Sharif Digital Repository

Nowadays, as the oil reservoirs reaching their half-life, using enhanced oil recovery methods is more necessary and more common. Simulations are the synthetic process of real systems. In this study, simulation of water and surfactant injection into a porous media containing oil (two-phase) was performed using the computational fluid dynamics method on the image of a real micro-model. Also, the selected anionic surfactant is sodium dodecyl sulfate, which is more effective in sand reservoirs. The effect of using surfactant depends on its concentration. This dependence on concentration in using injection compounds is referred to as critical micelle concentration (CMC). In this study, an... 

Using two techniques of thermogravimetry and differential scanning calorimetry under O2 and N2 gas atmosphere from 25 to 600 °C, the thermal behavior of chromium(VI) oxide CrO3 was investigated. The identity of products at different decomposition steps was confirmed by XRD technique. Both techniques produced similar results supporting the same steps for the compound. The received products were investigated by SEM electron microscope. The form and the size of crystals were investigated. Three distinct energy changes were observed, namely, two endothermic and one exothermic in DSC. The amount of ΔH for each peak is also reported  

Social norms are a core concept in social sciences and play a critical role in regulating a society's behavior. Organizations and even governmental bodies use this social component to tackle varying challenges in the society, as it is a less costly alternative to establishing new laws and regulations. Social networks are an important and effective infrastructure in which social norms can evolve. Therefore, there is a need for theoretical models for studying the spread of social norms in social networks. In this paper, by using the intrinsic properties of norms, we redefine and tune the Rescorla-Wagner conditioning model in order to obtain an effective model for the spread of social norms. We... 

The goal of this work is separation and recovery of catalyst residue in wastewater and byproducts of PTA (poly terephetalic acid) unit. Catalyst recovery consists in separating the maximum amount of catalyst and changing the same into valuable compounds. The PTA unit uses cobalt catalyst for oxidation reactions. The byproducts, which contain catalyst, were burned. In the case of metal oxide recovery in the ashes of waste materials, we could solve the problem of the Petrochemical Company. This new method may help us to recover catalyst from wastewater in PTA unit, after which small amounts of ions may be absorbed on a column filled with special absorbent, in such a way that the wastewater... 

The acidity and stability constants of M (MNPPAP) (MNPPAP: 2((4-methyl-5-nitro-6-(pyrrolidine-l-yl)pyrimidine-2-yl)amino)propionic acid) M: Cu2+, Cu (Bpy)2+ (Bpy: 2,2'-Bipyridine), or Cu(Phen) (Phen: 1,10-Phenanthroline) complexes were determined by potentiometric pH titration. It is shown that the stability of the binary Cu (MNPPAP) complex is determined by the basicity of the carboxylate group on one side and amine group on the other side. It is demonstrated that the equilibrium, Cu(Har)2+ (H ar: Heteroaromatic ligand such as Bpy or Phen) + Cu(MNPPAP) ^ Cu(Har)(MNPPAP) + Cu2+, is displacement due to the well known experience that mixed ligand complexes formed by a divalent 3d ion, a... 

A comparative investigation has been developed for the stability constants of several amino acid complexes with divalent metal ions, which have been determined by potentiometric pH titration. Depending on the metal ion-binding properties, vital differences in the building complexes were observed. The present study indicates that in some M(L) complexes, metal ions are arranged in carboxyl groups, but in other M(L)complexes, some metal ions are able to build chelate over amine groups. The results mentioned-above demonstrate that for some M(L) complexes, the stability constants are also largely determined by the affinity of metal ions for amine group. This leads to a kind of selectivity of... 

The acidity and stability constants of M-Met (M: M2+; Met 1: L-methionine) complexes, determined by potentiometric pH titrations, were used to make a comparative investigation with L-cysteine (Cys). It is shown that regarding to M ion - binding properties vital differences on complex bilding were considered. It is demonstrated, that in M-Met complexes, M ion is coordinated to the carboxyl group, M ion is also able to build macrochelate over amine group. The upmentioned results demonstrate that for M-Met complex the stability constants is also largly determined by the affinity of Cu2+ for amino group but in opposite to Met, some metal ions such as Co2+, Cu2+, and Zn2+ build with Cys 2... 

Waste water from ore plant layout central Alborz's coal has been investigated and analyzed. Studies showed that because of acidic character, the waste water contains heavy metals including Cu, Cr, Ba, Zn, V, Sr, Pb, Ni. Considering the importance of this topic for outgoing acidic waste waters which is hazardous for the environment, i.e. heavy metals, the same should not be transferred into the environment. Since their waste water is transferred into nearby agricultural ground, it was developed a method, so that waste water is primarily directed into a slug pond for sedimentation. In the second stage in another pond, the outflow of waste water was treated with chemicals. Also the pH was... 

The compounds α-lead oxide (α-PbO) and β-lead oxide (β-PbO) were purchased from Merck co. and used for thermal investigations in laboratory. The compound was heated in a thermogravimeter at different temperature, from 25 to 400 °C. The used gas atmosphere was O2. The received products were investigated by X-ray diffraction (XRD) technique. The received product Pb3O4 was confirmed by XRD. The textures of two different morphologies of α-PbO, β-PbO and the product Pb3O4 is investigated by scanning electron microscope (SEM) and transmission electron microscope (TEM) techniques. © 2018, Faculty of Metallurgy. All rights reserved  

In the study presented herein, a simple method for laboratory calcite cementation of a reconstituted gravelly sand was presented. This method was used to prepare cemented gravelly sand specimens, which have similar natural characteristics to alluvial deposit of the city of Tehran. The formation and distribution of calcite bonds, as well as the effectiveness of the presented calcite cementation method in increasing interparticle cohesion, as observed in weakly to moderately cemented soil in Tehran, were evaluated by means of chemical analysis, X-ray diffraction technique, and unconfined compressive strength tests. The cementation technique was used to prepare triaxial specimens with calcite... 

In this article, the induced airflow and the resultant particles resuspension due to a disk falling freely under the effect of gravity is studied using numerical and experimental approaches. The results showed that an axisymmetric vortex is generated on the disk tip as the disk falls and sheds after impacting the floor. While the effect of this ring vortex on the particles detachment from the floor is small, it has considerable influence on the dispersion of resuspended particles. The simulation results indicated that particles are mainly resuspended from an annular area beneath the disk tip where the generated wall shear is sufficiently high. As particles detachment is mainly controlled by... 

Site visits of selected factories and mines show large amounts of coal were collected as spoil and waste outside these locations due to un-efficiency of coal exploiting technology from mined material. The coal content of these waste materials is about 60%. In this work, we propose a method to be used for complete consumption of these materials in industry. In some samples, volume and weight of spoils could be decreased by half. This review also shows that aluminum oxide in industrial and minerals spoils are high, in some samples up to 25%. We suggest some remedies, e.g. we can use ashes produced by complete combustion of coal for production of aluminum hydroxide thus making it economical.... 

Rehabilitation is the best approach for patients who suffer physical disability of their upper-limbs. Maintaining the intensity of exercise during treatment is the main factor that makes the robots suitable for rehabilitation since robots do not get tired and do the exercises with constant intensity under supervision of the doctor. Two main categories of rehabilitation robots are End-Effector based robots and wearable robots. According to the fact that most problems occur in need of rehabilitation for hand wrist area, in this paper a wearable rehabilitation robot has been developed for the wrist. Nowadays, wearable robots attract more attention than the other group. Wearable robots are... 

This paper studies the effective parameters of a skilled service in playing tennis and determines their relationship with skill deals. Effective service in tennis plays an important role in gaining more desirable result and the most important factor of success in getting scores depends on the player's skills in serving an effective service. The characteristics of a good service are the high speed of the ball and the precision of landing the ball. The several parameters affecting on these two characteristic in the service, are studied in this paper. Therefore, the Kinematic parameters of 8 Iranian professional tennis athletes of first division tennis league and also 8 non-professional Iranian... 

The potential utilization of encapsulation techniques in food, pharmaceutical and agricultural products preparation, presents a new alternative for complementary technologies such as targeting delivery vehicles and carriers for active food ingredients. Encapsulation could be accomplished by different techniques like: simple or complex coacervation, emulsification technique, phase separation, spray drying, spray chilling or spray cooling, extrusion coating, freeze drying, fluidized-bed coating, liposomal entrapment, centrifugal suspension separation, co-crystallization and molecular inclusion complexation. Encapsulation is a method by which one bioactive material or mixture of materials is... 

In the past two decades, microfluidic systems have become more appealing due to their wide applications in many areas, such as electronics, biotechnology, medicine, etc. Recently, the advantages of using the bubble growth phenomenon as a robust actuator in microfluidic devices have directed research interests towards the investigation of various applications. In this research, a new transient thermo-hydraulic model has been developed for bubble growth in confined volumes. The present model has been used to describe the pumping effect produced by the bubble growth and collapse phenomenon in microchannels. The results show relatively good agreement with experimental data. This study is useful... 

The design of advanced nanobiomaterials to improve analytical accuracy and therapeutic efficacy has become an important prerequisite for the development of innovative nanomedicines. Recently, phospholipid nanobiomaterials including 2-methacryloyloxyethyl phosphorylcholine (MPC) have attracted great attention with remarkable characteristics such as resistance to nonspecific protein adsorption and cell adhesion for various biomedical applications. Despite many recent reports, there is a lack of comprehensive review on the phospholipid nanobiomaterials from synthesis to diagnostic and therapeutic applications. Here, we review the synthesis and characterization of phospholipid nanobiomaterials... 

PbCO 3·PbO and PbCO 3·2PbO compounds were prepared by thermal methods. The structure of each compound was determined by using XRD technique, and their purity was confirmed by analytical methods (98%). Also the thermal characteristics of each compound were investigated by thermogravimetry. At 600°C both compounds decompose completely and produce lead(II) oxide. © 2006 Nauka/Interperiodica  

the development and enlargement of city structure has caused the environmental problems on watershed of Latian dam which is one of the drinking water resourses of Tehran. The enlargement of Lavasan town and existence of an army garrison that it's effluents of treatment plant discharge to this river necessitate a water quality surveillance in entrance area of the dam. The present research includes the survey of this river's self-purification in the mentioned-above area. Numerical analysis is used in different methods to explain self- purification. Frist, we have the numerical analysis and analytical methods for a known sample in order to determine the accuracy and deviation between two... 

Using two techniques of thermogravimetry and differential scanning calorimetry under O2 gas atmosphere from 25 to 600°C, the thermal behavior of laboratory-produced compound lead(IV) oxide α-PbO2 was investigated. The identity of products at different stages were confirmed by XRD technique. Both techniques produced similar results supporting the same decomposition stages for the compound. Three distinct energy changes were observed, namely, two endothermic and one exothermic in DSC. The amount of ΔH for each peak is also reported. © 2008 Springer Science+Business Media, LLC