Sharif Digital Repository

The temperature and voltage dependence of spin transport is theoretically investigated in a new type of magnetic tunnel junction, which consists of two ferromagnetic outer electrodes separated by a ferromagnetic barrier and a nonmagnetic (NM) metallic spacer. The effect of spin fluctuation in magnetic barrier, which plays an important role at finite temperature, is included by taking the mean-field approximation. It is found that, the tunnel magnetoresistance (TMR) and the electron-spin polarization depend strongly on the temperature and the applied voltage. The TMR and spin polarization at different temperatures show an oscillatory behavior as a function of the NM spacer thickness. Also,... 

The spin-polarized transport is investigated in a new type of magnetic tunnel junction which consists of two ferromagnetic electrodes separated by a magnetic barrier and a nonmagnetic metallic spacer. Based on the transfer matrix method and the nearly-free-electron approximation the dependence of the tunnel magnetoresistance (TMR) and electron-spin polarization on the nonmagnetic layer thickness and the applied bias voltage are studied theoretically. The TMR and spin polarization show an oscillatory behaviour as a function of the spacer thickness and the bias voltage. The oscillations originate from the quantum well states in the spacer, while the existence of the magnetic barrier gives rise... 

In the present article, thermal behavior and heat transfer deterioration (HTD) of transcritical methane as well as the fluid state change in regenerative cooling with straight/curved rectangular channels are studied numerically. Simulations are conducted with a finite-volume based CFD solver utilizing reliable turbulence models and thermo-fluidic relations in transcritical conditions. The experimental and numerical results of hydrogen inside a heated tube in the literature are used for validation. The effects of mass flow rate, outlet pressure, wall temperature, surface roughness, and the channel geometry on the thermal behavior of the coolant fluid are studied in detail. According to the... 

In this article, the conjugate heat transfer of the methane coolant inside a rectangular channel is studied and the related Nusselt correlations are improved. The compressible methane flow enters the cooling channel at supercritical pressure and subcritical temperature. The coolant flow absorbs heat from the heated walls and exits the channel with a supercritical temperature. An in-house solver is developed employing Semi-Implicit Method for Pressure-Linked Equations-Consistent (SIMPLEC) algorithm accompanied by the appropriate thermodynamic and transport property relations for the supercritical conditions of the methane coolant. The solver is validated with the experimental data found in... 

Analytical studies on the effect of charge and magnetic impurities in a spin-polarized electron gas (SPEG) are carried out using a Thomas-Fermi semiclassical approximation (TFSA). The susceptibility matrix of an SPEG is calculated within the TFSA framework. Charge, spin and mixed charge-spin screening lengths are defined and calculated for the bulk metals (Fe, Co and Ni). It is found that these screening lengths do not strongly depend on temperature in metallic samples. Based on the Ruderman-Kittel-Kasuya-Yoshida (RKKY) model, the magnetic response function is then used to calculate the dependence of the exchange coupling between two ferromagnetic layers. It is seen that the exchange... 

The pK a of an acyclic aliphatic heptaol ((HOCH 2CH 2CH(OH)CH 2) 3COH) was measured in DMSO, and its gas-phase acidity is reported as well. This tertiary alcohol was found to be 10 21 times more acidic than tert-butyl alcohol in DMSO and an order of magnitude more acidic than acetic acid (i.e., pK a = 11.4 vs 12.3). This can be attributed to a 21.9 kcal mol -1 stabilization of the charged oxygen center in the conjugate base by three hydrogen bonds and another 6.3 kcal mol -1 stabilization resulting from an additional three hydrogen bonds between the uncharged primary and secondary hydroxyl groups. Charge delocalization by both the first and second solvation shells may be used to facilitate... 

A nanoscale logic NOR gate has been theoretically designed by magnetic flux inputs in a Z-shaped graphene nanoribbon composed of an armchair ribbon device sandwiched between two semi-infinite metallic zigzag ribbon leads. The calculations are based on the tight-binding model and iterative Green's function method, in which the conductance as well as current-voltage characteristics of the nanosystem are calculated, numerically. We show that the current and conductance are highly sensitive to both the magnetic fluxes subject to the device and the size of the system. Our results may have important applications for building blocks in the nanoelectronic devices based on graphene nanoribbons  

Theoretical studies on the spin-dependent transmission and current-voltage characteristic in a mesoscopic system, which consists of two semi-infinite ferromagnetic (FM) leads (as source and drain) separated by a typical periodic quantum dot (QD) are presented. The calculations are based on the tight-binding model and transfer matrix method, and investigate the magnetoresistance (MR) and the spin polarization within the Landauer-Büttiker formalism. The spin-dependent transport behavior can be controlled via a gate voltage and an applied bias in the ballistic regime. The numerical results are shown for a periodic polymer chain with nonmagnetic (NM) and FM leads, and also, with two FM leads.... 

Developing extremely efficient electrocatalysts for oxygen evolution reactions (OER) is a decisive step toward the progression of rechargeable metal-oxygen batteries, CO2 reduction, and water-splitting. Nanoporous high-entropy transition-metal sulfides (np-HETMS) represent a new generation of promising OER catalysts by virtue of their exceptional catalytic activity. However, their synthesis maintains to be a challenge by reason of the thermodynamic immiscibility of the constituting multi-principal metallic elements in the sulfide structure. Herein, for the first time, the np-HETMS ((CoFeNiMnCu)S2) nanoparticles with pyrite-phase was synthesized via a facile and easy adaptable... 

Nanoparticles of high-Z elements exhibit stronger photoelectric effects than soft tissues under gamma irradiation. Hence, they can be used as effective radiosensitizers for increasing the efficiency of current radiotherapy. In this work, superparamagnetic zinc ferrite spinel (ZnFe2O4) nanoparticles were synthesized by a hydrothermal reaction method and used as radiosensitizers in cancer therapy. The magnetic nanoparticles showed fast separation from solutions (e.g., ~ 1 min for 2 mg mL- 1 of the nanoparticles in ethanol) by applying an external magnetic field (~ 1 T). The ZnFe2O4 nanoparticles were applied in an in vitro radiotherapy of lymph node carcinoma of prostate cells (as high... 

Like-charge ion pairing is commonly observed in protein structures and plays a significant role in biochemical processes. Density functional calculations combined with the conductor-like polarizable continuum model were employed to study the formation possibilities of doubly charged noncovalently linked complexes of a series of model compounds and amino acids in the gas phase and in solution. Hydrogen bond interactions were found to offset the Coulombic repulsion such that cation-cation clusters are minima on the potential energy surfaces and neither counterions nor solvent molecules are needed to hold them together. In the gas phase the dissociation energies are exothermic, and the... 

In this paper, the project earthquake occurrence risk coefficient is determined for each construction project that is located in one of Iran's twenty seismic regions. This coefficient is allocated, regardless of the current situation of the project, being in the plan or execution phase or even completed. This coefficient indicates the possibility of an earthquake occurrence during a project's life time. To find this coefficient, the Gutenberg-Richter linear relationship has been applied, in conjunction with the Poisson distribution. The Gutenberg-Richter linear equation expresses the relationship between the magnitude of an earthquake and the number of occurrences, during a fixed time, of... 

Residential and commercial sectors, share a significant portion of energy consumption in Iran; 37 percent of the total per capita consumption. Therefore, identification of the relation between revenue and energy consumption could be a great assistance to policy makers for clarification of policies employed in energy sector. This paper attempts to explore and analyze the relationship between revenue and energy consumption in residential and commercial sectors for the years 1969 to 2009 in Iran by Smooth Transition Regression Models. Smooth transition regression model is a nonlinear time series model which can be considered as a developed form of Switching Regression Model. The obtained... 

This work explores the pyrolysis characteristics and kinetic behavior of paper-laminated phenolic printed circuit boards (PLP-PCBs) using thermogravimetric analysis under non-isothermal linear heating programs. The initial estimation of the kinetic parameters during the pyrolysis was obtained from the analysis of the experimental data by three isoconversional kinetic models, i.e. Flynn-Wall-Ozawa (FWO) and Kissinger-Akahira-Sunose (KAS) integral methods, as well as the Friedman differential method. For all three methods, the apparent activation energy exhibited a strong dependence on the degree of the reaction conversion. To allow for the complexity of the reactions involved in the PLP-PCB... 

Ischemic cerebral stroke is a major cause of death and morbidity. Currently, no neuroprotective agents have been shown to impact the clinical outcomes in cerebral stroke cases. Here, we report therapeutic effects of Se nanoparticles on ischemic stroke in a murine model. Anti-transferrin receptor monoclonal antibody (OX26)-PEGylated Se nanoparticles (OX26-PEG-Se NPs) were designed and synthesized and their neuroprotective effects were measured using in vitro and in vivo approaches. We demonstrate that administration of the biodegradable nanoparticles leads to resolution of brain edema, protection of axons in hippocampus region, and myelination of hippocampal area after cerebral ischemic...