Sharif Digital Repository

In the present work, high-energy mechanical alloying (MA) was employed to synthesize a nanostructured magnesium-based composite for hydrogen storage. The preparation of the composite material with composition of MgH2–5at% (TiCr1.2Fe0.6) was performed by co-milling of commercial available MgH2 powder with the body-centered cubic (bcc) alloy either in the form of Ti–Cr–Fe powder mixture with the proper mass fraction (sample A) or prealloyed TiCr1.2Fe0.6 powder (sample B). The prealloyed powder with an average crystallite size of 14nm and particle size of 384nm was prepared by the mechanical alloying process. It is shown that the addition of the Ti-based bcc alloy to magnesium hydride yields a... 

A comparative investigation has been developed for the stability constants of several amino acid complexes with divalent metal ions, which have been determined by potentiometric pH titration. Depending on the metal ion-binding properties, vital differences in the building complexes were observed. The present study indicates that in some M(L) complexes, metal ions are arranged in carboxyl groups, but in other M(L)complexes, some metal ions are able to build chelate over amine groups. The results mentioned-above demonstrate that for some M(L) complexes, the stability constants are also largely determined by the affinity of metal ions for amine group. This leads to a kind of selectivity of... 

The acidity and stability constants of M-Met (M: M2+; Met 1: L-methionine) complexes, determined by potentiometric pH titrations, were used to make a comparative investigation with L-cysteine (Cys). It is shown that regarding to M ion - binding properties vital differences on complex bilding were considered. It is demonstrated, that in M-Met complexes, M ion is coordinated to the carboxyl group, M ion is also able to build macrochelate over amine group. The upmentioned results demonstrate that for M-Met complex the stability constants is also largly determined by the affinity of Cu2+ for amino group but in opposite to Met, some metal ions such as Co2+, Cu2+, and Zn2+ build with Cys 2... 

Waste water from ore plant layout central Alborz's coal has been investigated and analyzed. Studies showed that because of acidic character, the waste water contains heavy metals including Cu, Cr, Ba, Zn, V, Sr, Pb, Ni. Considering the importance of this topic for outgoing acidic waste waters which is hazardous for the environment, i.e. heavy metals, the same should not be transferred into the environment. Since their waste water is transferred into nearby agricultural ground, it was developed a method, so that waste water is primarily directed into a slug pond for sedimentation. In the second stage in another pond, the outflow of waste water was treated with chemicals. Also the pH was... 

Machine learning algorithms often suffer from good generalization in testing domains especially when the training (source) and test (target) domains do not have similar distributions. To address this problem, several domain adaptation techniques have been proposed to improve the performance of the learning algorithms when they face accuracy degradation caused by the domain shift problem. In this paper, we focus on the non-homogeneous distributed target domains and propose a new latent subdomain discovery model to divide the target domain into subdomains while adapting them. It is expected that applying adaptation on subdomains increase the rate of detection in comparing with the situation... 

In the past two decades, microfluidic systems have become more appealing due to their wide applications in many areas, such as electronics, biotechnology, medicine, etc. Recently, the advantages of using the bubble growth phenomenon as a robust actuator in microfluidic devices have directed research interests towards the investigation of various applications. In this research, a new transient thermo-hydraulic model has been developed for bubble growth in confined volumes. The present model has been used to describe the pumping effect produced by the bubble growth and collapse phenomenon in microchannels. The results show relatively good agreement with experimental data. This study is useful... 

The thermal behavior of Fe3Si2O5(OH)4·Sb3O6(OH)·Sb2O3 (a sample of antimony from Sefidabe mine in Zahedan) was investigated by the technique of thermogravimetry under air atmosphere from 25 to 1200 °C. The obtained results from TGA were reported. This study reports comprehensive information about these minerals. XRD and XRF techniques, UV/visible and elemental analysis such as ICP are used to identify the products at different decomposition steps. The acidic leaching of this mineral Fe3Si2O5(OH)4·Sb3O6(OH)·Sb2O3 is carried out, and the obtained results are reported. In total, the recovery was achieved by leaching with hydrochloric acid was 85% at D80 granulation below 45 microns. In leaching...