Sharif Digital Repository

Due to the increasing cost of energy, we want in this study to increase energy efficiency and reduce waste of system energy. Oil, gas and petrochemical sector is a widespeard part in Iran, so the study of energy systems in the industry have a paramount importance. The study focused on the Tehran refinery steam and power systems, seeking the most economical system of power and steam for the Tehran refinery. To achieve this goal, with the help of simulation of power and steam system for Tehran refinery with Aspen Utility software, a superstructure obtained. Then, using a sensitivity analysis, we were able to achieve economic arrangment of utility system. In this study by increasing the... 

Particulate ceramic reinforced aluminum matrix composites have high specific strength and stiffness; however, low fracture toughness and deformability have restricted their industrial applications. Among the methods introduced to overcome this shortcoming is fabricating the layered composites which contain alternative layers of aluminum (Al) and discontinuously reinforced aluminum (DRA). In this study, two different routes; i.e., "Powder extrusion - Casting - Rolling" and "Powder extrusion - Roll bonding" were employed to produce layered Al-DRA composites. After production of Al6061/SiCp composites via hot powder extrusion, mentioned processes were utilized to make DRA-Al-DRA laminate. In... 

In this research, friction and wear behaviors of 2024 Al and 2024 Al-20 vol.% SiC composite -prepared by powder metallurgy method- were investigated in the temperature range 20- 250°C. Dry sliding wear tests were conducted at a constant sliding velocity of 0.5 m/s, an applied load of 20 N, and a sliding distance of 2500m using a pin-on-disc apparatus. Some of the wear tests were carried out with artificially aged specimens in order to determine the aging effects. Worn surfaces and wear debris were also examined by using SEM, EDS and XRD techniques. All specimens showed a transition from mild to severe wear above a critical temperature. In the mild wear regime, the wear rate and the friction... 

Today, base lead piezoelectrics are the center of attention due to their very good electrical properties, and low cost of production. Among these ceramics are PZT which is a combination of Pb(ZrxTi1-x)O3 and PCN which is a combination of Pb(CoxNb1-x)O3. PZT is a normal piezoelectric whose dielectric properties would be improved if relaxor is added. PCN is ferroelectric with perovskite structure and curie temperature -27℃ which is known as a relaxor with high constant dielectric properties. In this research, adding PCN to PZT was done by sol-gel seeding method. Calcination at a temperature of 900℃ was causing the creation of single-phase perovskite powder. After that, conventional sintering... 

The aim of this study is to investigate the effect of Copper oxide on the microstructure, properties, and grain growth kinetic in Tin oxide- Based varistors. Copper oxide was mixed in Tin oxide with different concentration, including 0, 0.1, 0.25, 0.5, and 1 mol% and the samples were sintered at 1250, 1300, and 1350 oC. Then, phase and microstructural characterization was investigated and consequently, electrical properties were evaluated. According to results, Copper Oxide with forming the liquid phase through the sintering process, accelerated grain growth. It was found that, by increasing concentration of CuO, mean grain size was increased from 2.6 µm in 1250 oC and 5 hours to 17.1 µm... 

In this research, the surface of multi-walled carbon nanotubes (CNTs), as template, were coated by Lead zirconate titanate (PZT) with composition of Pb(Zr0.52Ti0.48)O3 via sol-gel process. The final product is called PZT-CNT hybrid material. For functionalizing of CNTs, benzyl alcohol was used. Simultaneous thermal analysis (STA) proved that the as-derived amorphous material crystallized at 520 ˚C. Scanning Electron Microscope (SEM) images verified the deposition of a uniform coating of PZT on the surface of CNTs and proved that the functionalizing treatment was done successfully. X-ray diffraction (XRD) showed that the crystal structure of the hybrid was tetragonal perovskite.... 

The goal of this project is production of composite laminated sheetswith bimodal microstructure using ARB process. It is planned to produce a laminated sheet having bimodal grain size distribution in microstructure to increase the formability while maintaining the strength. Two different aluminum alloys including AA 1050 and AA5083 were ARB processed up to 9 cycles, Then the ARB samples were annealed under controlled temperatures and times. Due to structural differences like stacking fault energy,stored cold work energy and solute atoms concentration, annealing ofThese two alloys lead to different recrystallized grain sizes. In order to evaluate the recovery and recrystallization behavior of... 

TLP diffusion bonding method refers to a method in which two metal pieces can be bonded by putting an interlayer between two pieces and heating to a temperature lower than base metal melting point. Theoretically, this process shows that the bonding line disappears completely at the end of the process and it is not possible to recognize it. However, these assumptions were not accomplished in practice. Therefore, various parameters such as material of interlayer, thickness of interlayer, temperature and time of bonding, temperature and time of homogenizing and applied pressure on metal pieces should be controlled to achieve the best shearing strength results. Aluminum based composites have... 

In the present research, transient liquid phase bonding of dissimilar st52 low carbon manganese steel to 304 stainless steel by pure Cu foil, in induction furnace and SIC furnace, was investigated. Samples were bonded in induction and SIC furnace at 1150 0C for different bonding times. Samples were then cut transversely and cross section of samples was examined by optical and scanning electron microscope. Complete isothermal solidification time was more than 9 hours and 90 minutes for SIC and induction furnace, respectively. Micro hardness and shear strength tests were done on samples bonded in optimum condition. Shear strength of none homogenized samples which had been bonded in SIC... 

Last generation of solar cells which are organo-metal halide perovskite solar cells (PSCs) with power conversion efficiency over 20% are increasingly comparable to the silicon types, these PSCs are poorly stable under working environment. Carbon-based PSCs with lower cost and more stability seem a better choice for commercialization in future. In these PSCs TiO2 and NiO are working as electron and hole transporting materials, respectively. In addition, ZrO2 film between two mentioned layers works as a buffer layer to prevent direct contact. In this thesis, the initial powder, necessary for fabricating the buffer layer is synthesized at the first place. Then, since the printing method is a... 

Many efforts have been put into increasing the efficiency of dye-sensitized solar cells that part of it has been devoted to structure and chemical composition of photoanode electrode. In this thesis, the effect of changes in the composition and its influence on light scattering ability in photoanode of dye sensitized solar cells was studied.First, the nanoparticles of titanium dioxide powder through solvothermal method as well as spherical particle and barium titanate powder by sol-gel method were synthesized. XRD and FE-SEM analyses indicated that synthesized powders are in good size and morphology regarding the intended chemical composition. Optical properties of TiO2 particles were... 

In the present investigation, the mechanical alloying (MA) technique was employed to produce nanocrystalline Al-Ti Powder mixtures. Elemental Al and Ti powders were mixed with different compositions (0, 5, 10, and 20 wt.% Ti) and then, milled in a vibratory mill up to 7 hr. The variations of powder morphology and particle size, apparent and tap densities, microstructure, grain size, lattice strain, and microhardness were studied with increasing the milling time. While dissolution of Ti in the Al matrix resulted to the formation of supersaturated Al-Ti solid solution in the samples containing 5 and 10 wt.% Ti, the specimen with 20 wt.% Ti, eventually, led to nanocomposite powder with... 

The aim of this research was to fabricate an in-situ Al-Al3Ti nanocomposite from pure microsized aluminum and titanium powders by mechanical alloying and hot extrusion without any usage of nanometric particles or applying secondary heat treatments. The focus of the present research was fabricating a nanocomposite material with high strength, modulus and hardness accompanied with high fracture toughness that could be comparable with aluminum alloys in terms of fracture toughness. Mechanical alloying and hot extrusion techniques were employed to produce in-situ fully dense Al-Ti composites. Platenary and high energy vibratiory mill was used to produce composites with different percent of... 

Thin film of Indium oxide doped with tin is used as a transparent electrode for different applications like screening panels, solar cells, touch panels and elechtrochromic tools. Trading thin films of ITO are precipitated using sputtering. However sol gel method can be simple and economic to make transparent electrodes. In this thesis first ITO sols is prepared using Indium nitrate and tin chloride with two or four capacities due to the production of transparent oxides on soda lime glass. Then the effect of tin chloride with two and four capacities is investigated on resistance and optic properties. Results show that tin chloride with four capacities in comparison with tin of two capacities... 

Preserving and promoting the health of citizens in a society is one of the most important problems addressed in any country. The power sector discharges a huge volume of carbon dioxide which intensifies the climate change and consequent human health problems.The goal of this study is to evaluate the ultimate effect of climate change caused by power plant emissions on the human health using life cycle analysis approach for different provinces in Iran. An integrated model has been developed to evaluate the impact of climate change due to power plant emissions on the human health. This model includes the equations regarding the variations in carbon dioxide concentration in the atmosphere,... 

This thesis reviews briefly historical backgrounds and contexts of Darwin's theory and summarizes and describes his arguments in the Origin, and studies philosophical issues around Darwinism. This thesis includes four chapters: chapter one reviews historical line from Greek thinkers to ninteenth century scientists; chapter two summarizes ideas and arguments in the Origin; chapter three discusses some philosophical issues briefly; and chapter four is devoted to some conclusion  

Endurance Time (ET) method is a dynamic analysis method in which the structure is subjected to an intensifying accelerogram and its response is recorded at different times.On the other hand a new method for designing earthquake resistant structures is Performance-Based Design (P-BD) method. P-BD is a methodology in which structural design criteria are expressed in terms of achieving a set of different performance objectives. In this research the application of ET method and target curve (which is defined based on ET method concepts) in the performance-based design has been studied.Correlating time in ET method and earthquake return period, the design,assessment and retrofitting of different...