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    Investigation of the Effect of Particulate Emissions From Steel Complex on Adjacent Urban Areas Using Source and Receptor Modeling Approaches

    , M.Sc. Thesis Sharif University of Technology Zeinali, Shervin (Author) ; Torkian, Ayoob (Supervisor)
    Abstract
    Expansion of city boundaries as a result of increased population has reduced the distance from industrial complexes and health effects of industrial air pollution have been intensified. As such, studies are needed to determine appropriate methodologies for quantifying the effect of these industries on the concentration of air pollutants in urban areas. In this study, particulate emissions from a steel mill complex was modeled using ADMS4 and the predicted results were compared with actual measurements made in the adjacent urban area. A receptor model (CMB8.2) was also used to quantify the share of the steel mill on the heavy metals' concentrations in the city by considering other sources... 

    Synthesis of NO-bidentate- and ONO-Tridentate-Oxovanadium(IV) Complexes Supported on Fe¬3O4@SiO2 Core-Shell Magnetic Nanoparticle and Their Application in Oxidation of Sulfides and Alkenes

    , M.Sc. Thesis Sharif University of Technology Shahbazirad, Ayoob (Author) ; Bagherzadeh, Mojtaba (Supervisor)
    Abstract
    To synthesizeFe3O4@SiO2 core-shellnanoparticles,at first,Fe3O4 magnetic nanoparticle synthesisedby usingcoprecipitation method.Then tetraethyl orthosilicate (TEOS) was used to coverthe surface of this nanoparticle with layer of silica. In the next step, the surface of Fe3O4@SiO2 core-shellnanoparticlesfunctionalized by NO-bidentate and ONO-tridentate ligands. Finally the functionalized nanoparticle coordinated to oxovanadium(IV) to achieve Fe3O4@SiO2@NO-VO2+ and Fe3O4@SiO2@ONO-VO2+nanocatalysts for selective oxidation of sulfides to corresponding sulfoxide and oxidation of alkene. FT-IR, 1HNMR, 13CNMR, SEM, VSM and ICP analysis were used for characterization of this nanocatalysts. This... 

    Nanoparticle supported, magnetically separable vanadium complex as catalyst for selective oxidation of sulfides

    , Article Journal of Coordination Chemistry ; Volume 65, Issue 4 , 2012 , Pages 591-601 ; 00958972 (ISSN) Bagherzadeh, M ; Haghdoost, M. M ; Shahbazirad, A ; Sharif University of Technology
    2012
    Abstract
    A magnetically recyclable vanadium(V) catalyst was synthesized by covalent anchoring of VO(salen)Cl on silica-coated Fe 3O 4 nanoparticles. This straightforward preparation yields magnetically separable Fe 3O 4@SiO 2@VO(salen) nanoparticles with high vanadium loading. These nanoparticles were efficient catalysts for selective oxidation of sulfides to corresponding sulfoxides with urea hydrogen peroxide in excellent yields. Leaching and recycling experiments revealed that the nanocatalyst can be applied for nearly complete oxidation of sulfides for at least five successive cycles