Sharif Digital Repository

In this study, the dynamics of the accelerated and steady-state motion of a single bubble in a quiescent highly viscous Newtonian liquid was investigated theoretically and experimentally. The presented mathematical model was based on Newton's second law of motion and a balance of buoyancy, drag, history, and added-mass forces. Due to the presence of non-linear terms in the equation of motion, homotopy perturbation method was used as a powerful analytical method to calculate the velocity analytically. To obtain accurate results in the experiments, a high-speed camera was used to record the bubble motion from the moment of detachment to the time at which the terminal velocity is reached.... 

In this study, the dynamics of the accelerated and steady-state motion of a single bubble in a quiescent highly viscous Newtonian liquid was investigated theoretically and experimentally. The presented mathematical model was based on Newton's second law of motion and a balance of buoyancy, drag, history, and added-mass forces. Due to the presence of non-linear terms in the equation of motion, homotopy perturbation method was used as a powerful analytical method to calculate the velocity analytically. To obtain accurate results in the experiments, a high-speed camera was used to record the bubble motion from the moment of detachment to the time at which the terminal velocity is reached.... 

This study attempts to examine the natural gas fired power plants in Iran. The required data from natural gas fired power plants were gathered during 2008. The characteristics of thirty two gas turbine power plants and twenty steam power plants have been measured. Their emission factor values were then compared with the standards of Energy Protection Agency, Euro Union and World Bank. Emission factors of gas turbine and steam power plants show that gas turbine power plants have a better performance than steam power plants. For economic analysis, fuel consumption and environmental damages caused by the emitted pollutants are considered as cost functions; and electricity sales revenue are... 

In this paper, we introduce a new dataset for SAD and evaluate certain common methods such as GMM, DNN, and RNN on it. We have collected our dataset in a semi-supervised approach, using subtitled movies, with a labeling accuracy of 95%. This semi-automatic method can help us collect huge amounts of labeled audio data with very high diversity in language, speaker, and channel. We model the problem of SAD as a classification task to two classes of speech and non-speech. When using GMM for this problem, we use two separate mixtures to model speech and non-speech. In the case of neural networks, we use a softmax layer at the end of the network, with two neurons which represent speech and... 

The present investigation introduces a new series of cycloplatinated(II) complexes, with the general formula Pt(O-bpy)(Me)(CN-R)] (R = benzyl, 2-naphtyl and tert-butyl), which are able to generate the stable trans-Pt(IV) product in the solution after the reaction with iodomethane. In fact, the trans product is both the kinetic and thermodynamic product of the reaction; this observation was supported by DFT calculations. These Pt(II) complexes are supported by 2,2'-bipyridine N-oxide (O-bpy) and one of several isocyanides as the cyclometalated and ancillary ligands, respectively. These new Pt(II) complexes undergo oxidative addition with MeI to give the corresponding trans-Pt(IV) complexes.... 

Reaction of the electron-rich complex cis-[Pt(p-Me-C6H4)2(SMe2)2] with 2,2′-bipyridine N-oxide, O-bpy occurred by rollover cyclometalation to afford complex [Pt(O-bpy)(p-Me-C6H4)(SMe2)], 1. The obtained complex was characterized using NMR spectroscopy and its solid state structure was determined by the single crystal X-ray diffraction method. The reaction of 1 with seven diphosphine ligands, 1,1-bis(diphenylphosphino)methane (dppm), 1,2-bis(diphenylphosphino)ethane (dppe), 1,3-bis(diphenylphosphino)propane (dppp), 1,4-bis(diphenylphosphino)butane (dppb), N,N-bis(diphenylphosphino)amine (dppa), 1,2-bis(diphenylphosphino)benzene (dppbz) and 1,1′-bis(diphenylphosphino)ferrocene (dppf), in... 

Symmetrical and unsymmetrical biscyclometalated platinum(II) complexes [Pt(ptpy)2], 1, and [Pt(ptpy)(bppy)], 2, in which ptpy = deprotonated 2-(p-tolyl)pyridine and bppy = deprotonated 2-(3-bromophenyl)pyridine, have been prepared from the reaction between tris(pentafluorophenyl)borane, B(C6F5)3 and 1 equiv of monocyclometalated complexes [PtMe(ptpy)(ptpyH)], B, and [PtMe(ptpy)(bppyH)], C, respectively. The solid-state structures of 1 and 2 have been determined by X-ray crystallography. The reaction of 1 with 1 equiv of TlPF6 or [Au(PPh3)]OTF resulted in the production of heteronuclear complexes [Pt(ptpy)2Tl]PF6, 3 and {Pt(ptpy)2[Au(PPh3)]}OTF, 4, respectively. X-ray diffraction data showed... 

A mixture of the platinum(0) complex [Pt(PtBu3)2] and tetrakis(acetonitrile)copper(i) hexafluorophosphate in acetone activated a water molecule and gave the hydride platinum(ii) complex [PtH(CH3CN)(PtBu3)2]PF6, 1, and the hydroxide Cu(i) species. The crystal structure of complex 1 was determined by X-ray crystallography, indicating a distorted square planar geometry around the platinum center. Although three possible mechanisms are proposed for this transformation, monitoring of the reaction using NMR spectroscopy at low temperature reveals that a cooperative pathway involving formation of a Pt0-CuI dative bond complex is the most probable pathway. The hydride platinum complex 1 is stable in... 

The objective of this work was to study the microstructure of as cast, solution treated and overaged Rene 80 superalloy before and after welding treatment. Studies focused on identifying heat affected zone (HAZ) liquation cracking mechanism and the effect of preweld microstructure on it. The formation of HAZ liquation cracking or microfissuring is found to be strongly dependent on constitutional liquation of grain boundary precipitates. These liquated precipitates in the as cast state contain MC carbides and particularly γ/γ' eutectic islands. While in the overaged condition they consist of the MC carbides and borides. Also HAZ grain boundary liquation and subsequent resolidification occur... 

Shape memory polymers (SMPs) are a class of smart materials which can recover their shape even after many shape changes in application of an external stimulus. In this paper, flexural behavior of a composite beam, constructed of a corrugated part filled with SMPs, is studied. This composite beam is applicable in sensor and actuator applications. Since the corrugated profiles display higher stiffness-to-mass ratio in the transverse to the corrugation direction, the beams with a corrugated part along the transverse direction are stiffer than ones with a corrugated part along the length. Employing a developed constitutive model for SMPs and the Euler–Bernoulli beam theory, the behavior of the... 

The six-coordinated silver(I) complex [Au2Ag(μ-(PPh2)2py)2(OTf)2](OTf), 4 (py = pyridine, OTf = CF3SO3), and the five-coordinated silver(I) complex [Au2Ag(acetone)(μ-(PPh2)2py)2](PF6)3, 6, were prepared by the reaction of the precursor complexes 1(OTf)2 and 1(PF6)2, in which 1 = [Au2(μ-(PPh2)2py)2]2+, with 1 equiv of Ag(OTf) in dichloromethane and excess of Ag(PF6) in a mixture of dichloromethane/acetone, respectively. Also, the five-coordinated silver(I) complex [Au2Ag(μ-(PPh2)2py)2(py)(OTf)](OTf)2, 5, was obtained by the reaction of 4 with pyridine. The clusters 4-6 were characterized using multinuclear NMR spectroscopy and elemental microanalysis. The single-crystal X-ray diffraction... 

Gold (Au) nanoparticles are widely used in diagnosing cancer, imaging, and identification of therapeutic methods due to their particular quantum characteristics. This research presents different types of aqueous models and potentials used in TIP3P, to study the effect of the particle size and density of Au clusters in aquatic environments; so it can be useful to facilitate future investigation of the interaction of proteins with Au nanoparticles. The EAM potential is used to model the structure of gold clusters. It is observed that in the systems with identical gold/water density and different cluster radii, gold particles are distributed in aqueous environment almost identically. Thus, Au... 

In this paper, we investigate multi-quality of service (QoS) routing and spectrum assignment in elastic optical networks (EONs) by utilizing network state information in terms of bandwidth usage and holding time of established connections. Toward this aim, two types of traffic, namely big data traffic (BDT) requests, and fixed rate flow requests (FLRs) are considered, where BDTs can tolerate a pre-determined initial delay while FLRs must be served immediately without any delay. We assume that both frequency and time usage of optical bandwidth is slotted, and accordingly optical resources are defined in a two-dimensional (2D) time/frequency domain, where the smallest resource is specified... 

The low swirl flow is a novel method for stabilizing lean premixed combustion to achieve low emissions of nitrogen oxides. Understanding the characteristics of low swirl flows is of both practical and fundamental interest. In this paper, in order to gain better insight into low swirl stabilized combustion, large eddy simulation and dynamically thickened flame combustion modeling are used to characterize various features of non-reacting and reacting low swirl flows including vortex breakdown, shear layers’ instability, and coherent structures. Furthermore, four test cases with different equivalence ratios are studied to evaluate the effects of equivalence ratio on the flame and flow... 

A semicentralized joint cell muting and user scheduling scheme for interference coordination in a multicell network is proposed under two different temporal fairness criteria. In the proposed scheme, at a decision instant, each base station (BS) in the multicell network employs a cell-level scheduler to nominate one user for each of its inner and outer sections and their available transmission rates to a network-level scheduler which then computes the potential overall transmission rate for each muting pattern. Subsequently, the network-level scheduler selects one pattern to unmute, out of all the available patterns. This decision is shared with all cell-level schedulers which then forward... 

Time, cost and quality are among the crucial aspects of each project. In recent years, the demands of project stakeholders regarding reductions in the total cost and time of a project along with achieving the acceptable quality of the project have risen significantly. This leads researchers to developing models that incorporate the quality factor to previously existing time cost trade-off models.We develop a model for discrete time-cost-quality trade-off problem. For each activity, an execution mode can be selected from a number of possible ones. The time and cost of each mode are assumed to be crisp but the quality of each mode is a linguistic variable. Therefore, in this paper, fuzzy logic... 

In this paper, employing the definition of an effective configuration in the continuum damage mechanics, mechanical response of a compressible viscoelastic-viscoplastic material is investigated. We present a phenomenological viscoelastic-viscoplastic-viscodamage constitutive model, developed within the framework of irreversible thermodynamics. The formulation is based on the additive decomposition of the total strain into elastic, viscoelastic, and viscoplastic parts in the effective configuration. Thus, the Helmholtz energy is partitioned into elastic, elastic-viscoelastic, and viscoplastic parts. Then, each one is divided into deviatoric and volumetric energies. Considering the... 

Self-healing concrete materials have the capability to recover a part of the weakened mechanical properties induced by damage. In this paper, a constitutive model is proposed to investigate damage and healing phenomena in concrete materials. In order to consider the different behavior of concretes in tension and compression, a spectral decomposition of the stress is utilized. In addition, employing the Clausius-Duhem inequality and considering the irreversible thermodynamics, conjugate forces of the damage and healing are expressed. The Gibbs potential energy is decomposed into three parts: elastic, damage and healing. In this regard, damage and healing behavior are distinguished from the... 

In this paper, employing the Hencky strain, viscoelastic-viscoplastic response of self-healing materials is investigated. Considering the irreversible thermodynamics and using the effective configuration in the Continuum Damage-Healing Mechanics (CDHM), a phenomenological finite strain viscoelastic-viscoplastic constitutive model is presented. Considering finite viscoelastic and viscoplastic deformations, total deformation gradient is multiplicatively decomposed into viscoelastic and viscoplastic parts. Due to mathematical advantages and physical meaning of Hencky strain, this measure of strain is employed in the constitutive model development. In this regard, defining the damage and healing... 

Self-healing materials, as a class of intelligent materials, are capable to recover a part of the weakened mechanical properties induced by damage. In this article, based on the thermodynamics of irreversible processes, employing the effective configuration in the continuum damage-healing mechanics, a viscoelastic–viscoplastic constitutive model is presented. In the constitutive model development, we adopt an additive decomposition of the total strain into elastic, viscoelastic, and viscoplastic parts. In this regard, defining the damage and healing variables and employing the strain energy equivalence hypothesis, stress and strain tensors in the effective configuration are obtained....