Sharif Digital Repository

In the present work, several new thermodynamic linear isotherm regularities for the dense fluids have been derived for the first time. For this purpose, the thermodynamic perturbation theory (TPT) employing only the attractive effective pair potential (AEPP) as u(r) = - ϵeff (σeff / r)m was used, where σeff which is the effective hard core diameter, is temperature dependent and m > 0. Based on the derived regularities, the isotherm (Z - Z(0))v2 is a linear function of ρ2, ρ and 1/ρ, depends on the values of m = 12, 9 and 6, respectively where Z - Z(0) is the difference between the experimental compressibility factor of the real fluid (Z) and that of the reference fluid (Z(0)). Also, Z - Z(0)... 

In the present work, the thermodynamic of dense fluids, both compressed liquids and dense supercritical fluids, has been modeled, solely, based on the contribution of attraction of effective pair potential. The intermolecular interaction is modeled by the hard-core Yukawa potential (HCY) as an effective pair potential (EPP) with temperature dependent hard-core diameter. Using this EPP in the exact thermodynamic relations, an equation of state (EoS) for the compressibility factor of dense fluid has been derived. This EoS shows that (Z - ZCS) as function of ρ1/3 must be linear for each isotherm of fluid where ZCS is the compressibility factor of the reference fluid (Carnahan-Starling (CS) EoS)... 

In the present paper, the seismic response of an arch dam subjected to spatial variation of ground motions along the interface with its foundations is investigated. Recorded ground accelerations at the dam foundation interface of an arch dam were used for the purpose of this investigation. Topographic amplification between various points of the interface was studied by obtaining ratios of the response spectral displacement and spectral pseudo acceleration. Time shift and amplification between stations show the nonuniform nature of ground motions for large structures like dams. Recorded ground accelerations were interpolated for different nodes of the finite element model. The seismic... 

A new semi-rigid beam-to-column, as well as bracing-to-frame, connection has been developed. In addition to its application in building structures, due to its special features and characteristics, it can best lend itself to offshore jackets, where fracture caused by fatigue has always been a major concern. The adverse effects of welding, material embrittlement, residual stresses, etc., pronounced by cyclic loading on such structures, can be overcome by using this new connection. Moreover, it can be easily used in the structure of various modules used in the topside of platforms and FPSOs. The particular feature of this connection is its geometry, which is so devised that it allows much... 

Potent carbon-neutral energy carriers bring a vital solution for sustained industrialization and environmental protection. Hydrogen as a novel zero-emission energy carrier offers more than twice energy per unit mass compared to other fuels. Membrane reactor technology transforms gray hydrogen to blue by selective hydrogen separation and carbon dioxide capture from the product mixture. Moreover, improved reactant conversion during reversible steam reforming of methane, methanol, and ethanol; water gas-shift; and dehydrogenation of cyclic and aliphatic hydrocarbons as well as enhanced hydrogen yield are results of selective and distributed hydrogen separation from membrane reactor. In this... 

The photocatalytic degradation of p-nitrophenol (PNP) using TiO2 particles immobilized on a fiberglass cloth was investigated in a novel design of a photo-impinging stream reactor. A spray painted method has been used for the coating process. The structural properties of the immobilized sample were examined using X-ray diffraction and a scanning electron microscope (SEM). The photocatalytic degradation results showed the good performance of the reactor. The flow regime within the reactor was characterized and modeled by applying a liquid residence time distribution. A compartment model consisting of four continuous stirred regions was assigned to describe the flow pattern in the reactor. A... 

This review paper is devoted to the intensification of processes for nitrate removal. First, the developments of microfluidic sensors for nitrate detection and analysis have addressed. Second, the process variables of photocatalytic nitrate removal have been categorized according to their relationship with activity, selectivity and stability of the catalyst. The objective of this classification is to generate guidelines toward the photocatalytic process optimization. Third, because of the fact that a single method for nitrate removal faces some challenges, hybrid methods have been presented, and the best choice for nitrate removal can be referred to as photocatalytic – reverse osmosis... 

This review paper is devoted to the intensification of processes for nitrate removal. First, the developments of microfluidic sensors for nitrate detection and analysis have addressed. Second, the process variables of photocatalytic nitrate removal have been categorized according to their relationship with activity, selectivity and stability of the catalyst. The objective of this classification is to generate guidelines toward the photocatalytic process optimization. Third, because of the fact that a single method for nitrate removal faces some challenges, hybrid methods have been presented, and the best choice for nitrate removal can be referred to as photocatalytic – reverse osmosis... 

Since low-cost RFID systems are applied in ubiquitous varied applications, privacy and security of their users became a great concern. Therefore, the various authentication protocols have been proposed. In this paper, we inspect the three new-found RFID authentication protocols based on quadratic residue property via one of the well-organized formal RFID privacy models instead of intuitive analysis. We formally prove that modular squaring is the suitable technique to guarantee RFID authentication protocols against backward traceability. Then, the flaws are alleviated to resist traceability attacks  

This article presents a methodological approach for controller gain tuning of wind turbines using global optimization algorithms. For this purpose, the wind turbine structural and aerodynamic modeling are first described and a complete model for a 5 MW wind turbine is developed as a case study based on a systematic modeling approach. The turbine control requirements are then described and classified using its power curve to generate an appropriate control structure for satisfying all turbine control modes simultaneously. Next, the controller gain tuning procedure is formulated as an engineering optimization problem where the command tracking error and minimum response time are defined as... 

A twodimensional model, based on conservation of mass, momentum and energy equations, is represented in this paper in which the coke combustion process, for iron ore sintering in a packed bed, is simulated numerically. The aforementioned packed bed consists of iron ore, coke, limestone and moisture. The main objective of iron ore sintering is producing resistant agglomerates which can be used in blast furnaces. For this purpose, the sinter mixture is partially melted in high temperature and finally molten is allowed to cool. The molten production and subsequently, the solidification process are totally dependent on composition and components of mixture. Changes in bed porosity, caused by... 

Superalloys have a poor machinability and are often drilled using Electro Discharge Machining (EDM) methods. However EDM is a time-consuming process and has low surface integrity. Ultrasonic Assisted Drilling (UAD) technology is a modern method of drilling such materials. Although this method has very high capabilities, it has not been introduced widely to industry. In this study a special horn is designed and used to apply both rotation and vibration to drill bits. It can transfer power with high efficiency and has the capability to change tools easily. The setup is used to conduct deep drilling tests on Inconel 738LC with depth-to-diameter ratio of 10. The effect of ultrasonic vibration... 

Many efforts have been made to model bio-processes and investigate the main effective parameters using conventional known softwares. The main shortcoming of such models is that the bioreactor is considered a black box. Such simplification causes uncertainty in following different metabolic pathways of microorganisms. This study presents a new method for simulating bio-processes by integrating available conventional simulation softwares such as ASPEN PLUS and MATLAB. The former is used to simulate common process equipment, and the latter is employed to model Bio-reactor. Besides, the Bio-reactor is modeled mathematically with Dynamic Flux Balance Analysis (DFBA) concept using the metabolic... 

The urine formation and excretion system have long been of interest for mathematicians and physiologists to elucidate the obscurities within the process happens in renal tissue. In this study, a novel three-dimensional approach is utilized for modeling the urine concentrating mechanism in rat renal outer medulla which is essentially focused on demonstrating the significance of tubule's architecture revealed in anatomic studies and physiological literature. Since nephrons and vasculatures work interdependently through a highly structured arrangement in outer medulla which is dominated by vascular bundles, a detailed functional unit is proposed based on this specific configuration.... 

Crystallographic texture is one of the most sensitive parameters for controlling the microstructure of electrodeposited layers. In this work, we study the crystallographic texture of electrodeposited nickel-silicon carbide coatings. The nickel coatings containing SiC nanoparticles and microparticles were electrodeposited from an additive-free sulfate bath containing nickel ions and SiC particles. The effect of current density on the codeposited Ni/SiC was studied. The coatings were analyzed with scanning electron microscopy and X-ray diffraction. Pole figure studies were done to characterize the evolved crystallographic texture. The X-ray scans followed by Rietveld analysis using the... 

The low erosion resistance of titanium and its alloys has prevented their widespread application as joint implants. In addition, one essential requirement for the implants to bond with the living bone is the formation of a bone-like apatite on their surfaces in the host body. To enhance the erosion resistance of the surface, a diffused layer of TiB2 was formed at 1000uC on the commercial pure titanium. Hydroxyapatite was then coated on the boronised titanium by means of dip coating in a sol-gel solution. In order to confirm the biocompatibility of the specimens, they were soaked in a simulated body fluid for several days. The surface morphology of the specimens after exposure was studied by... 

Many theories and mathematical simulations have been proposed concerning urine concentrating mechanism (UCM). The WKM and region approach are the two most valuable methods for compensating the effect of tubule's architecture in renal medulla. They both have tried to simulate tubule's confinement within a particular region mathematically in one spatial dimension. In this study, continuity, momentum and species transport equations along with standard expressions for transtubular solutes and water transports on tubule's membrane were solved numerically in three spatial dimensions which practically is the main significance of our novel approach. Model structure has been chosen as simple as... 

This work describes a very simple, novel and selective spectrophotmetric method for simultaneous determination of sulfamethoxazole and trimethoprim in pharmaceutical preparation and synthetics samples using direct orthogonal signal correction-partial least squares (DOSC-PLS). The all factors affecting on the sensitivity were optimized and the linear dynamic range for determining of these drugs was found. The PLS modeling was used for the multivariate calibration of the spectrophotometric data and DOSC was used for preprocessing of data matrices and the prediction results of model. The experimental calibration matrix was designed by measuring the absorbance over the range 200-400 nm for 32...