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Capability of TiO2(B)-based Nanotubes to Adsorb Lithium Ion from Aqueous Solution
, M.Sc. Thesis Sharif University of Technology ; Askari, Masoud (Supervisor) ; Alamolhoda, Ali Asghar (Supervisor)
Abstract
Due to the technology advancement and the large-scale application of lithium-ion batteries in recent years, the market demand for lithium is growing rapidly and the availability of land lithium resources is decreasing significantly. As such, the focus of lithium extraction technologies has shifted to water lithium resources. Among various aqueous recovery technologies, the lithium ion-sieve (LIS) technology is considered the most promising one. This is because LISs are excellent adsorbents with high lithium uptake capacity, superior lithium selectivity, and good cycle performance. TiO2-based nanotubes are an appropriate option for adsorbing lithium from solution due to their high specific...
An approximate method for the surge response of the tension leg platform
, Article Journal of Marine Science and Application ; Vol. 13, issue. 1 , March , 2014 , p. 99-104 ; Tabeshpour, M. R ; Sharif University of Technology
2014
Abstract
The solution for the Duffing equation in a nonlinear vibration problem is studied in this paper. Clearly, in the case of the perturb parameter being a larger value, the traditional perturbation method is no longer valid but the Homotopy Perturbation Method (HPM) is applicable usually. HPM is used to solve the weak and strong nonlinear differential equations for finding the perturbed frequency of the response. The obtained frequencies via HPM and the approximate method have good accordance for weak and strong nonlinear differential equations. Additionally, the calculated responses by use of the approximate method are compared with the responses obtained from the Numerical method in the time...
Optimization of The Engine Mounts to Create the Desired Stiffness to Reduce Noise and Vibration
, M.Sc. Thesis Sharif University of Technology ; Nejat, Hossein (Supervisor) ; Salarieh, Hassan (Supervisor)
Abstract
In order to isolate the engine from the body of the car and chassis to reduce transient vibrations, an engine mount system is used. Using its flexible rubber components, the engine grip keeps the car's engine suspended, allowing it to shift power to the body and chassis. The purpose of this project is to optimize the geometry of the engine mount to achieve the desired static and dynamic stiffness values simultaneously. In this regard, by defining the hyperlastic and viscoelastic properties of the material used in the engine mount, we simulated the static stiffness and dynamic stiffness values of one of the most common engine mounts in the automotive industry. Then we investigate the effect...
Synthesis-structure-performance correlation for poly-aniline-Me-C non-precious metal cathode based on mesoporous carbon catalysts for oxygen reduction reaction in low temperature fuel cells
, Article Renewable Energy ; Volume 77 , 2015 , Pages 558-570 ; 09601481 (ISSN) ; Samiee, L ; Fattahi, M ; Seifkordi, A. A ; Shoghi, F ; Maghsodi, A ; Sharif University of Technology
Elsevier Ltd
2015
Abstract
In this work, attempt is made to development of active non-precious metal catalysts (NPMCs) for the oxygen reduction reaction in polymer electrolyte fuel cells (PEFCs) based on the heat treatment of poly-aniline/transition metal/carbon precursors. All the materials have been characterized by X-ray diffraction (XRD) small and wide angle, N2 adsorption-desorption isotherms, high-resolution transmission electron microscopy (TEM), Scanning electron microscope (SEM) and X-ray photo-electron spectroscopy (XPS). Moreover for electrochemical evaluation of samples, Rotating Disk electrode (RDE) technique and Fuel Cell test were employed. The results showed that onset potential for the optimized...
Spinel H4Ti5O12 nanotubes for Li recovery from aqueous solutions: Thermodynamics and kinetics study
, Article Journal of Environmental Chemical Engineering ; 2020 ; Shahnaz, G ; Askari, M ; Khosravi, A ; Hasan Zadeh, A ; Alamolhoda, A. A ; Sharif University of Technology
Elsevier Ltd
2020
Abstract
In this study, H4Ti5O12 nanotubes have been prepared as Li+ adsorbent by acid treatment of Li4Ti5O12 nanotubes. Li4Ti5O12 nanotubes were synthesized via a hydrothermal method in which TiO2(B) nanNotubes were used as a precursor. The prepared Li-ion sieve showed a significant high ion-exchange capacity (160.6 mgg-1) for lithium ions due to its large specific surface area of 115.4 m2 g-1 compared to the other related studies. The kinetics and isotherm investigation revealed that the pseudo-second-order equation well described the adsorption kinetics, and the Langmuir model well fitted the isotherm data. Furthermore, the low value of adsorption energy obtained from the Dubinin-Radushkevitch...
Spinel H4Ti5O12 nanotubes for Li recovery from aqueous solutions: Thermodynamics and kinetics study
, Article Journal of Environmental Chemical Engineering ; Volume 9, Issue 1 , 2021 ; 22133437 (ISSN) ; Ghasemi, S ; Askari, M ; Khosravi, A ; Hasan Zadeh, A ; Alamolhoda, A. A ; Sharif University of Technology
Elsevier Ltd
2021
Abstract
In this study, H4Ti5O12 nanotubes have been prepared as Li+ adsorbent by acid treatment of Li4Ti5O12 nanotubes. Li4Ti5O12 nanotubes were synthesized via a hydrothermal method in which TiO2(B) nanNotubes were used as a precursor. The prepared Li-ion sieve showed a significant high ion-exchange capacity (160.6 mgg−1) for lithium ions due to its large specific surface area of 115.4 m2 g-1 compared to the other related studies. The kinetics and isotherm investigation revealed that the pseudo-second-order equation well described the adsorption kinetics, and the Langmuir model well fitted the isotherm data. Furthermore, the low value of adsorption energy obtained from the Dubinin-Radushkevitch...
Design and Study of a Resistive Pulse Sensing System with a Tunable Pore
, M.Sc. Thesis Sharif University of Technology ; Taghipoor, Mojtaba (Supervisor) ; Shafii, Mohammad Behshad (Supervisor)
Abstract
Over the last few years, exploiting particle sensing systems for micro-nanoparticles has grabbed much attention. Attaining the physical properties of particles using resistive pulse sensing has been one of the utmost applicable methods of sensing particles. Pores are pivotal elements of systems based on resistive pulse sensing. Two electrodes are placed at both sides of the pore, filling the containers with an electrolyte solution. Pulses of particle translocation across the pore can be recorded by applying a voltage across the electrodes. In more developed versions of resistive pulse sensing systems, pore size is tunable to attain polydisperse particles within a dispersion. In subsequent...
Technical English for mechanical engineers
, Book ; Meghdari,Ali
Sharif University Press
2014
Abstract
Local educational institutions produce in-house English for Specific Purpose (ESP) materials according to the curriculum policies designated and developed by the Ministry of Higher Education In Iran. To this end, this book aims to be used in the Iranian setting at the tertiary level for undergraduate students majoring in Mechanical Engineering. Moreover, the style of English usage in this ESP textbook is American.
Regarding the content of the textbook, it has both thematic organizations in which the topics are relevant and includes sufficient treatment of the target language areas necessary for the students. The principle organizing approach of this textbook is theme-based. In addition,...
Regarding the content of the textbook, it has both thematic organizations in which the topics are relevant and includes sufficient treatment of the target language areas necessary for the students. The principle organizing approach of this textbook is theme-based. In addition,...
Feedback control of the neuro-musculoskeletal system in a forward dynamics simulation of stair locomotion [electronic resource]
, Article Proc. of IMechE Part H: Journal of Engineering in Medicine ; 2009, Vol. 223, No. 6, pp. 663-675 Journal of NeuroEngineering and Rehabilitation ; Volume 11, Issue 1, 30 April 2014, Article number 78 ; Meghdari, Ali ; Vossough, Gholam Reza ; Sharif University of Technology
Abstract
The aim of this study is to employ feedback control loops to provide a stable forward dynamics simulation of human movement under repeated position constraint conditions in the environment, particularly during stair climbing. A ten-degrees-of-freedom skeletal model containing 18 Hill-type musculotendon actuators per leg was employed to simulate the model in the sagittal plane. The postural tracking and obstacle avoidance were provided by the proportional—integral—derivative controller according to the modulation of the time rate change of the joint kinematics. The stability of the model was maintained by controlling the velocity of the body's centre of mass according to the desired centre of...
Design and Construction of a Soft Actuated Exoskeleton for Hand Rehabilitation of Stroke Patients
, M.Sc. Thesis Sharif University of Technology ; Ghafari, Ali (Supervisor) ; Meghdari, Ali (Supervisor)
Abstract
The main goal of this thesis is the design and development of a rehabilitation device for helping patients “to improve blood circulation” & retain and recover their abilities if possible that were lost during the stroke or a accident like that (my research in karaj/iran shows that it is possible by just movement of the specific body part). The focus is on hand in this thesis because Injuries to the hand are common and can be very debilitating since our hands are our primary means for interacting with our world. For rehabilitation in case of human hand there are several practices that should be done for patients either in home or in a rehabilitation center, time and money that is supposed to...
Silica chloride/wet SiO2 as a novel heterogeneous system for the deprotection of acetals under mild conditions [electronic resource]
, Article Phosphorus, Sulfur, and Silicon and the Related Elements ; Volume 178:2667-2670, Issue 12, 2003 ; Pourjavadi, Ali ; Zolfigol, Mohammad Ali ; Bamoniri, Abdolhamid
Abstract
A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition
Earthquake Branch
, M.Sc. Thesis Sharif University of Technology ; Bakhshi, Ali (Supervisor)
Abstract
In the past few decades, shaking tables are widely used to evaluate system response of structures under seismic excitations. These devices are used without any fundamental research performed on a shaking table system as an entity model. In most of these studies for simplicity, it is assumed that there exist no considerable vibration and displacement around the shaking tables, and no attention is paid to the peripheral substances such as soil settled under the foundation.
In this thesis, result of ambient vibration test on shaking table system (solid deck, concrete foundation and soil layer) has been presented. Precise sensors known as low frequency and high accuracy accelerometers have...
In this thesis, result of ambient vibration test on shaking table system (solid deck, concrete foundation and soil layer) has been presented. Precise sensors known as low frequency and high accuracy accelerometers have...
Selective synthesis of conjugated enynes from α-arylalkynols using LiCl-Acidic Al2O3 under solvent-free conditions [electronic resource]
, Article Journal of Chemical Research ; Volume 2002, Number 8, 1 August 2002, pp. 378-380(3) ; Bagheri Marandi, Gholam
Abstract
Free Content Selective synthesis of conjugated enynes from α-arylalkynols using LiCl-Acidic Al2O3 under solvent-free conditions
Selective preparation of fluorescent 1,8-naphthalimides using acidic alumina under microwave irradiation [electronic resource]
, Article Journal of Chemical Research ; 01/2001; 2001(11):485-487 ; Bagheri Marandi, Gholam
Abstract
7H-benzimidazo[2,1-a]benz[de]isoquinolin-7-one compounds were prepared in a selective manner by reaction between o-phenylenediamines and appropriate 1,8-naphthalenedicarboxylic anhydrides using acidic alumina under microwave irradiation
Comparison between Performance of Stone Columns and RAPs from the Bearing Capacity and Settlement Reduction Viewpoints
, M.Sc. Thesis Sharif University of Technology ; Pak, Ali (Supervisor)
Abstract
Out of several ground improvement techniques available, stone columns have been widely used. This technique has been successfully applied to increase the bearing capacity and to reduce the settlement for foundation of structures like liquid storage tanks, earthen embankments, raft foundations, etc., where a relatively large settlement is permissible. This technique has, generally, been proven successful in increasing the stiffness of weak soils, upgrading their safe bearing capacity, and reducing their total and differential settlements, as well as speeding up their consolidation process. The beneficial effects of stone column installation in weak deposits is manifested in the form of...
Performance of Partially Filled Mini-Channels with Porous Media
, M.Sc. Thesis Sharif University of Technology ; Nouri, Ali (Supervisor) ; Moosavi, Ali (Co-Advisor)
Abstract
Laminar forced convection flow through a channel partially filled with a porous material was numerically studied in this thesis. The Navier-Stokes and Brinkman-Forchheimer equations were used to model the fluid flow in the free and porous regions, respectively. Coupling of the pressure and velocity fields was resolved using the SIMPLEC algorithm. The local thermal equilibrium was adopted in the energy equation. The effects of the thermal conductivity ratio, Darcy number, porosity, Reynolds number and height of the porous insert on velocity and temperature field were investigated. The results show that the flow behavior and its associated heat transfer are susceptible to the variation of the...
Improvement of Stability of Haptic Force Interaction with Virtual Environments Using a Haptic Interface with a Separate Tracker
, M.Sc. Thesis Sharif University of Technology ; Meghdari, Ali (Supervisor) ; Nahvi, Ali (Supervisor)
Abstract
In the present study, a new version of haptic devices is presented in which user’s hand is in contact with the device just while collision with virtual surface. In this system, the position of user’s finger can be traced by using a camera and the haptic device follows user’s finger at the distance of about two centimeters. While the haptic device approaches to the virtual surface, gradually reduces its speed and stops about two centimeters distant of virtual plane. Then user’s hand collides with the haptic device which is static. Greater fidelity, transparency, more stability and also no need to large actuators are of the advantages of this system. In this project, first we present a new...
Simulation of the Biomolecule Imaging and Manipulation Via AFM by Molecular Dynamics Method
, M.Sc. Thesis Sharif University of Technology ; Meghdari, Ali (Supervisor) ; Moosavi, Ali (Supervisor)
Abstract
In this thesis we try to find optimized parameters for imaging and manipulation of a biosample with AFM. For this we have prepared a numerous Molecular Dynamics simulation and find some reliable result. So, first we have focused on imaging process in Non contact mode (the less harmful mode). Then we headed into the manipulation process. The main problem about manipulating a biosample is the environment. In imaging section, the process of imaging a biomolecule by AFM is modeled using molecular dynamics simulations. Since the large normal force exerted by the tip on the biosample in contact and tapping modes may damage the sample structure and produce irreversible deformation, the non-contact...
Characterzing Variation of Small Strain Shear Modulus of Unsaturated Sand During Hydraulic Hysteresis with Bender Elements
, M.Sc. Thesis Sharif University of Technology ; Pak, Ali (Supervisor) ; Khosravi, Ali (Supervisor)
Abstract
Results of previous studies on silt and clay indicated that variations in the small strain shear modulus, Gmax, during drying had a non-linear increasing trend with matric suction with greater values upon wetting. However, due to different material properties and inter-particle forces, different behaviour in Gmax is expected for sand. Although considerable research has been devoted in recent years to characterize the behaviour of Gmax of sand during drying, rather less attention has been paid to the effect of hydraulic hysteresis on Gmax and its variations during wetting. In the study presented herein, an effort was made to characterize the variation of Gmax for specimens of sand during...
Sequential Competitive Facility Location In Continuous Geometric Space
, M.Sc. Thesis Sharif University of Technology ; Abam, Mohammad Ali (Supervisor)
Abstract
Abstract The problem of competetive facility location can be defined as follows: There are a number of customers in the form of points in space, and two players arrange a number of facilities in the form of points in space, given some limitations, respectively. Each customer’s connection to each facility has a cost for the customer and an advantage for the facility, and each customer wants to be connected to at most one of the facilities which has the lowest cost for him. The goal is to find the strategy of placing the facilities and determining the cost which the facility receives from the customer, in such a way that the player’s profit is maximised.In this thesis, we first sought to...