Sharif Digital Repository

The main aim of this study was to improve current efficiency and to obtain thicker coatings via aluminum oxide (Al2O3) addition to the chromium (Cr) (III) bath. Design/methodology/approach ‐ Pure Cr and nanocomposite Cr–Al2O3 coatings were electrodeposited from Cr (III) bath onto cathode copper substrates by conventional method. Dependence of current efficiency to current density, Al2O3 content and particle size were investigated. Findings ‐ Current efficiency increased with Al2O3 amount and decreased with Al2O3 particle size. Maximum current efficiency was achieved at 25 A/dm2 for pure Cr and 30 A/dm2 for composite coatings. Al2O3 bath content, current density and stirring rate increased... 

Cr and Cr-Al2O3 coatings were electrodeposited from Cr(III) bath with both pulsating and direct current onto copper substrates. Pulsating current resulted in homogeneous films of higher Al2O3 content and lower particle agglomeration than the direct current. Differences were more tangible at shorter duty cycles and pulse frequencies. Pulsating current improved both microhardness and corrosion resistance. The presence of alumina nanoparticles resulted in greater current efficiency, higher film microhardness and better corrosion resistance. Maximum current efficiency, highest microhardness and densest electrodeposited coatings were achieved at current density of 20 A dm-2, duty cycle of 40% and... 

A two-step pack cementation technique was used to cover nickel-based IN-738LC superalloy with a Cr-aluminide coating layer. The IN-738LC/Cr-aluminide samples were oxidized at 900 °C for 350 and 700 h, isothermally, and 175 and 350 h, cyclically. Each cycle lasted for 25 h. Effects of the isothermal and the cyclic oxidation on (a) morphology, (b) new-phase formation, (c) weight gain, and (d) oxidation reactions were investigated by scanning electron microscopy, electron dispersive spectroscopy, X-ray diffraction, and weight gain measurements. From results, it was concluded that the oxygen attack was more severe during the cyclic oxidation than the isothermal procedure. Kinetics of the... 

The effect of NaOH content of electrolyte on the properties of ceramic coatings, produced in silicate solution, was studied. Morphology, chemical analysis, phase composition, and cross-section of the ceramic coatings were investigated by SEM, EDS, XRD, and OM, respectively. The corrosion resistance and corrosion mechanism were also studied using potentiodynamic polarization and electrochemical impedance spectroscopy in a 3.5% NaCl solution. To study the surface roughness, a brightness SEM image analysis method was used. Results suggested that increasing the NaOH concentration of sediment production size causes thickness and coating roughness to decrease. The lowest corrosion rate belonged to... 

Optimum operating parameters for pulse co-deposition of nano-Al2O3 with Cr from a trivalent chromium bath onto Cu cathode are selected by using “technique for order performance by similarity to ideal solution” (TOPSIS), “VIšekriterijumsko KOmpromisno Rangiranje” (VIKOR), “elimination and choice expressing the reality” (ELECTRE) and “complex proportional assessment” (CORPAS) accompanied with analytic hierarchy processing (AHP) to compare methods for achievement of the best tribological coating performance. Criteria for appropriate selection include wear loss, corrosion resistance, micro-hardness, bath condition and current efficiency. Results ascertain the best Cr–Al2O3 nano-composite coating... 

Hot corrosion is a serious problem in gas turbines due to poor quality fuels which contain Na, V, S and Cl. To resolve the problem, Cr-aluminide was coated on IN-738LC superalloy with a two steps pack cementation process. Oxidation behavior and near-surface microstructure of the coating showed consecutive increase in destruction by exposition to Na2SO4, 75Na2SO4 + 25 V2O5 and 70Na2SO4 + 25 V2O5 + 5NaCl (wt.%). Kinetic studies indicated parabolic corrosion rate in salt-less samples due to diffusion. Similar expression for salt-covered samples was assessed for oxide dissolution. Plate-like, broken-plate-like and cauliflower-like morphologies attributed to the corrosion products were observed... 

This work describes coating of NiCoCrAlY on IN-738LC superalloy by high-velocity oxygen fuel (HVOF) process. Properties of the coatings are significantly influenced by oxygen/fuel ratio and other spraying parameters. The effect of oxygen/fuel ratio on the oxidation behavior, bond strength, hardness, roughness and microstructure including porosity, inclusion formation and unmelted particles are discussed here. The porosity and inclusion in C1 coating are maximal. C2 coating with oxygen/fuel ratio of 2 has the highest bond strength and the lowest unmelted particles. C3 coating with the lowest total porosity and inclusion has the minimal roughness and the highest oxidation resistance and... 

Abstract: This work describes coating of NiCoCrAlY on IN-738LC superalloy by high-velocity oxygen fuel (HVOF) process. Properties of the coatings are significantly influenced by oxygen/fuel ratio and other spraying parameters. The effect of oxygen/fuel ratio on the oxidation behavior, bond strength, hardness, roughness and microstructure including porosity, inclusion formation and unmelted particles are discussed here. The porosity and inclusion in C1 coating are maximal. C2 coating with oxygen/fuel ratio of 2 has the highest bond strength and the lowest unmelted particles. C3 coating with the lowest total porosity and inclusion has the minimal roughness and the highest oxidation resistance... 

Thermal-sprayed MCrAlY coatings have become widespread in various industries such as power plants, aeronautics, and oil and gas firms. High-temperature oxidation behavior of these coatings is therefore of significance. Spraying of two prevalent MCrAlY powders (NiCoCrAlY and CoNiCrAlY) on Hastelloy substrate by high velocity oxygen and fuel method and exposing them to 1000 °C air for resolving of their cyclic oxidation behavior are presented in this paper. The coatings were characterized by x-ray diffraction, scanning electron microscopy and energy-dispersive x-ray spectroscopy. The obtained oxidation kinetic indicated that at 1000 °C, the thermally sprayed NiCoCrAlY coating has greater... 

In this paper we study and evaluate the performance of a spectral-phase encoded optical CDMA (SPE-OCDMA) system using advanced receiver structures based on second harmonic generation (SHG) effect imposed in a Thick or Thin crystal. This receiver structure is employed as the nonlinear pre-processor prior to the conventional low-speed photodetector. In our performance evaluation amplified spontaneous emission (ASE) of the optical amplifiers, receiver front end thermal noise and photodetector shot noise which are effective in low power conditions, and multiple access interference (MAI) noise which is the dominant source of noise in high power conditions in any coherent OCDMA communications... 

In this paper, the authors analyze conditions under which they can be certain on the intensity addition of a given device, such as tapped-delay lines, used in digital incoherent all-optical communication systems. A general expression for phase-induced intensity noise that is applicable to all types of semiconductor lasers is derived by defining an optical self-SNR expression that can be used to analyze and measure phase-induced intensity noise. The result shows that in order to have a minimal phase-induced intensity noise in most digital optical incoherent systems, a large optical self-SNR, e.g., 20 dB or more, is needed. This in turn is shown to place a limit on the maximum rate of... 

In this paper we study and present an in-depth analysis on the operability and the viability of a typical wireless optical CDMA (OCDMA) local area network. Three receiver structures for OCDMA systems, using optical orthogonal codes (OOC) with minimum auto and cross-correlations as signature sequence, namely, correlation, correlation with hard-limiter, and chip-level detection are studied and proposed for such a network. For the synchronization circuit design the performance of two algorithms for OOC based OCDMA networks, namely, simple serial-search and multiple-shift in the context of wireless OCDMA LAN are studied. Furthermore, we study a synchronization method based on matched filtering... 

In this article, design of an adaptive control scheme for a class of uncertain single-input single-output systems in strict feedback form via a backstepping technique has been proposed. It is assumed that system output and its derivatives are available. By virtue of the observability concept, it is shown that for this class of systems there exists a one-to-one map, which maps output and its derivatives to system states. By means of this mapping and using linearly parametrised approximators, such as fuzzy logic systems or neural networks, the uncertain nonlinear dynamics and unavailable states are estimated. The proposed adaptive controller guarantees that the closed-loop system is uniformly... 

In this paper, an adaptive fuzzy controller, based on backstepping technique, has been proposed for temperature control of a general class of continuous stirred tank reactors (CSTRs). Using the observability concept, an adaptive fuzzy controller using temperature measurement has been designed. A fuzzy logic system is used to estimate the concentration dependent terms and other unknown system parameters appearing in the control law. It is shown that the closed loop system is asymptotically stable and influences of minimum approximation error and external disturbance on the L2 norm of the output tracking error can be attenuated arbitrarily. The performance of the proposed controller has been... 

In this paper, an adaptive fuzzy temperature controller is proposed for a class of continuous stirred tank reactors (CSTRs) based on input-output feedback linearization. Since for control implementation concentrations of all species are needed, based on the observability concept, a fuzzy logic system is used to estimate the concentration dependent terms and other unknown system parameters in the control law, using temperature measurements. It has been shown that the H∞ tracking control performance with a prescribed attenuation level is achieved, by using the proposed controller. Finally the effectiveness of the proposed controller has been demonstrated by applying it to a benchmark chemical... 

In this paper, two nonlinear observer based controllers for temperature control of a continuous stirred tank reactor in which a special class of parallel exothermic reactions take place are proposed. A reduced order nonlinear observer is constructed to estimate the concentration in the reactor. The observer is coupled with two nonlinear controllers, designed based on two well-known techniques, namely input-output linearization and backstepping for controlling the reactor temperature. For dampening the effect of observer error dynamics, a compensating term is used in each control law. The asymptotical stability of the closed-loop system is shown by the Lyapunov's stability theorem. The... 

A novel packet-based photonic label switching router for a multirate all-optical switch using generalized multiprotocol label switching is proposed. The idea is based on using optical code-division multiple access (OCDMA) as multiplexing technique and treating OCDMA codes as labels. The system can coexist with current wavelength division multiplexing systems on the same infrastructure. The concept of switch fabric is introduced. Label processing and label swapping functionalities of the switch are discussed. In-depth analyses are made for spectrally phase-encoded OCDMA (SPE-OCDMA) due to its capabilities of supporting high data rates, large code cardinality, and its secure transmission.... 

Autocorrelation receiver (AcR) is usually used as the general receiver for transmitted reference (TR) communication systems on a quite intuitive basis. In this paper, we apply the principle of statistical invariance to obtain the optimum TR receiver on a decision-theoretic basis, and it is shown that the autocorrelation receiver is optimal only in a special case. Performance of the optimum receiver and the suboptimum AcR for some important modulation schemes is also evaluated. The results imply that allocating a part of the transmitted energy and bandwidth to reference pulses would not help improve the performance of the system and the optimal performance might be achieved via much simpler...