Sharif Digital Repository

Synthesis and characterization of a new series of low molecular weight (MW = 500–3000) OH-terminated linear aliphatic unsaturated polyesters based on cis-2-butene-1,4-diol and oxalic to sebacic acid were investigated. Direct polycondensation and transesterification methods were used for the syntheses. The latter was recognized to be the preferable method due to its lower reaction temperature and time, lower diol/diacid ratio, absence of decarboxylation, and formation of a product with low polydispersity (Mw/Mn = 1.3–2.7). Elemental analysis, GPC, FTIR, 1H-NMR, DSC, and WAXD were used for the investigations. A segmented polyurethane based on poly (cis-2-butylene adipate) glycol was also... 

In this study, the plastic instabilities associated with the Portevin-Le Chatelier (PLC) and their effects on the mechanical properties and the fracture surfaces have been investigated for AA 5083. Tensile tests were performed at various temperatures and strain rates in order to do so. Then, serrated and smooth yielding domains were determined in Ln ε̇-1/T diagram. The stress-strain curves related to the serrated domain show the values of flow stress decreases by increasing the strain rate at a constant temperature. In addition, the plot of critical strain versus imposed strain rate indicates an inverse manner at very low strain rates. It is confirmed that the type of PLC bands alters the... 

Permeability of porous materials is an important characteristic which is extensively used in various engineering disciplines. There are a number of issues that influence the permeability coefficient among which the porosity, size of particles, pore shape, tortuosity, and particle size distribution are of great importance. In this paper a C++ GPU code based on three-dimensional lattice Boltzmann method (LBM) has been developed and used for investigating the effects of the above mentioned factors on the permeability coefficient of granular materials. Multirelaxation time collision scheme of the LBM equations is used in the simulator, which is capable of modeling the exact position of the... 

In this work, neural networks are used for estimation of flow stress of AA5083 with regard to dynamic strain ageing that occurs in certain deformation conditions and varies flow stress behavior of the metal being deformed. The input variables are selected to be strain rate, temperature and strain and the output value is the flow stress. In the first stage, the appearance and terminal of dynamic strain aging are determined with the aid of tensile testing at various temperatures and strain rates and subsequently for the serrated flow and the smooth yielding domains different neural networks are constructed based on the achieved results. While a feed-forward backpropagation algorithm is... 

In this work, a novel multi-layer pressure-temperature swing adsorption (PTSA) process was designed for efficient simultaneous water and mercaptans removal from natural gas (NG) to less than 0.1 ppmv and 3 ppmv in a mini liquefied NG unit. The proposed multi-layer PTSA consists of a three-layer fixed bed including activated alumina, molecular sieves 4A and 13X. To gain in-depth insights about the process, a descriptive model considering mass, energy and momentum balances, along with the kinetic and equilibrium equations was developed. After validating the model with the experimental and operational data from the literature, the total energy requirement and long-term operational requirements... 

The effective constitutive parameters of a three-dimensional periodic structure are calculated using its Bloch modes. These modes and their propagation constants are obtained from eigenvectors and eigenvalues of the generalized transfer matrix of a unit layer of the structure. Effective bulk permittivity and permeability tensors of the medium are obtained when two of the Bloch modes are dominant, i.e., propagate without significant decay inside the medium. The effect of the strongly decaying Bloch modes, which are excited at the interface with a conventional medium, are included by means of surface impedance matrices. The results are in excellent agreement with full-wave electromagnetic... 

The effective constitutive parameters of a three-dimensional periodic structure are calculated using its Bloch modes. These modes and their propagation constants are obtained from eigenvectors and eigenvalues of the generalized transfer matrix of a unit layer of the structure. Effective bulk permittivity and permeability tensors of the medium are obtained when two of the Bloch modes are dominant, i.e., propagate without significant decay inside the medium. The effect of the strongly decaying Bloch modes, which are excited at the interface with a conventional medium, are included by means of surface impedance matrices. The results are in excellent agreement with full-wave electromagnetic... 

The influence of electron beam (EB) irradiation and organoclay (OC) loading on the properties of low-density polyethylene (LDPE)/ethylene-vinyl acetate (EVA) blends was investigated. The samples were subjected to the EB irradiation with the dose values of 50 and 250kGy. X-ray diffraction (XRD), gel content, mechanical, thermal, and electrical properties were utilized to analyze the characteristics of the LDPE/EVA blends with and without OC at different irradiation dosages. Gel content analysis showed that the OC promotes considerably the insoluble part so that the LDPE/EVA blends filled with OC become fully crosslinked at 250kGy; possibly through the formation of further crosslinks between... 

Attempts were made to trace the effect of organoclay (OC) on the rheological and mechanical behaviors of the low density polyethylene (LDPE)/ethylene-vinyl acetate (EVA) blends. To do this effectively, in addition to LDPE/EVA/OC system, pure LDPE and LDPE/EVA blends were also examined as model systems. The rheological behavior was determined by the capillary rheometer. Morphological characterization was also carried out using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and theoretical approach based on interfacial energies. Shear viscosity, tensile strength and elastic modulus of LDPE/EVA were found to decrease by increasing the EVA... 

The present paper demonstrates the performance of the radiation grafting technique as a chemically based surface pretreatment method to adhesion modification of polyethylene surfaces toward the metallic layer. Gamma irradiation over a dose range of 4-10 kGy is used for grafting of vinyl monomers including acrylamide (AAm) and 1-vinyl-2-pyrrolidone (NVP) onto the surface of three different polyethylenes including low density polyethylene (LDPE) and two kinds of high density polyethylenes, namely HDPE-1 and HDPE-2. The grafting yield is evaluated based on the weight increase of the samples. It is found that the grafting yield is dominated by the crystallinity of the polyethylene, so that lower... 

The tiny graviton Matrix theory [1] is proposed to describe DLCQ of type IIB string theory on the maximally supersymmetric plane-wave or AdS5 × S5 background. In this paper we provide further evidence in support of the tiny graviton conjecture by focusing on the zero energy, half BPS configurations of this matrix theory and classify all of them. These vacua are generically of the form of various three sphere giant gravitons. We clarify the connection between our solutions and the half BPS configuration in script N sign = 4 SYM theory and their gravity duals. Moreover, using our half BPS solutions, we show how the tiny graviton Matrix theory and the mass deformed D = 3,script N sign = 8...