Sharif Digital Repository

Atom transfer radical polymerization (ATRP) is a convenient approach to synthesis of polymer with narrow molecular weight distribution. ATRP of acrylamide (AAm) is taken into consideration because of the intrinsic properties of acrylamide such as water solubility and biocompatibility. As reported in many recent works, polymerization of acrylamide by this method didn’t provide monomodal molecular weight distributions. In best condition with strong ligands such as Me4Cyclam, polymerization was carried out in a short time with high yield but polymerization was not highly controlled. It was shown that polymerization of acrylamide under typical ATRP condition displayed a much lower ATRP... 

This project aims to design a drug to fight leukemia and some autoimmune diseases having few side effects. These drugs are composed of natural sugar and amino acid structures. Among the various treatments available, drug structures as inhibitors of enzymes involved in cancer-related cellular processes is an important treatment. Methotrexate is one of the most widely used anticancer drugs in the last half-century and treats leukemia and many autoimmune diseases such as psoriasis. It is a derivative of folic acid (vitamin B9) and one of the drugs with specific properties. It is an anti-folate whose anti-metabolic effects can help kill cancer cells. One of the problems with using this drug to... 

Entrepreneurship is a process that requires high motivation for success. Self-efficacy is to believe the person's ability to organize and carry out certain types of activities to produce specific outcomes. Thus helping to increase self-efficacy beliefs in people who have attempted to entrepreneurship can increase their chances of success. On the other hand Self-leadership has been defined as “the process” of influencing oneself to establish the self-direction and self-motivation needed to perform. And include three major strategies named Behavioral focused strategies, Intrinsic motivation (Natural Reward) strategies, Constructive thought pattern strategies and some specific behaviors in each... 

With the increasing development of Internet of Things (IoT) devices, issues such as establishing effective communication, optimizing energy consumption, ensuring reliability and improving the quality of services provided by these devices become more and more complex and critical challenges. With the introduction of fog computing model by Cisco in 2012, some of these challenges were successfully managed. Fog computing is a distributed computing paradigm that acts as a middle layer between cloud data centers and IoT-based devices/sensors. By distributing computing resources closer to edge devices, fog computing enables real-time data processing and analysis. However, one of the key aspects in... 

The airport terminal is difficult to plan and design due to the different components and the intricate complexity of its parts. At the airport terminal, we face a queue system which simulation is always a good way to analyze. In addition, computer simulation using modern softwares with the capability to model different types of systems, including the airport terminal, while being less realistic than analytical models, is less costly than operational Exercise.In this study, a supportive approach for better and specific management of Iranian airport terminal buildings with discrete-event simulation is proposed, considering the need for managing the airport terminals building in the country and... 

Limited water resources in Iran have made dams an important part of the country’s infrastructure. As a result of the large number of in-progress and expected dam projects in the country, consideration of sustainability factors during planning, construction and operation phases of dam projects can create significant economical, social and environmental impacts in the long term. To come up with an inclusive sustainable development, new sustainability assessment approaches seek for sustainable development at the entire project’s life-cycle; they are looking for sustainable development at all design, construction, operation, maintenance and even demolition phases. In this research we have... 

Despite of many advantages, electro submersible pumps (ESP) have very high costs in maintenance. Since ESP usually operates in deep wells, it should be transported to the surface in order to malfunction. In addition, the state of ESP equipment cannot be determined because of unavailability of vibration measurement on the site. Thus, this equipment fails suddenly. This process costs a lot on country’s oil and water & wastewater industry. so in this thesis, at first, the potential failure modes (PFM) of ESPs are investigated, then proper methods are presented for condition monitoring. Finally, the presented methods are verified by experimental tests and wavelet analysis. The results show that... 

In this thesis its considered the characterization of an ultrasound wave in a medium with some obstacles. Derivation of speed of molecules and pressure of the wave is carried out in the Cartesian coordinates system. Simulation is carried out to prove the dependency of wave speed to set up parameters such as the target point (x,y,z) at which the speed value is obtained, the location of the obstacles, the amplitude of original wave emitting from the source, and the propagation speed in different layers of the medium. From the numerical results, it is apparent that the amplitude of the speed wave gets degraded as the wave travels through the medium which is a function of reflection and... 

Carl Jung's analytical psychology is a psychoanalytic theory that has been established with the assumption of the existence of a collective and inheritable unconscious containing archetypes. The archetypes are psychic patterns that have evolved throughout human history and are inherited by human infants. Repressing these innate and universal properties can cause psychic problems for humans. Those repressed innate properties could emerge indirectly to keep the mental balance, but this may cause problems due to being out of conscious control of the individual. According to Jung's claim, remembering and accepting these repressed identities and then integrating the conscious and unconscious... 

Nowadays, most of businesses are becoming computer-based. This trend causes the organizations to become more vulnerable to internal and external threats. Internal threats are done through insiders. Insiders unlike outsiders have capabilities which aid them to easily carry out their illicit activities. Unfortunately, most of research in computer security has focused on the outsider threats, whereas the most damaging is the result of insiders’ illicit activities.This dissertation addresses three primary necessities of the research in the area of insider threat: a consistent definition of insider threat, a classification of types of insider threats, and a classification of vulnerabilities which... 

Integrity of closed-loop systems with integral action control is characterized by using a series of successively more difficult to obtain conditions: Integral Stabilizable (IS), Integral Controllable (IC), Integral Controllable with Integrity (ICI), and Decentralized Integral Controllability (DIC). The IS condition requires that for a Linear Time-Invariant (LTI) finitedimensional (FD) plant, G(s), one finds a stabilizing decentralized controller with integral action. For G(s) to be IC, in addition to being IS, one should be able to reduce the gain of
all control loops by the same factor from a finite value to (but not including) zero without introducing instabilities. ICI requires that... 

This project focuses on the Tennessee East-man challange problem(TEP) and the impact of setpoint changes and controller tunning on plant performance and profitability. TE has four major units. it is an unstable system due to the reaction within the reactor and a recycle streamcausing snow ball effect. As a result the control of this system is not easy. The study has been conducted along two main directions. First, selecting the optimal values for the setpoints and applying them in the simulation. secondly, try to find better parameter for controller in simulation. Simulation is based on working of Ricker. In TEP like the other multivariable systems, it is ameanable to use a centralized... 

Intraction in multi input multi output (MIMO) system makes control of these systems difficult.There are two ways to control such systems; Centralized and Decentralized control. One way in which a centralized controller is designed is using a precompensator. With application of the pre-compensator, the MIMO sytem is decoupled into several SISO systems and one can control these seperatly. Almost all previews methods for the design of pre-compensator assume that the model of the plant containsno uncertainties.In this thesis a new method is proposed which takes into account model uncertaintes in the design of the pre-compensator.The form of the uncertainties considred an interval-parametric  

Decentralized control is a typical method for the design of industrial MIMO control systems. However, in most multivariable systems, the existence of large interactions limit the achievable performance of such controllers. In the Nyquist Array design method proposed by Rosenbrock, the system interactions can be reduced using a precompensator, such that a decentralized controller may be used with acceptable performance. A well designed pre-compensator will effectively decouple the system and the multivariable systems may be considered as a set of SISO systems. It is therefore obvious that the key element in the Nyquist Array design method is the design of the pre-compensator. There are two... 

For increasing longevity of a structure, it is not enough to notice only to designing aspects. In operation phase of a construction, we can increase the level of service and longevity. Asset-based Organizations, in addition to design their new assets, should maintain them. Infrastructures, such as road, bridge, dam, and water network, are important because of social and economic aspects. So they need special attention. There are efficient models for infrastructure maintenance that consider infrastructure element information, such as condition rate, weight, dimensions, deterioration rate, and cost of maintenance as inputs and give planning for maintenance in future. This planning, involves a...