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shayegan--jalaledin
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Performance Comparison of Membrane Bioreactor and Activated Sludge Processes in Starch Wastewater Treatment
, M.Sc. Thesis Sharif University of Technology ; Shayegan, Jalaledin (Supervisor)
Abstract
In this study the performance of the conventional activated sludge and the membrane bioreactor systems were investigated and their operations were compared. . A membrane bioreactor and a conventional activated sludge system which includes one aeration basin and one settling tank were designed and constructed. The feed was synthetic and the BOD:N:P ratio was 100:5:1. In order to starting the systems, the sludge supplied from the municipal wastewater treatment plant and inoculated. Then, the inoculated sludge was adapted to treat the starch wastewater with step by step increasing the feed COD. . The performance of two systems investigated in inlet COD=2500 mg/L and four hydraulic retention...
Upgrading "Qaed Basir"Petrochemical Wastewater Treatment Plant
, M.Sc. Thesis Sharif University of Technology ; Borghei, Mehdi (Supervisor) ; Shayegan Salek, Jalaledin (Supervisor)
Abstract
Golpayegan Qaed Basir Petrochemical Company is one of the lucrative and entrepreneurial companies in Iran. Every day in this complex, a large amount of wastewater is being generated and transferred to the evaporative lag after the primary and secondary purification outside the complex and it is not restored. Considering the growing importance of surface and underground water resources, reuse of wastewater is a valuable production. In this research, the optimization of the sewage treatment system of the complex was evaluated by replacing the chemicals in the primary purification unit and also by using chloride-ferric and trickling filter for tertiary purification(treating) of the...
The simultaneous effect of silica nanoparticles and rubber particles on the toughness of epoxy polymer
, Article International Journal of Nanomanufacturing ; Volume 5, Issue 3-4 , 2010 , Pages 232-244 ; 17469392 (ISSN) ; Bagheri, R ; Sharif University of Technology
2010
Abstract
The objective of this study is to investigate the effects of both rubbery phase and nanosilica on mechanical properties of epoxy. Three series of formulations based on epoxy including nanosilica, rubber and rubber/nanosilica were prepared. Transmission electron microscopy showed that nanoparticles were homogeneously dispersed throughout the epoxy matrix. Compression and fracture toughness tests along with scanning electron microscopy and transmission optical microscopy were also done to evaluate the properties of the compounds. Although the results of compression tests indicate that addition of nanosilica could not change elastic modulus and yield strength of neat resin significantly,...
Design of Anaerobic Digestion for Solid Waste Treatment
, M.Sc. Thesis Sharif University of Technology ; Shayegan, Jalaleddin (Supervisor)
Abstract
In this project, performance of anaerobic digestion of organic waste in liquid phase has been investigated in an experimental process. Thus, the objective of this study was to optimize the organic loading rates, temperature and mixing of anaerobic digestion to the treatment of municipal solid wastes. To achieve this, the pilot scale experiment was conducted in 70l, fully mixed reactor. The start-up process was established over a period of 2 months. Starting the digestion in two stages was done with two different feed stocks, in which the feed stock of the first stage was star and in the second stage vegetables were considered as the organic waste. Experiment was investigated in mesophilic...
Design and Simulation of Process Units for Various Municipal Wastewater Treatment Methods
, M.Sc. Thesis Sharif University of Technology ; Shayegan, Jalaloddin (Supervisor)
Abstract
In this thesis, an algorithm is developed based on Multi Criteria Decision Analysis (Analytical Hierarchy Process, TOPSIS) combination with Fuzzy logic, and then user-friendly software with a GUI was designed and introduced. By using this method, it becomes possible to compare processes based on their ratings and users desired importance, and finally determine the closest process to the user ideal choice
Bioleaching of Heavy Metal from Industrial Incinerator Ash
, M.Sc. Thesis Sharif University of Technology ; Shayegan, Jalal (Supervisor)
Abstract
This study focused on the investigation of bioleaching of heavy metals from incinerator ash using Thiobacillus thiooxidans. Eight factors were examined for their significance on bioleaching using a Placket-Burman factorial design. Four significant variables (pulp density, Initial pH, sulfur Concentration and inoculation amount) were selected for the optimization studies. The combined effect of these variables on metal bioleaching was studied using a central composite design. Second order polynomials were established to identify the relationship between the recovery percent of the metals and the four significant variables. The optimal values of the variables for maximum metals bioleaching...
Methylene Blue Removal from Contaminated Water by using Graphene Nano-Palte
, M.Sc. Thesis Sharif University of Technology ; Shayegan, Jalaleddin (Supervisor)
Abstract
Organic dye couldn’t be treated by conventional method (biological method) due to their durable structure. In recent years, graphene based adsorbent has become more popular; this is because of high specific surface area and presence of numerous functional group on its surface. Due to the widespread application of organic dye in different industry especially in textile industry, stability and toxicity nature of them, finding an appropriate and cost effective method in treatment of this pollutant is very important. In this study, preparing and characterization of 3-D gel magnetic graphene oxide/kappa carrageenan was conducted and its ability of dye adsorption was tested. For this purpose, at...
Experimental Study of Effective Factors on Removing Heavy Metals from Produced Water using Iron Nanoparticles
, M.Sc. Thesis Sharif University of Technology ; Shayegan, Jalaleddin (Supervisor)
Abstract
The oilfields' wastewater, the water that is produced beside oil and is called ''Produced Water'', includes a large variety of pollutants. Heavy metals such as Lead, Manganese, Zinc and Barium and their compounds are some of the produced water's pollutants and because of their high stability they accumulate in life cycle. So a suitable and proper treatment is necessary. A combination of effectual and important parameters such as good adsorption, magnetic properties and low prices made Iron nanoparticles have a bright future in management of environmental pollutions. In this study Maghemite and Magnetite nanoparticles are used to remove heavy metals and effect of others factors such as pH,...
Treatment of Oilfield Produced Water with Dissolved Air Precipitation/ Solvent Sublation
, M.Sc. Thesis Sharif University of Technology ; Shayegan, Jalaloddin (Supervisor)
Abstract
Because of production of large volumes of Produces Water during oil exploration, it is necessary to purify this water for reuse or discharging to environment. Thus, finding a suitable method for removing contaminations seems necessary. In the present study, removal of soluble and dispersed organic contaminants from produced water by Dissolved Air Precipitation/ Solvent Sublation has been studied. Combination of floatation by dissolved air and extraction with solvent has been used for removal of organic compounds in order to study simultaneous effect of both methods on removal efficiency. Samples used in the experiments were tested in two groups: the first group was synthesized samples of...
Optimization of Water Consumption and Wastewater Treatment in Refinery
, M.Sc. Thesis Sharif University of Technology ; Shayegan, Jalaloddin (Supervisor)
Abstract
Water is used as a key material in different processes of chemical industries. Considering abundant demand of chemical industries for water, pollution that threats this valuable material and the fact that there is currently no proper substitute for water, an urgent necessity is felt for economic utilization of water in industrial processes and optimal use of water resources. A variety of methods have been developed for analysis of water consumption in industrial processes, amongst are Pinch methodology and Mathematical Programming approach. In this thesis a Petroleum Refinery has been preferred as a case study in which optimization of water consumption in the aforementioned petroleum...
Experimental Analysis and Simulation of Pollution Distribution in Ground Water and Soil
, M.Sc. Thesis Sharif University of Technology ; Shayegan, Jalal (Supervisor)
Abstract
Underground water is one of major resources of drinking water in Iran and thus, its quality (in terms of absence of pollutants) is a matter of great importance. The main goal of this research was to investigate the pollution concentration in underground water and soil in two regions: Dasht-e-naz in Sari and the fields near Sarkhoun gas refinery. The second goal was to determine the source and measure the distribution of the pollutants (in case of presence) and determine potential risks caused by them. The first step was to perform experimental tests in the two regions. In Sari's Dasht-e-naz region, a number of wells were chosen for sampling according to the direction of underground water...
Investigation and Controlling of Sludge Bulking in Wastewater Treatment Plant with Synthetic Wastewater
, M.Sc. Thesis Sharif University of Technology ; Shayegan, Jalaleddin (Supervisor)
Abstract
Biological treatment is an essential part of wastewater treatment. One of the major problems of the biological treatment systems is a solid separation. Filamentous bulking is a type of solid separation problem that settled sludge volume and the turbidity of the effluent will be increase in bulking condition. The presence of excessive Filamentous bacteria causes filamentous bulking. In this thesis, filamentous bulking were studied to understand this phenomena better and tried to control that with the different methods. This research was conducted in laboratory scale Sequencing Batch Reactor (SBR), conventional activated sludge and conventional activated sludge with anaerobic selector with...
Distribution and mobility of petroleum hydrocarbons in soil: Case study of the south pars gas complex, Southern Iran
, Article Iranian Journal of Science and Technology - Transactions of Civil Engineering ; Volume 36, Issue C2 , 2012 , Pages 265-275 ; 22286160 (ISSN) ; Ardestani, M ; Shayegan, J ; Sharif University of Technology
2012
Abstract
This article discusses the distribution of total petroleum hydrocarbons (TPH) contamination in soil within areas of the South Pars Gas Complex (S.P.G.C.), located on the northern shore of the Persian Gulf. To assess the potential risk to groundwater, in situ contaminant mobility was also examined in vertical soil profiles. Sampling was conducted in two rounds, and TPH was determined in accordance with standard methods of TPH analysis. The maximum detected concentration was 10268±785 mg/kg in the area of the waste disposal site. Significant heterogeneity in natural attenuation of different hydrocarbon compounds during transport in the soil was observed. Although the groundwater samples did...
Studies on the catalyst preparation methods and kinetic behavior of supported cobalt catalysts for the complete oxidation of cyclohexane
, Article Reaction Kinetics, Mechanisms and Catalysis ; Volume 114, Issue 2 , Jan , 2015 , Pages 611-628 ; 18785190 (ISSN) ; Khorasheh, F ; Shayegan, J ; Sharif University of Technology
Springer Netherlands
2015
Abstract
Low cost dispersed supported cobalt oxide nanocatalysts on activated carbon (AC) were prepared by two different methods: (1) combined impregnation and deposition–precipitation (IMP-DP) and (2) heterogeneous deposition–precipitation (HDP). XRD, TEM, FESEM, BET and Boehm techniques were used for the characterization of the support and the catalysts. Characterization analyses indicated the negative effect of the wet impregnation method on the IMP-DP technique for the preparation of catalysts for the total oxidation of cyclohexane in air. The catalysts prepared by HDP and IMP-DP methods were found to have significant differences in oxidation activity, morphology, particle size, and shape of...
Supported copper and cobalt oxides on activated carbon for simultaneous oxidation of toluene and cyclohexane in air
, Article RSC Advances ; Volume 5, Issue 7 , Dec , 2015 , Pages 5107-5122 ; 20462069 (ISSN) ; Khorasheh, F ; Shayegan, J ; Sharif University of Technology
Royal Society of Chemistry
2015
Abstract
Copper and cobalt oxides supported on almond shell derived activated carbon (AC) with different loadings were synthesized by sequential and co-deposition-precipitation methods leading to Cu(shell)/Co(core)/AC, Co(shell)/Cu(core)/AC and Cu-Co(mixed)/AC catalysts that were subsequently used for catalytic oxidation of gaseous mixtures of toluene and cyclohexane in air in a tubular flow reactor. The catalysts and the support were characterized by Boehm test, Brunauer-Emmett-Teller (BET) surface area, X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy...
Fouling control mechanism by optimum ozone addition in submerged membrane bioreactors treating synthetic wastewater
, Article Journal of Environmental Chemical Engineering ; Volume 6, Issue 6 , 2018 , Pages 7294-7301 ; 22133437 (ISSN) ; Hazrati, H ; Shayegan, J ; Sharif University of Technology
2018
Abstract
In this paper, the effect of ozone on membrane fouling of membrane bioreactor (MBR) systems was investigated. Sludge specification such as soluble microbial product (SMP), extracellular polymeric substance (EPS), viscosity, particle size distribution (PSD), microscopic observations and sludge volume index (SVI) in presence of ozone were determined. Further, EPS, Fourier-transform infrared (FTIR) analysis, excitation-emission matrix (EEM) fluorescence spectroscopy, and gel permission chromatography (GPC) are considered to determine cake layer characteristics. The results indicated COD removal did not show significant difference with ozonation. Ozone also increases the particle size and...
Optimal selection of an integrated produced water treatment system in the upstream of oil industry
, Article Process Safety and Environmental Protection ; Volume 117 , 2018 , Pages 67-81 ; 09575820 (ISSN) ; Roshandel, R ; Shayegan, J ; Sharif University of Technology
Institution of Chemical Engineers
2018
Abstract
Produced water (PW), water extracted along with oil, can cause important environmental challenges due to its high volume and salinity and is considered a key factor in the economic exploitation of oil fields. Therefore, making use of a cost-effective integrated system of wastewater treatment is a fundamental requirement in oil and gas industries. In this paper, the integrated PW treatment system is presented using superstructure-based mathematical optimisation methodology which is aimed at minimising the total annual cost. Two distinct scenarios of injection and reuse in industrial scale are considered to propose an efficient and optimal integrated system. The results show that, despite the...
A model for investigation of optimal hydrogen pathway, and evaluation of environmental impacts of hydrogen supply system
, Article International Journal of Hydrogen Energy ; Volume 33, Issue 24 , 2008 , Pages 7314-7325 ; 03603199 (ISSN) ; Saboohi, Y ; Shayegan, J ; Sharif University of Technology
Elsevier Ltd
2008
Abstract
In order to achieve a hydrogen economy, developing widespread hydrogen supply systems are vitally important. A large number of technological options exist and are still in development for hydrogen production, storage, distribution., which cause various pathways for supplying hydrogen. Besides the technical factors, there are other effective parameters such as cost, operability, reliability, environmental impacts, safety and social implications that should be considered when assessing the different pathways as optimal and viable long-term alternatives. To aid this decision-making process, we have developed a generic optimization-based model for the long-range energy planning and design of...
Sensitivity analysis of the environmental impact of chemical processes through integrated computer-aided modeling
, Article Scientia Iranica ; Volume 9, Issue 1 , 2002 , Pages 29-38 ; 10263098 (ISSN) ; Rashtchian, D ; Shayegan, J ; Sharif University of Technology
Sharif University of Technology
2002
Abstract
A comprehensive representation of the environmental impact of a plant should incorporate not only the process variables that mainly affect the generation step but also the non-process ambient conditions that have influence on the dispersion step. Albeit, at best, only the process-related variables can be manipulated in order to optimize the environmental behavior of the process. In this study, an environmental model is coupled with a chemical process model. The approach is applied to an existing nitric acid production plant to study the effects of selected process variables on the environmental impact of the process. The insights that this approach provides can be used in retrofit studies to...
The effect of influent COD and upward flow velocity on the behaviour of sulphate-reducing bacteria
, Article Process Biochemistry ; Volume 40, Issue 7 , 2005 , Pages 2305-2310 ; 13595113 (ISSN) ; Ghavipanjeh, F ; Mirjafari, P ; Sharif University of Technology
2005
Abstract
The effect of up velocity and influent COD concentration on the activity of sulphate-reducing bacteria (SRB) in UASB reactors is discussed. To study these effects, four UASB reactors were built and utilized in parallel. Examinations were carried out in two different concentrations of molasses (500 mg COD/l and 1000 mg COD/l) and four different upward flow velocities. It was observed that at velocities greater than 1 m/h, SRB bacteria were easily washed out from the reactors due to lower density and lack of ability to form dense and firm granules. It was found that in low-strength wastewaters with a COD to sulphate ratio of 2, an upward velocity in the range of 1.5-2.5 m/h could be...