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Synthesis and Characterization of Electrospun N/S Doped ZnO and Investigation of their Applications in Dye Degradation
, M.Sc. Thesis Sharif University of Technology ; Poujavadi, Ali (Supervisor)
Abstract
In this research, the synthesis of the electrospum nano fiber doped zinc oxide and its photocatalyst usage was investigated. The band gap of the zinc oxide in the area of UV leads to deactivation of this material at the visible light. With due the attention to sunny weather in Iran and the fact that about 50 percentage of sunlight is visible light, producing and usage of catalyst materials actived at visible light is economical. Doping is one of the ways of activating ZnO at visible light, so in this research thiourea is used as the source of ZnO doping. The results of the expriments done at visible light and also spectrums of DRS, XPS and XRD prove that the doping is happened. Also, in this...
Intra-Articular Drug Delivery System for the Treatment of Inflammatory Arthritis
, M.Sc. Thesis Sharif University of Technology ; Abdekhodaie, Mohammad Jafar (Supervisor)
Abstract
The objective of this research is to design a drug delivery system that allows anti-inflammatory drugs to be injected directly into the joint (intra-articular injection) for the treatment of arthritis so that reduce the side effects associated with oral consumption of these drugs, increase the duration of drug retention in the joint environment, and reduce the side effects caused by repeated injections while improving effectiveness. To achieve this, first, desirable features were determined by considering the anatomy of the joint environment, the biological changes caused by the disease, and reviewing published articles and commercial products in the field; appropriate drug and raw materials...
Simulating the Effect of Cuff Pressure on Brachial Artery for Calculating the Photoplethysmography(PPG) Singnal
, M.Sc. Thesis Sharif University of Technology ; Firoozabadi, Bahar (Supervisor) ; Saeedi, Mohammad Saeed (Supervisor)
Abstract
One of the most important reasons of death in today’s world is the diseases related to cardiovascular system. Hypercholesterolemia is one of the most common forms of these diseases. There are a lot of experiments for diagnosing this disease, which are classified into two groups: invasive and noninvasive experiments. One of the well-known noninvasive experiments in this area is the photoplethysmography in which the changes of the photoplethysmography signal can reveal some valuable information about the cardiovascular system’s health.The objective of this study is to simulate the photoplethysmography experiment considering the clinical conditions of the experiment. In this work, the obtained...
Investigating the Impact of International Policies on Supply Chain Management in Oil, Gas, and Petrochemical Industries
, M.Sc. Thesis Sharif University of Technology ; Najafi, Mehdi (Supervisor) ; Rafiee, Majid (Supervisor)
Abstract
Policies affect supply chain management in oil, gas and petrochemical industries. In this study, structural equation modeling was used to evaluate the relationship between variables in AMOS software. The findings also indicated that international policies affect different aspects of supply chain management in the following order: product realization management (coordination), customer delivery management (partnership), planning management (planning) and resource management (implementation). Finally, suggestions were made on how to find financing such as bank loans, prioritizing payments in the light of their criticality, as well as on the creation. This study aimed to investigate the impact...
An exploratory study on application of various classification models to distinguish switchable-hydrophilicity solvents based on 3D-descriptors
, Article Separation Science and Technology (Philadelphia) ; 2020 ; Shiri, F ; Sharif University of Technology
Taylor and Francis Inc
2020
Abstract
A set of solvents were classified into the switchable-hydrophilicity solvents (SHSs) and non-switchable-hydrophilicity solvents based on forming or not forming a biphasic mixture with water. SHSs have been developed to make the reaction and product separation processes easier. Herein, three classifier algorithms and various feature selection techniques relay on 3D-molecular descriptors to characterize chemicals and forecast their classes were employed. Cfs-SVM method was employed to perform a classification study. The importance of this study helps to understand more about the presence of hydrophobic groups, their position, and their shape in the molecule. © 2020, © 2020 Taylor & Francis...
An exploratory study on application of various classification models to distinguish switchable-hydrophilicity solvents based on 3D-descriptors
, Article Separation Science and Technology (Philadelphia) ; Volume 56, Issue 5 , 2021 , Pages 961-969 ; 01496395 (ISSN) ; Shiri, F ; Sharif University of Technology
Bellwether Publishing, Ltd
2021
Abstract
A set of solvents were classified into the switchable-hydrophilicity solvents (SHSs) and non-switchable-hydrophilicity solvents based on forming or not forming a biphasic mixture with water. SHSs have been developed to make the reaction and product separation processes easier. Herein, three classifier algorithms and various feature selection techniques relay on 3D-molecular descriptors to characterize chemicals and forecast their classes were employed. Cfs-SVM method was employed to perform a classification study. The importance of this study helps to understand more about the presence of hydrophobic groups, their position, and their shape in the molecule. © 2020 Taylor & Francis Group, LLC
Improved Supply Chain Management Performance by Applying Hybrid Forecast Method
, M.Sc. Thesis Sharif University of Technology ; Hajji, Alireza (Supervisor)
Abstract
In today’s competitive world, using an efficient forecast method is necessity for companies. To now, many forecast methods have been developed, but many of them have not an expected efficiency. In this research, we develop a new hybrid forecast method with application of forecasting retails demand. The hybrid method is the combination of ARIMA method and neural networks. To test the efficiency of the method we use the 96 weeks data of plastic containers demand. We also comprise the hybrid method with other forecast methods including naïve method, ARIMA method and neural network method by applying root mean square error and mean absolute percentage error indexes. In the case of plastic...
Modification of carbohydrate polymers via grafting in air. 1. Ceric-Induced synthesis of starch-g-polyacrylonitrile in presence and absence of oxygen [electronic resource]
, Article Starch - Starke ; Volume 54, Issue 3-4, pages 140–147, April 2002 ; Zohurian Mehr, Mohammad J
Abstract
Monomer grafting, a unique technique for polysaccharide modification, is always performed under inert (e.g., N2) atmosphere. This work is the first report related to evaluating the possibility and efficiency of the grafting of acrylonitrile (AN) onto starch in presence of oxygen. Thus, corn starch (in both granular and gelatinized states) as well as soluble starch were grafted by AN using a ceric-carbohydrate redox initiating system. Graft copolymerizations were performed under nitrogen, air, and oxygen atmospheres at similar conditions. Grafting occurrence was verified using chemical and spectral proofs. The polymerization mechanism and kinetics were investigated by recording the...
Modification of carbohydrate polymers via grafting in Air. 2. Ceric-Initiated graft copolymerization of acrylonitrile onto natural and modified polysaccharides [electronic resource]
, Article Starch - Stärke ; Volume 54, Issue 10, pages 482–488, October 2002 ; Zohuriaan-Mehr, Mohammad J
Abstract
Acrylonitrile (AN) was grafted onto various natural and modified polysaccharides (i.e., gum arabic, gum tragacanth, xanthan gum, sodium alginate, chitosan, sodium carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose) by using ceric-carbohydrate redox initiating system. After overcoming practical problems, mainly from the high viscosity of the aqueous solutions of the different substrates, the graft copolymerization reactions were run either in air or in N2 atmosphere under similar conditions. Grafting was confirmed using chemical and spectral (FTIR) proofs. The reactions were kinetically investigated using semi-empirical expressions and time-temperature profiles. An anomalous...
Modeling of in Plane Behavior of Retrofitted Adobe Walls with Finite Element Method under Cyclic Loading
, M.Sc. Thesis Sharif University of Technology ; Bakhshi, Ali (Supervisor) ; Ghannad, Mohammad Ali (Co-Advisor)
Abstract
Statistical studies indicate the fact that in Iran, like many other developing countries, a significant percentage of buildings are made of traditional materials and most of them are adobe buildings especially in rural areas. Furthermore, geological data indicates that Iran is located in alps-Himalayas seismic zone and exposed by destructive earthquakes and adobe buildings suffer the most damages comparing with other type of the structures. According to these explanations, this research deals with adobe buildings behavior and provides solutions for reinforcing them and improving the seismic response of these buildings. These studies include numerical modeling with finite elements methods by...
Silica chloride/wet SiO2 as a novel heterogeneous system for the deprotection of acetals under mild conditions [electronic resource]
, Article Phosphorus, Sulfur, and Silicon and the Related Elements ; Volume 178:2667-2670, Issue 12, 2003 ; Pourjavadi, Ali ; Zolfigol, Mohammad Ali ; Bamoniri, Abdolhamid
Abstract
A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition
Modeling of photoplethysmography signal for quantitative analysis of endothelial cells during reactive hyperemia
, Article 2012 19th Iranian Conference of Biomedical Engineering, ICBME 2012 ; 2012 , Pages 174-178 ; 9781467331302 (ISBN) ; Firoozabadi, B ; Saidi, M. S ; Sharif University of Technology
2012
Abstract
In this study, at first the cardiovascular system is modeled based on the 1D method and then the simulation of the reactive hyperemia experiment has been applied on the model. In this simulation, by applying a cuff at the brachial artery, the flow downstream of the cuff is occluded. Then with releasing the cuff immediately, a large amount of shear stress, about 4 times the basal amount, is applied downstream of the cuff and consequently to the endothelial cells in a very short moment. Considering a reported experimental transfer function between shear stress and vasodilation, the increase of the artery diameter due to the sudden increase of the shear stress is obtained. Finally, the...
Distributed Fault-tolerant Computation for Massive Data
, M.Sc. Thesis Sharif University of Technology ; Maddah-Ali, Mohammad Ali (Supervisor)
Abstract
In this thesis we consider the problem of distributed computation by many processors.We mainly concentrate on matrix multiplication problem in this thesis because of its importance. A distributed system consists of N worker processors and one master processor. The master processor should distribute the computation between workers and after computation in each of them, collect the results. In this thesis, we are going to mitigate the effect of straggler processors by using coding methods. Straggler processors can cause delays in the computation time.In this thesis, we firstly introduce a method to multiply any number of matrices in each other. The proposed method occurred in one shot without...
Incomplete Reduction of Iron Ore in a Fluidized Bed Reactor
, M.Sc. Thesis Sharif University of Technology ; Halali, Mohammad (Supervisor)
Abstract
The main goal of current investigation was partial reduction of Fe2O3 available in Hematite-rich ore to Magnetite by Fludization Bed method. The reductive gas, CO, was produced by incomplete combustion of Acetylene and Airmixed in inappropriate ratio. X-Ray Diffraction and X-Ray Florescence analyses were implemented in order to conducting qualitative analysis of present phases before and after reduction of the ore. Quantitative analysis of the same phases was also conducted by Titration. The latter analysis revealed the precise magnitude of available iron in each of the oxide containing phases. The chemical composition of the reactor gas was also determined before and after reduction...
Sequential Competitive Facility Location In Continuous Geometric Space
, M.Sc. Thesis Sharif University of Technology ; Abam, Mohammad Ali (Supervisor)
Abstract
Abstract The problem of competetive facility location can be defined as follows: There are a number of customers in the form of points in space, and two players arrange a number of facilities in the form of points in space, given some limitations, respectively. Each customer’s connection to each facility has a cost for the customer and an advantage for the facility, and each customer wants to be connected to at most one of the facilities which has the lowest cost for him. The goal is to find the strategy of placing the facilities and determining the cost which the facility receives from the customer, in such a way that the player’s profit is maximised.In this thesis, we first sought to...
Distributed Verifiable Computing: Algorithms and Analysis
, M.Sc. Thesis Sharif University of Technology ; Maddah Ali, Mohammad Ali (Supervisor)
Abstract
Zero knowledge proofs allow a person (prover) to convince another person (verifier) that he has performed a specific computation on a secret data correctly, and has obtained a true answer, without having to disclose the secret data. QAP (Quadratic Arithmetic Program) based zkSNARKs (zero knowledge Succinct Non-interactive Argument of Knowledge) are a type of zero knowledge proof. They have several properties that make them attractive in practice, e.g. verifier's work is very easy. So they are used in many areas such as Blockchain and cloud computing. But yet prover's work in QAP based zkSNARKs is heavy, therefore, it may not be possible for a prover with limited processing resource to run...
Privacy Preserving Communication Schemes for Light Clients in Blockchain Networks: Algorithms and Analysis
, M.Sc. Thesis Sharif University of Technology ; Pakravan, Mohammad Reza (Supervisor) ; Maddah Ali, Mohammad Ali (Co-Supervisor)
Abstract
Lightweight clients are a type of blockchain users who do not store all the blocks in the blockchain due to limited resources. These users store only a small part of each block and when needed, request transactions from full nodes that store the entire blockchain. These users have no role in block validation and only want to receive transactions related to their addresses with proof of the inclusion in the block from full nodes.Since light clients rely on full nodes for receiving transactions, their privacy against full nodes is important. The current implementation of Bitcoin uses Bloom filters for privacy, but this offers very little privacy to the users.In this thesis, we study the...
Multi independent latent component extension of naive bayes classifier
, Article Knowledge-Based Systems ; Volume 213 , 2021 ; 09507051 (ISSN) ; Hediehloo, A ; Shiri Harzevili, N ; Sharif University of Technology
Elsevier B.V
2021
Abstract
Naive Bayes (NB) classifier ease of use along with its remarkable performance has led many researchers to extend the scope of its applications to real-world domains by relaxing the conditional independence assumption of features given the information about the class variable. However, fulfilling this objective, most of the generalizations, cut their own way through compromising the model's simplicity, make more complex classifiers with a substantial deviation from the original one. Multi Independent Latent Component Naive Bayes Classifier (MILC-NB) leverages a set of latent variables to preserve the overall structure of naive Bayes classifier while rectifying its major restriction. Each...
Coded Computing for Distributed Machine Learning
, Ph.D. Dissertation Sharif University of Technology ; Maddah Ali, Mohammad Ali (Supervisor)
Abstract
Nowadays, we are forced to use distributed computing due to the growth of data, the challenge of storing and processing it, as well as the emergence of new problems in machine learning and the complexity of the models. In distributed computing, the computation is per- formed by a distributed system consisting of several worker nodes such that, the main task is divided into several smaller tasks and assigned to each worker node. Then, different worker nodes will cooperate to accomplish the main task. Although distributed systems are efficient in solving problems and dealing with the mentioned challenges, they are vulnerable to the presence of stragglers, adversarial worker nodes, high...
Designing Online Algorithm for Admission Control in Payment Channel Networks
, M.Sc. Thesis Sharif University of Technology ; Maddah Ali, Mohammad Ali (Supervisor)
Abstract
Payment channel networks (PCNs) are a promising technology to improve the scalability of cryptocurrencies. Users can send instant and almost free transactions via payment channel networks and, at the same time, enjoy the security guarantees of Blockchains. In order to open a mutual payment channel, two users should send a ``channel creation" transaction to the underlying Blockchain. Through this transaction, two parties deposit some money on the Blockchain. This money, which we call the channel's capacity, can be used to send off-chain transactions between the two users. After the channel creation, the channel-holders can send each other off-chain transactions by forwarding the money back...