Sharif Digital Repository

Atom transfer radical polymerization (ATRP) is a convenient approach to synthesis of polymer with narrow molecular weight distribution. ATRP of acrylamide (AAm) is taken into consideration because of the intrinsic properties of acrylamide such as water solubility and biocompatibility. As reported in many recent works, polymerization of acrylamide by this method didn’t provide monomodal molecular weight distributions. In best condition with strong ligands such as Me4Cyclam, polymerization was carried out in a short time with high yield but polymerization was not highly controlled. It was shown that polymerization of acrylamide under typical ATRP condition displayed a much lower ATRP... 

In this research with Finite Element Methods in ABAQUS, numerical modeling has done in three-dimensions, which can be used to determine the effect of different factors on the surface settlement. Also, various factors such as geotechnical conditions, tunnel diameter,tunnel depth, the impact of the thickness of the segments and the amount of eccentricity of the structure relative to the longitudinal axis of the tunnel considered in this study. Face Pressure Supports, and Grout Injection Pressures are taken into account, too.Tunnel drilling causes a change in the displacement area and creates a changing zone around the tunnel. In this regard, not only adjacent buildings will be affected by... 

Toll Pricing as a means to relieve traffic congestion has received significant attention by transportation planners recently. Inappropriate use of transportation networks is one of the major reasons that cause congestion in networks. Toll Pricing is a method of traffic management which guides the traffic flow to proper time and path in order to reduce the total delay in networks. This thesis investigates a method for solving Minimum Toll Revenue problem in real and large scale transportation networks. The objective of this problem is to find tolls that simultaneously cause users to use the transportation network effectively and minimize the total toll revenues that must be collected.... 

In this research, we have used green tea polyphenols as green reductants for reduction of graphene oxide. Furthermore, for the first time, the presence of some metals such as iron, tungsten and copper in the efficiency of reduction is investigated. XPS spectra indicate that iron can be considered as one of the best choices for helping polyphenols in the reduction process. Hence, we used AFM, XPS, Raman spectroscopy and I-V diagram to characterize graphene oxide reduced by polyphenols and iron. In recent years, hydrazine has been recognized as one of the standard reducing agents for effective reduction of graphene oxide. In our analysis, it is found that the conductivity of our reduced... 

This study is aimed at simulation of double emulsion formation in a microfluidic double flow focusing device which consists of two cross-junctions connected serially. The water in oil (w/o) emulsions are produced in the first junction. In the second junction, water in oil emulsions are encapsulated by an outer aqueous phase to generate water in oil in water (w/o/w) double emulsions. Water in oil emulsions are formed in hydrophobic channels and water in oil in water double emulsions are formed in hydrophilic channels. A three phase numerical model, based on the VOF-CSF method, is developed for simulating the process of double emulsion formation. An adaptive mesh refinement technique is... 

Patients with a single ventricle disease who have undergone Fontan surgery have always had long-term complications. These complications include pulmonary artery stiffness and decreased ability to exercise. In fact, due to removal of the right ventricle from the circulatory system, blood pressure and pulsatility inflow to total cavopulmonary connection (TCPC) are reduced following this surgery. Creating waves (radial displacement) on the IVC (Inferior Vena Cava) wall can increase pulmonary flow pulsations. The Objective of this study is to test the effect of induced wave amplitude on the pulmonary flow pulsations at the rest condition. Computational fluid dynamic (CFD) simulations were... 

On account of the exhausting nature and increasing daily cost of the fossil fuels, it seems that replacing the fossil fuels by an alternative source of energy is inevitable. Moreover, in the remote areas that the electricity network is not accessible, the use of distributed sources (DSs) such as solar energy and wind energy is advantageous. Continuity of the supply and voltage control of the load in spite of the stochastic nature of the generated power of the renewable energy resources are the main concerns in the distributed generation (DG) systems. In this thesis, stand-alone operation of a DG unit comprising a solar unit and wind turbine as primary sources of energy is considered. A... 

Statistical studies indicate the fact that in Iran, like many other developing countries, a significant percentage of buildings are made of traditional materials and most of them are adobe buildings especially in rural areas. Furthermore, geological data indicates that Iran is located in alps-Himalayas seismic zone and exposed by destructive earthquakes and adobe buildings suffer the most damages comparing with other type of the structures. According to these explanations, this research deals with adobe buildings behavior and provides solutions for reinforcing them and improving the seismic response of these buildings. These studies include numerical modeling with finite elements methods by... 

Natural disasters, such as earthquakes and hurricanes, can strike without warning, resulting in a range of destruction from structural damage to loss of life. For this reason, research on structural control, which provides a new basis for design of structural systems against winds, earthquakes, waves, and traffic loadings, become of interest in civil engineering. This thesis focuses on using fluid dampers as a passive energy dissipation device. Viscous Fluid Dampers (VFD) are the most commonly used passive energy dissipation devices that are manufactured in various forms. However, the orifice type of Viscous Fluid Damper (VFD) is considered for structural applications. In this thesis, the... 

In this thesis we consider the problem of distributed computation by many processors.We mainly concentrate on matrix multiplication problem in this thesis because of its importance. A distributed system consists of N worker processors and one master processor. The master processor should distribute the computation between workers and after computation in each of them, collect the results. In this thesis, we are going to mitigate the effect of straggler processors by using coding methods. Straggler processors can cause delays in the computation time.In this thesis, we firstly introduce a method to multiply any number of matrices in each other. The proposed method occurred in one shot without... 

The main goal of current investigation was partial reduction of Fe2O3 available in Hematite-rich ore to Magnetite by Fludization Bed method. The reductive gas, CO, was produced by incomplete combustion of Acetylene and Airmixed in inappropriate ratio. X-Ray Diffraction and X-Ray Florescence analyses were implemented in order to conducting qualitative analysis of present phases before and after reduction of the ore. Quantitative analysis of the same phases was also conducted by Titration. The latter analysis revealed the precise magnitude of available iron in each of the oxide containing phases. The chemical composition of the reactor gas was also determined before and after reduction... 

Abstract The problem of competetive facility location can be defined as follows: There are a number of customers in the form of points in space, and two players arrange a number of facilities in the form of points in space, given some limitations, respectively. Each customer’s connection to each facility has a cost for the customer and an advantage for the facility, and each customer wants to be connected to at most one of the facilities which has the lowest cost for him. The goal is to find the strategy of placing the facilities and determining the cost which the facility receives from the customer, in such a way that the player’s profit is maximised.In this thesis, we first sought to... 

Zero knowledge proofs allow a person (prover) to convince another person (verifier) that he has performed a specific computation on a secret data correctly, and has obtained a true answer, without having to disclose the secret data. QAP (Quadratic Arithmetic Program) based zkSNARKs (zero knowledge Succinct Non-interactive Argument of Knowledge) are a type of zero knowledge proof. They have several properties that make them attractive in practice, e.g. verifier's work is very easy. So they are used in many areas such as Blockchain and cloud computing. But yet prover's work in QAP based zkSNARKs is heavy, therefore, it may not be possible for a prover with limited processing resource to run... 

Lightweight clients are a type of blockchain users who do not store all the blocks in the blockchain due to limited resources. These users store only a small part of each block and when needed, request transactions from full nodes that store the entire blockchain. These users have no role in block validation and only want to receive transactions related to their addresses with proof of the inclusion in the block from full nodes.Since light clients rely on full nodes for receiving transactions, their privacy against full nodes is important. The current implementation of Bitcoin uses Bloom filters for privacy, but this offers very little privacy to the users.In this thesis, we study the... 

Power system frequency regulation entitled load frequency control (LFC) has been one of the important control problems in electric power system design and operation. Off-normal frequency can directly impact on power system operation and system reliability. A large frequency deviation can damage equipment, degrade load performance, cause the transmission lines to be overloaded and can interfere with system protection schemes, ultimately leading to an unstable condition for the power system . On the other hand, the increasing need for electrical energy in the 21st century, as well as limited fossil fuel reserves and the increasing concerns with environmental issues for the reduction of carbon... 

The  aim  of  this  work  is  to  investigate  some  theoretical  models  developed  in  recent years for describing electronic correlation and apply them to some special problems  and  metallicity  and  insulating  behavior  of  one  type  of  paramagnetic  systems. One  of  the  vast‐applied  and  effective  routines  for  investigating  the  strongly  correlated electron systems is Dynamical Mean Field Theory (DMFT). In the first part,  the  equations  of  DMFT  are  solved  on  nearly  real  frequency  axis  with  a  effective and more reliable solver a little parameter γ above the real axis. This approach  appears  fine  structures  that  can’t  be  captured  with  the ...