Sharif Digital Repository

Aromatic aldehydes and ketones are readily acetalized or ketalized under microwave irradiation in the presence of water as a solvent  

A four-step synthetic strategy was applied to achieve novel methacrylic monomers. 5-Norbornene-2,2-dimethanol was prepared from a Diels–Alder reaction of cyclopentadiene and acrolein, followed by the treatment of the adduct with an HCHO/KOH/MeOH solution. The resulting 1,3-diol (1) was then acetalized with different aromatic aldehydes having OH groups on the ring to produce four spiroacetal derivatives. The reaction of methacryloyl chloride with the phenolic derivatives led to four new methacrylic monomers that were identified spectrochemically (mass, FTIR, 1H-NMR, and 13C-NMR spectroscopy). Free radical solution polymerization was used to prepare novel spiroacetal–norbornene containing... 

In this study, dissimilar friction stir welding was performed between AA5052 aluminium and AZ31 magnesium alloys using a variety of parameters. The results revealed that the optimal range of welding parameter is between 20 and 38 rpm/mm.min−1 (the ratio of rotation speed to travel speed). The findings of the X-ray diffraction and Micro-hardness tests on the stir zone indicated that when the rotation speed is increased, it leads to the formation of intermetallic compounds such as Al12Mg17 and Al3Mg2. The polarization test was used to assess the corrosion rate in various zones. The corrosion rate in the stir zone is higher than in other zones due to macro-galvanic couple between Al and Mg.... 

We introduce hyper-D-width and hyper-T-width as the first stable (see Definition 3) measures of connectivity for hypergraphs. After studying some of their properties and, in particular, proposing an algorithm for computing nearly optimal hyper-T-decomposition when hyper-T-width is constant, we introduce some applications of hyper-D-width and hyper-T-width in solving hard problems such as minimum vertex cover, minimum dominating set, and multicut  

A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition  

The interaction of dislocation with strengthening particles, including primary and secondary γ′, during different stages of creep of Rene-80 was investigated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). During creep of the alloy at 871 °C under stress of 290 MPa, the dislocation network was formed during the early stages of creep, and the dislocation glide and climb process were the predominant mechanism of deformation. The density of dislocation network became more populated during the later stages of the creep, and at the latest stage of the creep, primary particles shearing were observed alongside with the dislocation glide and climb. Shearing of γ′... 

The main contribution of this paper is utilizing bio-inspired evolutionary algorithm for reliability oriented high level synthesis. In this paper genetic algorithm is used to schedule a data-flow graph considering latency and resource allocation considering resource constraints and area overhead. Then a co-evolutionary strategy merges the results of these solutions to find the RT level design of the circuit which satisfies both performance and area constraints. To satisfy the user-defined reliability, another genetic algorithm is developed to insert some hardware redundancies to the resulted data-path. Experimental results show using the proposed approach results in an acceptable reliability... 

Rene-80, as an alloy for production of the jet turbine blades, shows high mechanical properties as well as microstructure stability during the high temperature engine operation. In this study we tried to have a deep insight on the microstructure of the cast Rene-80 and the evolution of microstructure during the different stages of the relatively complex GE class-A heat treatment. Although the solution heat treatment homogenized the chemical alloy segregation resulted from the casting to some extent, it did not cause all the casting γ′ particles to dissolve completely in the matrix. Primary aging caused growth in the residue particles as well as growth of the new precipitated particles, which... 

Mood disorders are the leading cause of disability worldwide and their incidence has significantly increased after the COVID-19 pandemic. Despite the continuous surge in the number of people diagnosed with psychiatric disorders, the treatment methods for these conditions remain limited. A significant number of people either do not respond to therapy or discontinue the drugs due to their severe side effects. Therefore, alternative therapeutic interventions are needed. Previous studies have shown a correlation between immunological alterations and the occurrence of mental health disorders, yet immunomodulatory therapies have been barely investigated for combating psychiatric conditions. In...