Sharif Digital Repository

Composites are made to obtain several mechanical and physical properties selectively. But joining and manufacturing of complex shapes restricts their usages. Transient liquid phase (TLP) bonding is a novel method for joining of these materials without any defects that occur in other welding methods, such as melting or solid state methods. In this research, temperture gradiant TLP bonding of AA6061/SiC/15p using gallium as interlayer was performed. To obtain the optimum conditions, joining was performed at 260, 310, 360 and 410 ˚C, and pressure of 5 and 10 Mpa with holding time of 5 and 10 minutes, the joined samples then solutionized at 530˚C for 70 minutes. Optical and scanning electron... 

Polycarbonate (PC) is known as one of the engineering plastics with remarkable mechanical properties, but the application of this polymer is limited due to its high notch sensitivity. Blending polycarbonate with other polymers such as acrylonitrile butadiene styrene (ABS) is a method to resolve this disadvantage. PC/ABS blends are commonly used in automotive industry, electrical and electronic devices. As PC and ABS are not completely miscible, a variety of compatibilizers are used to achieve a suitable microstructure and high engineering properties. Considering crucial applications of PC/ABS blends, different flame retardants are also used to reduce the flammability. These flame retardants... 

Today, base lead piezoelectrics are the center of attention due to their very good electrical properties, and low cost of production. Among these ceramics are PZT which is a combination of Pb(ZrxTi1-x)O3 and PCN which is a combination of Pb(CoxNb1-x)O3. PZT is a normal piezoelectric whose dielectric properties would be improved if relaxor is added. PCN is ferroelectric with perovskite structure and curie temperature -27℃ which is known as a relaxor with high constant dielectric properties. In this research, adding PCN to PZT was done by sol-gel seeding method. Calcination at a temperature of 900℃ was causing the creation of single-phase perovskite powder. After that, conventional sintering... 

The aim of this study is to investigate the effect of Copper oxide on the microstructure, properties, and grain growth kinetic in Tin oxide- Based varistors. Copper oxide was mixed in Tin oxide with different concentration, including 0, 0.1, 0.25, 0.5, and 1 mol% and the samples were sintered at 1250, 1300, and 1350 oC. Then, phase and microstructural characterization was investigated and consequently, electrical properties were evaluated. According to results, Copper Oxide with forming the liquid phase through the sintering process, accelerated grain growth. It was found that, by increasing concentration of CuO, mean grain size was increased from 2.6 µm in 1250 oC and 5 hours to 17.1 µm... 

Recently, Polypropylene has been extensively used in a variety of applications in the polymer industry, but its quite low stiffness and toughness limit this polyolefin’s application in the engineering functions; thus, the market of polymer blend and composite manufacturing has grown noticeably in the last few years. In the current project, short Flax fibers are used in order to reinforce the PP matrix. Firstly, Flax fibers were washed with the gentle and harsh condition during the alkalization process, then the optimized alkalization condition was determined through comparison of results from X-ray Diffraction (XRD ), Attenuated Total Reflectance FTIR (ATR-FTIR) and microscopic surface... 

In this research, the surface of multi-walled carbon nanotubes (CNTs), as template, were coated by Lead zirconate titanate (PZT) with composition of Pb(Zr0.52Ti0.48)O3 via sol-gel process. The final product is called PZT-CNT hybrid material. For functionalizing of CNTs, benzyl alcohol was used. Simultaneous thermal analysis (STA) proved that the as-derived amorphous material crystallized at 520 ˚C. Scanning Electron Microscope (SEM) images verified the deposition of a uniform coating of PZT on the surface of CNTs and proved that the functionalizing treatment was done successfully. X-ray diffraction (XRD) showed that the crystal structure of the hybrid was tetragonal perovskite.... 

Nowadays, the development of different polymer blend nanocomposites is of great importance for achieving electrical and antistatic properties for various applications such as auto parts and the packaging industry. Immiscible polymer blends with conductive nanoparticles such as carbon nanotube, graphene, etc. can reach the conductivity threshold with low amounts of nanoparticles and produce desired electrical properties. In the present study, we have attempted to develop a polystyrene(PS)/ethylene-octene copolymer(EOC)/carbon nanotube(CNT) blend nanocomposite with suitable electrical conductivity. The compounding was performed by melt mixing at two weight percent of 80/20 and 50/50 (PS/EOC)... 

Due to the negative effects of conventional plastics on the enviroment, especially in the packaging sector, extensive efforts have been put to replace these polymers with biodegradable polymers. Starch is one of the biodegradable polymers which has attracted a lot of attentions because of low cost and good processability. Native starch has the form of granule and can be processed to a continuous phase after gelatinization in the presence of a plasticizer. The resulting material is a biodegradable plastic-like material called thermoplastic starch (TPS) which is processed using conventional technologies, but suffers from low mechanical properties and high hydrophilicity. Addition of natural... 

The goal of this project is production of composite laminated sheetswith bimodal microstructure using ARB process. It is planned to produce a laminated sheet having bimodal grain size distribution in microstructure to increase the formability while maintaining the strength. Two different aluminum alloys including AA 1050 and AA5083 were ARB processed up to 9 cycles, Then the ARB samples were annealed under controlled temperatures and times. Due to structural differences like stacking fault energy,stored cold work energy and solute atoms concentration, annealing ofThese two alloys lead to different recrystallized grain sizes. In order to evaluate the recovery and recrystallization behavior of... 

Last generation of solar cells which are organo-metal halide perovskite solar cells (PSCs) with power conversion efficiency over 20% are increasingly comparable to the silicon types, these PSCs are poorly stable under working environment. Carbon-based PSCs with lower cost and more stability seem a better choice for commercialization in future. In these PSCs TiO2 and NiO are working as electron and hole transporting materials, respectively. In addition, ZrO2 film between two mentioned layers works as a buffer layer to prevent direct contact. In this thesis, the initial powder, necessary for fabricating the buffer layer is synthesized at the first place. Then, since the printing method is a... 

As contrast enhancement agent, two different structures of superparamagnetic nanoparticles were synthesized. Iron oxide nanoparticles were prepared through an alkaline coprecipitation method of Iron (II) and (III) ions. PEG-6000 was used as biocapping material and its effect on particle size, colloidal stability and cytotoxicity was evaluated. On the other hand, novel core/shell structures were produced by NaBH4 reduction process of iron (III) in an aqueous media following by further oxidation by two different methods using (CH3)3NO oxygen transferring agent and exposure to oxygen flow. In both cases, structural examinations were conducted via X-ray diffraction, electron microscopy and... 

The microstructure, morphology and quality of the perovskite organic-inorganic layer as an absorber layer in perovskite solar cells has a significant role on the efficiency and energy conversion of the device. Different solvent engineering methods have been employed to prepare the perovskite layer with the desired properties and thier reproducibility have been studied. Herein, we applied a two-step solution approach by solvent engineering method, using solvents such as isopropyl alcohol, acetone and thier mixture, for preparation of lead iodide films. Moreover, their metallurgical and photovoltaic properties were investigated. The impact of solvent engineering, using solvents such as... 

In line with advances in science and technology in the areas of robotics, artificial intelligence, computer and control, unmanned vehicles are being more utilized and focused. On the other hand, development and further advances of these vehicles is highly dependent on the level of their autonomy. Motion planning is one of the most important issues in this regard. Due to high levels of autonomy required for unmanned air vehicles (UAV), the subject of motion planning is of valuable interest in aerospace applications. The goal of the motion planning problem, that is the subject of this research, is to extract an optimal trajectory for the UAV from an initial location toward its target point... 

Providing more choices to customers for determining the cost of their required reliability levels is one of the most important targets of restructured power system. Centralized management of reliability in Vertically Integrated Utility (VIU) applying the same policies to different customers is replaced with decentralized management allowing customers to participate in reliability management based on their required reliability levels. In this thesis, impact of emergency demand response programs, interruptible load contract and wind farms on the long-term security constrained unit commitment has been studied. Random outages of generators and transmission lines, load forecast inaccuracies as... 

The primary purpose of the present thesis is to understand the dynamic behavior of partially premixed flames of counterflow burners. In this project, work has been done on the previously designed and built counterflow burner. By setting up partially premixed flames in this burner, acoustic excitation of these flames has been done, and finally data acquisition by taking video of the flame and then using image processing to extract the dynamic response of these flames. The flames that we have examined in this project are all in a laminar regime and the fuel used in these flames is also natural gas. The frequencies that we have examined in these flames are 25 and 40 Hz, and these tests were... 

In the present work, the local Chemiluminescence method has been implemented on a laminar premixed propane-air flame. The goal of this work is to achieve a system capable of measuring the intensity of Chemiluminescent radiations of CH* and OH* radicals locally and with high spatial and temporal accuracy. For this purpose, a setup has been designed and developed. In order to achieve high spatial accuracy for local measurements, a Cassegrain lens has been designed and built, which has the ability to collect light from a cylindrical control volume with a cross-sectional diameter of 58 μm and a depth of 3.4 mm. An optical system for dividing and filtering light based on wavelength has also been... 

Sharp crested weirs are one of the main and oldest means of measuring discharge in water conveyance systems. Many studies have been done on sharp rectangular weirs and have provided many relationships regarding the effect of geometric parameters and various factors on discharge coefficient of the weirs.In some places, due to existence of obstacles or barriers in the channel, it is impossible to create a symmetrical continuous weir some other cases, multiple or asymmetric or curved weirs should be used, which is the main concept of this project. Since it seems unlikely that a purely mathematical model can review the impact of the multiplicity and asymmetry of these weirs without using...