Sharif Digital Repository

Confining nematic liquid crystal between two curved boundary conditions while the nematic molecules have a degenerate planar anchoring leads to complex and beautiful textures of molecular disparagement(defect) in the bulk and on the surfaces. Such the liquid crystal shells are made with double-emulsion techniques in microfluidic devices have provided applications for micro-scale colloidal linkers.In this work, we have numerically minimized the elastic energy in one-constant approximation in present of Fournier’s degenerate surface potential with finite element method. The nematic shell is confined between two spherical surfaces that we have studied the final energies and their related... 

Today safety is one of the major competition factors in automotive industries . The vehicles of today are more and more dependent on electronic systems , for driving safety and ease on control for the driver . Some systems are more or less standard in vehicles on the market , examples of such systems are ABS , ABC , etc. Despite of the effect of these systems on vehicle dynamics ,because they only control longitudinal dynamics and don't receive any feedback from vehicle lateral behavior , now control systems ,named VDC , have been developed and implemented in advanced vehicles. The operation of such systems is as this that in any time instance they evaluate vehicle dynamical behavior.... 

Analytic hierarchy process (AHP) is a structured technique for organizing and analyzing complex decision. This process is used around the world in a wide variety of decision situation, in fields such as government, business, industry, healthcare, and education. In this method, decision problem first is decomposed into a hierarchy of more easily comprehended sub-problems, each of which can be analyzed independently. Once the hierarchy is built, the decision makers systematically evaluate its various elements by comparing them to one another two at a time, with respect to their impact on an element above them in the hierarchy. In this thesis we will study the hierarchy process and also study a... 

In recommender systems, the available data structure is mostly in the form of a graph; Therefore, during the past years, graph based recommendation methods, especially Graph neural networks, have received a lot of attention. These networks obtain the representation of user nodes and items by aggregating multi-hop neighbors in different ways. Unfortunately, the existing methods are part of the Supervised learning scenario and due to the lack of data in recommender systems, they have faced serious challenges. These challenges reduce the ability to learn to representation nodes and the accuracy of recommendations. Recently, knowledge graph based recommendations have achieved excellent... 

In this project ionic liquid and there mixtures were coated on Pt/ Al2O3 , the prepared catalyst were characterization by SEM, BET and XRD techniques.In the first stage the effect of the coated ionic liquid on the Pt/Al2O3 were investigated, on the rate of C=C hydrogenation. in the second stage effect of the thickness of ionic liquids on the rate of the cyclohexene hydrogenation were studied. Result revelad that by increasing the ionic liquid polarity, the reaction rate increased. Also the reaction rate decreased by increasing the thickness of ionic liquid  

Polycarbonate (PC) is known as one of the engineering plastics with remarkable mechanical properties, but the application of this polymer is limited due to its high notch sensitivity. Blending polycarbonate with other polymers such as acrylonitrile butadiene styrene (ABS) is a method to resolve this disadvantage. PC/ABS blends are commonly used in automotive industry, electrical and electronic devices. As PC and ABS are not completely miscible, a variety of compatibilizers are used to achieve a suitable microstructure and high engineering properties. Considering crucial applications of PC/ABS blends, different flame retardants are also used to reduce the flammability. These flame retardants... 

In recent years, due to greater attention scientific communities to environment and environmental friendly material, use of natural fibers as reinforcing the polymers has increased significantly. High specific strength, low density, cheap, stiffness and recycled by nature, are including promotional items using natural fibers as reinforcing in the polymer composites. In This study has tried in the first place an appropriate method for producing polypropylene composites reinforced with short jute fibers should be presented and then the physical and mechanical properties of composites will be investigated. Used MAPP and Silane for compatibility took improved between natural jute fibers as a... 

Recently, Polypropylene has been extensively used in a variety of applications in the polymer industry, but its quite low stiffness and toughness limit this polyolefin’s application in the engineering functions; thus, the market of polymer blend and composite manufacturing has grown noticeably in the last few years. In the current project, short Flax fibers are used in order to reinforce the PP matrix. Firstly, Flax fibers were washed with the gentle and harsh condition during the alkalization process, then the optimized alkalization condition was determined through comparison of results from X-ray Diffraction (XRD ), Attenuated Total Reflectance FTIR (ATR-FTIR) and microscopic surface... 

The discovery of oil and gas resources in deep waters led to the invention of various platforms adapted to these waters. As the search for oil and gas resources is advanced to deep water, it is impossible to use fixed platforms in these depths. Hence, the idea of using floating platforms that can be used in deep waters has been increasingly considered. An option for the exploration and extraction of offshore oil resources is semi-submersible platforms. Under wave, wind, and current forces, a floating structure moves from its initial location. Types of mooring systems are used to maintain the position of the platform. During the life of a platform, mooring lines may be damaged under... 

Dye sensitized solar cells are one of the cheap and available technologies that have attracted the attention of many researchers. Many factors such as morphology, microstructure, phase composition and the arrangement of photoanode electrode layers have an effect on the photovoltaic properties of DSSCs. Different approaches have been used to improve the efficiency of this type of cells. Among these approaches, we can mention the use of a mixture of different phases of titanium dioxide and the use of perovskite titanate structures as photoanodes. In the current study, the performance of nickel titanate on light absorption and electron-hole separation in titanium dioxide-based dye-sensitized... 

Studying the interaction of active particles with walls and obstacles has a great importance for practical purposes. Using this knowledge, it is possible to control the motion of active particles in different environments.Experimental evidences show that after encountering with a wall, most of the active particles slide along the wall for some time and then detach in a certain direction, independent of their incoming angle. This special collision is considered to guide, sort or trap active particles.In this dissertation, using Brownian dynamics simulations and theories, we study how different selfpropelled particles and walls influence each other. We explore the behavior of two important... 

Discontinuously reinforced aluminum matrix composites (DRA) are candidates as a substantial class of materials for improved strength, stiffness, and wear resistance. However, the low fracture resistance of DRA's has restricted the widespread use of these materials as structural components. Consequently, intrinsic and extrinsic mechanisms have been considered in order to enhance the damage tolerance of composite materials based on microstructural and architectural modification, respectively. The intrinsic toughening technique has shown to elevate fracture resistance to some extent; usually at the expense of reducing several other properties such as strength. The more recent approach to... 

The purpose of this study is fabrication and characterization of a mesoporous Perovskite solar cell using Barium Titanate as the mesoporous electron transfer layer. In this study, TiO2 nanoparticles and BaTiO3 oxide perovskites were prepared by sol-gel synthesis method and their pastes were applied to the conductive substrate by spin coating method and applied to electron transfer layer in perovskite solar cells. Then Perovskite solar cells were fabricated with different structures from the electron transfer layer.The results of X-ray diffraction analysis showed that pure Barium Titanate and Titanium dioxide nanoparticles were successfully synthesized with tetragonal and cubic crystal... 

Lipid bilayers are one of nature’s solutions to confine and compartmentalize molecules and microorganisms. Usually, the thickness of the membrane is very small compared to the length scale at which it is studied. Therefore it is convenient to represent it with a 2-dimensional surface that has a stretch, shear, and curvature energy. Triangulated surfaces are the most popular discretization method to study the mechanical behavior of vesicles and fluid membranes since their elastic and bending moduli can be rigorously defined. Fluid membranes pose a particular challenge because they do not have a shear modulus. The dynamic triangulation algorithm is the state-of-the-art method developed to... 

In the first part of this research, we have developed a simple and effective ratiometric fluorescence sensor for selective detection of dopamine (DA) in alkaline media by simply mixing thioglycolic acid (TGA) functionalized orange fluorescent cadmium telluride (CdTe) quantum dots (QDs) with amino-functionalized blue fluorescent carbon nanodots (CDs). Under a single excitation wavelength of 365 nm, the sensor exhibits dual-emissions centered at 445 and 603 nm. The fluorescence of CdTe QDs is selectively quenched by DA, whereas the fluorescence of CDs is insensitive to the analyte. In the presence of different amounts of DA, the variations in the dual emission intensity ratios exhibit a... 

As contrast enhancement agent, two different structures of superparamagnetic nanoparticles were synthesized. Iron oxide nanoparticles were prepared through an alkaline coprecipitation method of Iron (II) and (III) ions. PEG-6000 was used as biocapping material and its effect on particle size, colloidal stability and cytotoxicity was evaluated. On the other hand, novel core/shell structures were produced by NaBH4 reduction process of iron (III) in an aqueous media following by further oxidation by two different methods using (CH3)3NO oxygen transferring agent and exposure to oxygen flow. In both cases, structural examinations were conducted via X-ray diffraction, electron microscopy and... 

Reconstruction of stochastic dynamical equations from measured timeseries of complex systems plays a crucial role in retrieving dynamic information and studying macroscopic states of such systems. This method which has been pursued for decades is practical in diverse fields like physics, biology, ecology, economics, social science, neuroscience and so on. To obtain stochastic dynamic equation, we have to calculate Kramers-Moyal coefficients from Markovian processes measured time series. We aim to propose new method for deriving these coefficients which is more accurate than two current methods, namely the histogram and kernel methods. In this dissertation, we studied dynamic equations of... 

Perovskite solar cells, with high efficiency operation, have been candidated as a cost-effective and environmentally friendly technology. Despite the great progress, there are some primarily issues remained regarding to the perovskite film and its fabrication methods. A very common perovskite cell structure is FTO/TiO2/CH3NH3PbI3/Spiro-OMeTAD/Au. Although, this structure has some advantages, lack of full surface coverage of perovskite film leads researchers to put much effort on finding other constructions. This surface inhomogeneity reduces the amount of light absorption and therefore efficiency. One way to produce a complete and uniform film is applying mixed-halide composition; such as... 

Wellbore storage effect is one of the biggest problems of petroleum engineers in analyzing the reservoir properties. In this phenomenon, at the beginning time of production from a reservoir, the fluid is initially produced from the well and not from the reservoir. Due to this effect, the pressures are distorted and could not be used in reservoir analysis. In this thesis the wellbore storage effect would be removed in naturally fractured reservoirs using deconvolution method. Using this method the range of data used could be increased. In this method special techniques are used in order to determine reservoir behaviour.
Using the method presented in this thesis, petroleum engineers could...