this paper1 we consider higher isoperimetric numbers of a (finite directed) graph. In this regard we focus on the nth mean isoperimetric constant of a directed graph as the minimum of the mean outgoing normalized flows from a given set of n disjoint subsets of the vertex set of the graph. We show that the second mean isoperimetric constant in this general setting, coincides with (the mean version of) the classical Cheeger constant of the graph, while for the rest of the spectrum we show that there is a fundamental difference between the nth isoperimetric constant and the number obtained by taking the minimum over all n-partitions. In this direction, we show that our definition is the... 

    Optimal Trajectory Planning for Flight through Microburst Wind Shears

    , M.Sc. Thesis Sharif University of Technology Kiani, Maryam (Author) ; Pourtakdoost, Hossein (Supervisor)
    Abstract
    An optimal trajectory for flight through Microburst wind shears is designed which minimizes the maximum deviation from desired trajectory With respect to optimal control methods. The suitable performance of airplane retrieval in abort landing and landing phases at microburst encounter is achieved by influence of mentioned design in worse case of wind fluctuation and variation. 3D Vicroy microburst model is selected to investigate its effects on 6 DOF jet engine aircraft EOMs. Above optimal control problem is solved using gradient method of SD . Furthermore, sensitivity of optimal trajectory to lateral and longitudinal location of microburst, microburst parameters, throttle setting and... 

    Solving the Bus Rapid Transit Network Design Problem with Ant System Algorithm (in Realistic Urban Network)

    , M.Sc. Thesis Sharif University of Technology Kishani, Najme (Author) ; Poorzahedy, Hossein (Supervisor)
    Abstract
    Network design problem (NDP) is an important problem in transportation planning, in which transit network design is one the most important problems. Public transportation means, however, can not meet urban mobility needs in the developing countries satisfactorily. Bus services are usually unsuitable, insufficient, and unreliable. Bus Rapid Transit (BRT) system, is an emerging public transport alternative designed to provide appropriate, low cost, and effective services, and improve mobility in both developed and developing countries. To design public transportation systems, existing constraints such as resources and budget have to be considered to serve estimated demand properly. Bus Rapid... 

    Design of a Smart Algorithm Based on Two Dimensional Wavelet Transformation for Detection and Classification of Power Quality Disturbances

    , M.Sc. Thesis Sharif University of Technology Mollayi, Nader (Author) ; Mokhtari, Hossein (Supervisor)
    Abstract
    Power Quality can be simply defined as the quality of voltage at electrical loads. Detection and classification of voltage and current disturbances is of high importance in power system protection and monitoring. This procedure cannot be implemented by operators because of the high volume of the data which must be processed. So, it is needed to automate this procedure. Systems designed for this purpose usually contain three main parts: feature generation, feature selection and classifier design. The algorithms used for feature generation for power quality disturbances are mainly based on discrete Fourier transformation or discrete wavelet transformation. These approaches have shown some...