Sharif Digital Repository

During preliminary investigation phase of the national Chabahar-Zahedan railway line, serious geotechnical problems including non-uniform settlements, tensile cracks, and local collapse were reported in parts of the path near the coastline. A follow-up field investigation revealed that the in-situ soil at construction site has a metastable structure being sensitive to saturation and loading. Therefore, a comprehensive series of physical, chemical, electro-chemical, and geotechnical tests were conducted to classify and characterize the soil properties and behavior in its natural state. The natural soil was classified as a clayey loess with moderately dispersive to dispersive characteristics.... 

Infinite series solutions are obtained for electrical potential, electroosmotic velocity, ionic conductance, and surface physicochemical properties of long pH-regulated rectangular nanochannels of low surface potential utilizing the double finite Fourier transform method. Closed form expressions are also obtained for channels of large height to width ratio for which the depthwise variations vanish. Neglecting the Stern layer impact, the effects of EDL (Electric Double Layer) overlap, multiple ionic species, and association/dissociation reactions on the surface are all taken into account. Moreover, finite-element-based numerical simulations are conducted to account for the end effects as well... 

The polysaccharide, kappa-carrageenan (κC) was chemically modified to achieve a novel superabsorbent hydrogel via graft copolymerization of methacrylamide (MAM) onto the substrate followed by alkaline hydrolysis. Ammonium persulfate (APS) and N,N′-methylene bisacrylamide (MBA) were used as a free-radical initiator and a crosslinker, respectively. The saponification reaction was carried out using sodium hydroxide aqueous solution. Either κC-g-PMAM or hydrolyzed κC-g-PMAM (PMAM: polymethacrylamide) was characterized by FT-IR spectroscopy. The effect of grafting variables (i.e. concentration of MBA, MAM, and APS) and alkaline hydrolysis conditions (i.e. NaOH concentration, hydrolysis time and... 

As the first part of a continued research on conversion of carboxymethyl cellulosesodium salt (CMC) to useful biopolymer-based materials, large numbers of cyanide functional groups were introduced onto CMC by grafting with polyacrylonitrile (PAN). The graft copolymerization reactions were carried out under nitrogen atmosphere using ceric ammonium nitrate (CAN) as an initiator. Evidence of grafting was obtained by comparing FTIR spectra of CMC and the graft copolymer as well as solubility characteristics of the products. The synthetic conditions were systematically optimized through studying the effective factors including temperature and concentrations of initiator, acrylonitrile monomer,... 

Semi-analytical solutions are obtained for the electrical potential, electroosmotic velocity, ionic conductance, and surface physicochemical properties associated with long pH-regulated nanochannels of arbitrary but constant cross-sectional area. The effects of electric double layer overlap, multiple ionic species, and surface association/dissociation reactions are all taken into account, assuming low surface potentials. The method of analysis includes series solutions which the pertinent coefficients are obtained by applying the wall boundary conditions using either of the least-squares or point matching techniques. Although the procedure is general enough to be applied to almost any... 

The dispersion of a neutral solute band by electrokinetic flow in polyelectrolyte layer (PEL)-grafted rectangular/slit microchannels is theoretically studied. The flow is assumed to be both steady and fully developed and a first-order irreversible reaction is considered at the wall to account for probable surface adsorption of solutes. Considering low electric potentials, analytical solutions are obtained for electric potential, fluid velocity and solute concentration. Special solutions are also obtained for the case without wall adsorption. To track the dispersion properties of the solute band, the generalized dispersion model is adopted by considering the exchange, the convection and the... 

A new type of collapsible soil was encountered in Southern Iran and caused some serious technical problems including subsidence, collapse and sinkholes during the construction of Zahedan-Chabahar railway. Field observations indicated that in-situ soil contains excessive amount of salts resulting in dispersive features in response to seepage forces in addition to its collapsibility. Therefore, a systematic research plan including field sampling and laboratory testing was carried out to investigate the observed geotechnical features. Results of physio-chemical tests revealed the dominance of Sodium in excess of 70% relative to total dissolved salts, which results in high dispersive potential.... 

Dielectrophoresis (DEP) is an electrokinetic phenomenon which is used for manipulating micro- and nanoparticles in micron-sized devices with high sensitivity. In recent years, electrode-based DEP by patterning narrow oblique electrodes in microchannels has been used for particle manipulation. In this theoretic study, a microchannel with triangular electrodes is presented and a detailed comparison with oblique electrodes is made. For each shape, the behavior of particles is compared for three different configurations of applied voltages. Electric field, resultant DEP force, and particle trajectories for configurations are computed by means of Rayan native code. The separation efficiency of... 

This paper presents a bi-objective VMI problem in a single manufacturer-single vendor multi-retailer (SM-SV-MR) supply chain, which a redundancy allocation problem is incorporated. In the hybridized problem, a manufacturer produces a single item using several machines that work in series, and stores it in a warehouse to replenish one vendor who delivers it to several retailers using the shortest possible route. A novel meta-heuristic, called hybrid bat algorithm (HBA), with calibrated parameters is utilized to find a near-optimum solution. To show the efficiency of HBA, the results are compared to the ones using the traditional BA and a genetic algorithm  

The vendor-managed inventory (VMI) is a common policy in supply chain management (SCM) to reduce bullwhip effects. Although different applications of VMI have been proposed in the literature, the multi-vendor multi-retailer single-warehouse (MV-MR-SW) case has not been investigated yet. This paper develops a constrained MV-MR-SW supply chain, in which both the space and the annual number of orders of the central warehouse are limited. The goal is to find the order quantities along with the number of shipments received by retailers and vendors such that the total inventory cost of the chain is minimized. Since the problem is formulated into an integer nonlinear programming model, the... 

In this paper, a multi-item economic production quantity model with fuzzy demand is developed in which shortages are backordered and the warehouse space is limited. While the demand is assumed to be a trapezoidal fuzzy number, the centroid defuzzification method is used to defuzzify fuzzy output functions. The Lagrangian relaxation procedure is first employed to solve the problem. Then, the model is extended to a constrained fuzzy integer nonlinear programming, in order to suit real-world situations. As the extended model cannot be solved in a reasonable time using exact methods, two meta-heuristic algorithms, named the genetic algorithm (GA) and the particle swarm optimisation (PSO) each... 

Carboxymethylcellulose sodium salt (CMC) was doubly modified to prepare a novel poly(acrylamidoxime) chelating resin. Acrylonitrile was firstly graft polymerized onto CMC using cerium ammonium nitrate as an initiator. The polyacrylonitrile (PAN) grafted CMC was then amidoximized via treatment with hydroxylamine to prepare the ion exchange resin. The sorption capacity of the resin towards bivalent metal ions was evaluated while varying the pH, the loading of the PAN and the initial metal ion concentration. The adsorption kinetics were investigated for the cupric ion. The chelating resin exhibited very high metal sorption capacity in comparison with either synthetic or polysaccharide-based... 

The purpose of this study is to investigate production of high quality ammonium uranyl carbonate (AUC) from “uranyl nitrate + ammonium bicarbonate”, or “uranyl nitrate + sodium carbonate” precursor solutions, by controlled injection of ammonium carbonate solution which could be applicable in material testing reactor (MTR) fuel production plant for recycling of rejected uranium oxide powder. The experimental observations revealed: at pHs higher than 6, precipitation proceeds with formation of no intermediate, thus ensuing a better morphology and size distribution of the AUC products. The results of scanning electron microscopy, X-ray diffraction, particle size analysis, and uranium content... 

The present investigation is devoted to the fully developed slip flow mixed convection in vertical microducts of two different cross sections, namely, polygon, with circle as a limiting case, and rectangle. The two axially constant heat flux boundary conditions of H1 and H2 are considered in the analysis. The velocity and temperature discontinuities at the boundary are incorporated into the solutions using the first-order slip boundary conditions. The method considered is mainly analytical in which the governing equations in cylindrical coordinates along with the symmetry conditions and finiteness of the flow parameter at the origin are exactly satisfied. The first-order slip boundary... 

Acoustically excited lean premixed low-swirl flames were experimentally investigated to gain a better understanding of detrimental thermoacoustic couplings which can occur in applications like low-NOx gas turbines. Propane-air flames were imaged and analyzed at equivalence ratios of 0.6 to 0.8, mean flow velocities of 3.5 to 5.5 m/s and excitation frequencies of 135 Hz to 555 Hz. It was observed that with increasing excitation frequency, mean flame shape gradually became wider up to a Strouhal number of about 2.5 and then slowly reverted back to the unexcited flame shape. Such large changes in mean flame shape and possibly flow field under acoustic excitations can significantly affect flame... 

This is a theoretical study dealing with longitudinal gaseous slip flow forced convection between a periodic bunch of microcylinders arranged in regular array. The selected geometry has applications in microscale pin fin heat sinks used for cooling of microchips. The flow is considered to be hydrodynamically and thermally fully developed. The two axially constant heat flux boundary conditions of H1 and H2 are considered in the analysis. The velocity and temperature discontinuities at the boundary are incorporated into the solutions using the first order slip boundary conditions. The method considered is mainly analytical in which the governing equations and three of the boundary conditions... 

The present investigation considers the fully developed electro-osmotic flow of power-law fluids in a planar microchannel subject to constant wall heat fluxes. Using an approximate velocity distribution, closed form expressions are obtained for the transverse distribution of temperature and Nusselt number. The approximate solution is found to be quite accurate, especially for the values of higher than ten for the dimensionless Debye-Huckel parameter where the exact values of Nusselt number are predicted. The results demonstrate that a higher value of the dimensionless Debye-Huckel parameter is accompanied by a higher Nusselt number for wall cooling, whereas the opposite is true for wall... 

The issue of entropy generation in laminar forced convection of a Newtonian fluid through a slit microchannel is analytically investigated by taking the viscous dissipation effect, the slip velocity and the temperature jump at the wall into account. Flow is considered to be hydrodynamically fully developed but thermally developing. The energy equation is solved by means of integral transform. The results demonstrate that to increase Knudsen number is to decrease entropy generation, while the effect of increasing values of Brinkman number and the group parameter is to increase entropy generation. Also it is disclosed that in the thermal entrance region the average entropy generation number... 

Engineering, procurement and construction (EPC) contracts are commonly used for the construction of oil and gas production facilities. These projects are subjected to many uncertainties. EPC contractors often assume most of the project risks. Several studies have focused on the identification and analysis of EPC project risks. However, they generally fail to define appropriate and effective risk management strategies. The objective of this study is to define efficient risk mitigation strategies that can be utilized in EPC oil and gas projects. A comprehensive review of literature was conducted to identify the risks in EPC projects. Experts' opinion were used to analyze and categorize these... 

Natural soils contain a certain amount of salt in the form of dissolved ions or electrically charged atoms, originated from the long-term erosion by acidic rainwater. The dissolved salt poses an extra osmotic water potential being normally neglected in laboratory measurements and numerical analyses. However, ignorance of salinity may result in overestimation of stability, and the design may not be as conservative as thought. Therefore, this research aims to first experimentally examine the influence of pore water salinity on water retention curve and saturated permeability of natural dispersive loess under saline and desalinated conditions. Second, the measured parameters are used for...