Sharif Digital Repository

ZnO nano particles and mordnite zeolite nano particles were prepared by precipitation method and hydrothermal method,respectively. The influence of solvent and surfactant in ZnO nano particles synthesis were studied to reform the structure of nano particles.These nano particles were based on different supports to improve and enhance their photocatalytic activities. Synthesized catalysts characterized by X-ray diffraction (XRD), Scanning electron microscopy (SEM), Fourier transform-infra red spectra (FTIR), UV-Vis spectroscopy and BET techniques. To investigated photocatalytic activity of the synthesized catalysts under UV irradiation, they were used to degradation bio-environmental... 

In this thesis, we aim to study the elastic-plastic behavior of short fiber reinforced composites experimentally and analytically. The experimental investigation is applied to glass fiber-polypropylene composites (PP/GF). The samples are produced by injection process with maximum temperature of 190C. Fibers are randomly oriented in this procedure of fabrication. The samples are tested in tension, and the mechanical strength is measured by changes in fiber content. The Young's modulus is also investigated in these experiments.Also in this thesis, an analytical model for calculation of Young’s modulus of fiber reinforced composite materials is proposed. In this analysis a displacement field is... 

Green chemistry seeks to reduce or eliminate the use of hazardous substances in the chemical industry through the development of new products and processes .The replacement of harmful, widely used solvents and reagents is a key part of this approach. Supercritical fluid such as CO2 or water are good solvent for replaceement Exchange reactions involving the displacement of hydrogen bonded to carbon by deuterium are of interest in a broad variety of disciplines, such as the preparative chemistry of isotopically labeled materials, fundamental studies of carbonehydrogen bond activation processes, and studies of the nature of catalysts. The low cost of water and its environmental friendliness... 

Natural products obtained from plant extract are well known as a valuable source for research and assessments which eventuates to the discovery of some compounds possessing biological and pharmacological properties. Our aims have been to investigate and identify some natural products having the ability to effect on protein misfolding. In neurodegenerative disorders, like Alzheimer’s and Parkinson’s, a protein or a peptide undergoes conformational changes, and consequently the protein transform to fibrils coined amyloid. To determine the effective anti-amyloid compounds in natural products, Borage leaves was chosen. The plant extract was extracted using soxhlet and applied to hen white egg... 

Cleanrooms have been widely used in many industries. The main goal in designing a clean space is to control the level of particles concentration. As a result, introduction, generation, and retention of airborne particles inside the environment need to be minimized. In this research, the effects of main parameters on the generation and deposition of particles through cleanrooms have been numerically investigated. At first, the role of geometric features of swirl diffusers on the induction effect and the resultant air mixing has been evaluated. Using parametric study approach, the diffuser geometry has been optimized and sensitivity of its optimum features to the airflow rate has been... 

High-quality online services demand reliable and fast packet delivery at the network layer. However, clear evidence documents the existence of compromised routers in the ISP and enterprise networks, threatening network availability and reliability. A compromised router can stealthily drop, modify, inject, or delay packets in the forwarding path to launch Denial-of-Service, surveillance, man-in-the-middle attacks, etc. So researches tried to create intrusion detection methods to identify adversarial routers and switches. To this end, data-plane fault localization (FL) aims to identify faulty links and is an effective means of achieving high network availability. FL protocols use... 

Confining nematic liquid crystal between two curved boundary conditions while the nematic molecules have a degenerate planar anchoring leads to complex and beautiful textures of molecular disparagement(defect) in the bulk and on the surfaces. Such the liquid crystal shells are made with double-emulsion techniques in microfluidic devices have provided applications for micro-scale colloidal linkers.In this work, we have numerically minimized the elastic energy in one-constant approximation in present of Fournier’s degenerate surface potential with finite element method. The nematic shell is confined between two spherical surfaces that we have studied the final energies and their related... 

Trolling mode atomic force microscope (TR-AFM) significantly reduces the hydrodynamic drag generated during operation in liquid environments. This is achieved by utilizing a long nanoneedle and keeping the cantilever out of liquid. In this research, a continuous mathematical model is developed to study TR-AFM dynamics near a sample submerged in the liquid. Effects of cantilever torsion, nanoneedle flexibility, and liquid-nanoneedle interactions are considered in the model. The finite element model of the TR-AFM resonator considering the effects of fluid and nanoneedle flexibility is presented in this research, for the first time. The model is verified by ABAQUS software. The effect of... 

A liquid crystal is a state of matter composed of highly anisotropic building blocks. When liquid crystals are exposed to surfaces with given shapes and anchoring conditions, the orientation of their molecules gets spatially disordered and topological defects may form in the system. The interplay between liquid crystals and the geometry and topology of the colloidal particles has motivated extensive recent studies.In this thesis, we present the numerical modeling results for two faceted colloidal particles in a thermotropic nematic liquid crystal. To obtain the equilibrium nematic field with a finiteelement method, we numerically minimize the free energy of the system that based on the... 

Providing high bandwidth network infrastructures for ever increasing need of data transport is of great importance. The underling infrastructure for many communication services such as GSM/3G/4G mobile networks and Internet services is Synchronous Digital Hierarchy (SDH) optical transport systems. SDH are standardized protocols that multiplex multiple lower rate digital bit streams, such as E1 and Ethernet, and transfer them synchronously over optical fiber using lasers or LEDs. In addition to high data transfer rates, flexible network management and protection mechanisms have great importance, hence are part of SDH standards. In order to obtain flexible network architecture and protected... 

Development of Smart Grid and deployment of smart meters in large scale has raised a lot of concerns regarding customers’ privacy. Consequently, several schemes have been proposed to overcome the above mentioned issue. These schemes mainly rely on data aggregation as a method of protecting users’ privacy from the grid operators. However, the main problem with most of these schemes is the fact that they require a large amount of processing power at the meter side. This, together with the fact that smart meters don’t usually have a powerful processor, can cause the unavailability of smart meter data at the required time for operators of the grid, and at the same time disables smart meters from... 

Secure routing is a major key to service maintenance in wireless ad hoc networks. Ad hoc nature exposes the network to several types of node misbehavior or attacks. Wormhole attack is one of the most severe active attacks to mobile ad hoc networks. Noting the resource limitations in such networks, nodes may have a tendency to behave selfishly. Selfish behavior can have drastic impacts on network performance. We have proposed a Misbehavior-Tolerant Multipath Routing protocol (MTMR) which detects and punishes all types of misbehavior such as selfish behavior, wormhole, sinkhole and grey-hole attacks. The protocol utilizes a proactive approach to enforce cooperation. In addition, it uses a... 

Dynamic spectrum access with the aid of cognitive radio (CR) technology is a viable solution to spectrum scarcity. There are many military and emergency applications that require the use of cognitive radio ad-hoc networks (CRAHNs). In these net- works, nodes must first find each other in a wide spectrum and then exchange their desired data. The process of finding each other in a multichannel environment is a challenging task and is usually known as rendezvous. Since rendezvous is the first step in communication, disrupting will disable the nodes from establishing proper communication sessions. That results in a drastic degrade in the performance of the network. Therefore, it is important to... 

Spray-wall impingement is one of the phenomenon that associated in different subject such as spray cooling, combustion chamber and gas turbine. With the impingement of spray to the wall, liquid film begins to form. Wall film characteristics is still an important subject to study. Due to the various stages of liquid film formation from injection of spray till spray-wall impingement, the investigation of this phenomenon is far more complicated. This paper is meant to provide detailed data on spray-wall impingement and wall film formation physics with the help of computational analysis of OpenFOAM . A Lagrangian-Eulerian method based on discrete phase model (DPM) was employed to model... 

Light propagation through turbid media, such as biological tissues, experience scattering due to inhomogeneous distribution of refractive indices of their microscopic structure. Scattering and diffusion of light not only limit many optical imaging techniques, but are also big challenges for telecommunication, spectroscopy, and other optical techniques. Recently many new imaging methods are developed that work in strongly scattering media such as optical coherence tomography, diffusion tomography, and laser speckle velocimetry. In this thesis, we have studied how wavefront shaping techniques can tackle the problem of scattering. By spatially shaping the wavefront of the incident beam, using...