Sharif Digital Repository

The polysaccharide, kappa-carrageenan (κC) was chemically modified to achieve a novel superabsorbent hydrogel via graft copolymerization of methacrylamide (MAM) onto the substrate followed by alkaline hydrolysis. Ammonium persulfate (APS) and N,N′-methylene bisacrylamide (MBA) were used as a free-radical initiator and a crosslinker, respectively. The saponification reaction was carried out using sodium hydroxide aqueous solution. Either κC-g-PMAM or hydrolyzed κC-g-PMAM (PMAM: polymethacrylamide) was characterized by FT-IR spectroscopy. The effect of grafting variables (i.e. concentration of MBA, MAM, and APS) and alkaline hydrolysis conditions (i.e. NaOH concentration, hydrolysis time and... 

Semi-analytical solutions are obtained for the electrical potential, electroosmotic velocity, ionic conductance, and surface physicochemical properties associated with long pH-regulated nanochannels of arbitrary but constant cross-sectional area. The effects of electric double layer overlap, multiple ionic species, and surface association/dissociation reactions are all taken into account, assuming low surface potentials. The method of analysis includes series solutions which the pertinent coefficients are obtained by applying the wall boundary conditions using either of the least-squares or point matching techniques. Although the procedure is general enough to be applied to almost any... 

The dispersion of a neutral solute band by electrokinetic flow in polyelectrolyte layer (PEL)-grafted rectangular/slit microchannels is theoretically studied. The flow is assumed to be both steady and fully developed and a first-order irreversible reaction is considered at the wall to account for probable surface adsorption of solutes. Considering low electric potentials, analytical solutions are obtained for electric potential, fluid velocity and solute concentration. Special solutions are also obtained for the case without wall adsorption. To track the dispersion properties of the solute band, the generalized dispersion model is adopted by considering the exchange, the convection and the... 

Infinite series solutions are obtained for electrical potential, electroosmotic velocity, ionic conductance, and surface physicochemical properties of long pH-regulated rectangular nanochannels of low surface potential utilizing the double finite Fourier transform method. Closed form expressions are also obtained for channels of large height to width ratio for which the depthwise variations vanish. Neglecting the Stern layer impact, the effects of EDL (Electric Double Layer) overlap, multiple ionic species, and association/dissociation reactions on the surface are all taken into account. Moreover, finite-element-based numerical simulations are conducted to account for the end effects as well... 

As the first part of a continued research on conversion of carboxymethyl cellulosesodium salt (CMC) to useful biopolymer-based materials, large numbers of cyanide functional groups were introduced onto CMC by grafting with polyacrylonitrile (PAN). The graft copolymerization reactions were carried out under nitrogen atmosphere using ceric ammonium nitrate (CAN) as an initiator. Evidence of grafting was obtained by comparing FTIR spectra of CMC and the graft copolymer as well as solubility characteristics of the products. The synthetic conditions were systematically optimized through studying the effective factors including temperature and concentrations of initiator, acrylonitrile monomer,... 

Dielectrophoresis (DEP) is an electrokinetic phenomenon which is used for manipulating micro- and nanoparticles in micron-sized devices with high sensitivity. In recent years, electrode-based DEP by patterning narrow oblique electrodes in microchannels has been used for particle manipulation. In this theoretic study, a microchannel with triangular electrodes is presented and a detailed comparison with oblique electrodes is made. For each shape, the behavior of particles is compared for three different configurations of applied voltages. Electric field, resultant DEP force, and particle trajectories for configurations are computed by means of Rayan native code. The separation efficiency of... 

A new type of collapsible soil was encountered in Southern Iran and caused some serious technical problems including subsidence, collapse and sinkholes during the construction of Zahedan-Chabahar railway. Field observations indicated that in-situ soil contains excessive amount of salts resulting in dispersive features in response to seepage forces in addition to its collapsibility. Therefore, a systematic research plan including field sampling and laboratory testing was carried out to investigate the observed geotechnical features. Results of physio-chemical tests revealed the dominance of Sodium in excess of 70% relative to total dissolved salts, which results in high dispersive potential.... 

Carboxymethylcellulose sodium salt (CMC) was doubly modified to prepare a novel poly(acrylamidoxime) chelating resin. Acrylonitrile was firstly graft polymerized onto CMC using cerium ammonium nitrate as an initiator. The polyacrylonitrile (PAN) grafted CMC was then amidoximized via treatment with hydroxylamine to prepare the ion exchange resin. The sorption capacity of the resin towards bivalent metal ions was evaluated while varying the pH, the loading of the PAN and the initial metal ion concentration. The adsorption kinetics were investigated for the cupric ion. The chelating resin exhibited very high metal sorption capacity in comparison with either synthetic or polysaccharide-based... 

This paper presents a bi-objective VMI problem in a single manufacturer-single vendor multi-retailer (SM-SV-MR) supply chain, which a redundancy allocation problem is incorporated. In the hybridized problem, a manufacturer produces a single item using several machines that work in series, and stores it in a warehouse to replenish one vendor who delivers it to several retailers using the shortest possible route. A novel meta-heuristic, called hybrid bat algorithm (HBA), with calibrated parameters is utilized to find a near-optimum solution. To show the efficiency of HBA, the results are compared to the ones using the traditional BA and a genetic algorithm  

The vendor-managed inventory (VMI) is a common policy in supply chain management (SCM) to reduce bullwhip effects. Although different applications of VMI have been proposed in the literature, the multi-vendor multi-retailer single-warehouse (MV-MR-SW) case has not been investigated yet. This paper develops a constrained MV-MR-SW supply chain, in which both the space and the annual number of orders of the central warehouse are limited. The goal is to find the order quantities along with the number of shipments received by retailers and vendors such that the total inventory cost of the chain is minimized. Since the problem is formulated into an integer nonlinear programming model, the... 

In this paper, a multi-item economic production quantity model with fuzzy demand is developed in which shortages are backordered and the warehouse space is limited. While the demand is assumed to be a trapezoidal fuzzy number, the centroid defuzzification method is used to defuzzify fuzzy output functions. The Lagrangian relaxation procedure is first employed to solve the problem. Then, the model is extended to a constrained fuzzy integer nonlinear programming, in order to suit real-world situations. As the extended model cannot be solved in a reasonable time using exact methods, two meta-heuristic algorithms, named the genetic algorithm (GA) and the particle swarm optimisation (PSO) each... 

Natural soils contain a certain amount of salt in the form of dissolved ions or electrically charged atoms, originated from the long-term erosion by acidic rainwater. The dissolved salt poses an extra osmotic water potential being normally neglected in laboratory measurements and numerical analyses. However, ignorance of salinity may result in overestimation of stability, and the design may not be as conservative as thought. Therefore, this research aims to first experimentally examine the influence of pore water salinity on water retention curve and saturated permeability of natural dispersive loess under saline and desalinated conditions. Second, the measured parameters are used for... 

We provide an efficient ready-to-run code gensaw that generates single or large ensembles of self-avoiding, flexible, semiflexible, rotationally isometric or helical chains in the bulk or subject to arbitrary confinement and tethering conditions, where we allow for arbitrary intramolecular bending and dihedral energy functions. The resulting configuration files are provided in various common formats and can be immediately used to do molecular simulations or statistical analysis. We work out analytic expressions for the mean squared end-to-end distance and gyration radius of the semiflexible, helical and rotational isomeric state models with a finite number of bonds and arbitrary interaction... 

Several lattice Boltzmann models for multi-phase flow have been developed, but few of them are capable of modeling fluid flows with high density ratio in the order of 1000. Therefore, an advanced chromodynamics, Rothmann-Keller (RK) type model is employed in current study, which can handle liquid-gas density ratio in the order of 1000 and viscosity ratio in the order of 100. Other distinctive characteristics of the proposed model are high stability, and capability of setting parameters such as surface tension independently. In spite of these benefits, the original RK model fails to model wetting tendency of the fluids. As a result, it is impossible to correctly simulate two-fluid phase flow... 

During preliminary investigation phase of the national Chabahar-Zahedan railway line, serious geotechnical problems including non-uniform settlements, tensile cracks, and local collapse were reported in parts of the path near the coastline. A follow-up field investigation revealed that the in-situ soil at construction site has a metastable structure being sensitive to saturation and loading. Therefore, a comprehensive series of physical, chemical, electro-chemical, and geotechnical tests were conducted to classify and characterize the soil properties and behavior in its natural state. The natural soil was classified as a clayey loess with moderately dispersive to dispersive characteristics.... 

To study of vibration effect on fluidization behaviour of high moisture materials, a laboratory vibro-fluidized bed dryer was designed and fabricated. The blower was selected based on transferring velocity of particles and pressure drop caused by airflow through the bedplate and the channels. It was centrifugal type with backward blades, static pressure of 3.5 kPa, flow rate of 0.4 m 3/s and impeller diameter of 0.4 m. The dryer was constructed with 4.9 kW electrical heater capacity, bed plate with holes diameter of I mm and 140626 holes/m 2. The dryer chamber was made of Plexiglass with 0.16×0.16 m square section and 0.5 m height The bedplate was vibrated mechanically, which was adjustable... 

The bio-microfluidic systems are usually encountered with non-Newtonian behaviors of working fluids. The rheological behavior of some bio-fluids can be described by differential viscoelastic constitutive equations that are related to PTT and FENE-P models. In the present work, thermal transport characteristics of the steady fully developed electroosmotic flow of these fluids in a slit microchannel with constant wall heat fluxes have been investigated. The Debye-Huckel linearization is adopted and the effects of viscous dissipation and Joule heating are taken into account. Analytical solutions are obtained for the transverse distributions of velocity and temperature and finally for Nusselt... 

Carbon nanotubes (CNTs) decorated with Cu2O particles were grown on a Ni catalyst layer deposited on a Cu substrate by thermal chemical vapor deposition from liquid petroleum gas. Ni catalyst nanoparticles with different sizes were produced in an electroplating system at 45 °C using the corrosive effect of H2SO4 which was added to solution. These nanoparticles provide the nucleation sites for CNT growth avoiding the need for a buffer layer. The surface morphology of the Ni catalyst films and CNT growth over this catalyst was studied by scanning electron microscopy (SEM). High temperature surface segregation of the Cu substrate into the Ni catalyst layer and its exposition to O2 at... 

Facial expression recognition is a challenging and interesting problem in computer vision and pattern recognition. Geometric variability in both emotion expression and neutral face is a fundamental challenge in facial expression recognition problem. This variability not only directly affects geometric facial expression recognition methods, but also is a critical problem in appearance methods. To overcome this problem, this paper presents an approach which eliminates geometric variability in emotion expression; thus, appearance features can be accurately used for facial expression recognition. Therefore, a fixed geometric model is used for geometric normalization of facial images. This model... 

In the present study, the thermal characteristics of electroosmotic flow of power-law fluids in rectangular microchannels in the presence of pressure gradient are investigated. The governing equations for fully developed flow under H1 thermal boundary conditions are first made dimensionless and subsequently solved through a finite difference procedure for a non-uniform grid. The influence of the major parameters on thermal features of the flow such as the temperature distribution and Nusselt number is discussed by a complete parametric study. The results reveal that the channel aspect ratio and the non-Newtonian characteristic of the fluid can affect the thermal behavior of the flow. It is...