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tabatabaee-mehr--mohammad-ali
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Modification of carbohydrate polymers via grafting in air. 1. Ceric-Induced synthesis of starch-g-polyacrylonitrile in presence and absence of oxygen [electronic resource]
, Article Starch - Starke ; Volume 54, Issue 3-4, pages 140–147, April 2002 ; Zohurian Mehr, Mohammad J
Abstract
Monomer grafting, a unique technique for polysaccharide modification, is always performed under inert (e.g., N2) atmosphere. This work is the first report related to evaluating the possibility and efficiency of the grafting of acrylonitrile (AN) onto starch in presence of oxygen. Thus, corn starch (in both granular and gelatinized states) as well as soluble starch were grafted by AN using a ceric-carbohydrate redox initiating system. Graft copolymerizations were performed under nitrogen, air, and oxygen atmospheres at similar conditions. Grafting occurrence was verified using chemical and spectral proofs. The polymerization mechanism and kinetics were investigated by recording the...
Modification of carbohydrate polymers via grafting in Air. 2. Ceric-Initiated graft copolymerization of acrylonitrile onto natural and modified polysaccharides [electronic resource]
, Article Starch - Stärke ; Volume 54, Issue 10, pages 482–488, October 2002 ; Zohuriaan-Mehr, Mohammad J
Abstract
Acrylonitrile (AN) was grafted onto various natural and modified polysaccharides (i.e., gum arabic, gum tragacanth, xanthan gum, sodium alginate, chitosan, sodium carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose) by using ceric-carbohydrate redox initiating system. After overcoming practical problems, mainly from the high viscosity of the aqueous solutions of the different substrates, the graft copolymerization reactions were run either in air or in N2 atmosphere under similar conditions. Grafting was confirmed using chemical and spectral (FTIR) proofs. The reactions were kinetically investigated using semi-empirical expressions and time-temperature profiles. An anomalous...
Effective Action of Non-Local Nambu-Jona-Lasinio Model in a Constant Magnetic Field
, M.Sc. Thesis Sharif University of Technology ; Sadooghi, Neda (Supervisor)
Abstract
In the framework of the Standard Model of Particle Physics, Quantum Chromodynamics (QCD) is known to be the only theory which describes the strong nuclear force. Because of the property of asymptotic freedom, perturbative methods fail to describe QCD at low energies. Here, mesons and baryons build the main degrees of freedom of QCD. To describe the dynamics of mesons at low energies, nonperturbative methods are used. The Nambu–Jona-Lasinio (NJL) model is one of the most important effective models, which is used to study the nonperturbative phenomena of QCD at low energies. The Lagrangian density of this model includes a local four-fermion term,which descibes the interaction between the...
The Effect of Magnetization on the Evolution of the Plasma of Quarks and Gluons
, Ph.D. Dissertation Sharif University of Technology ; Sadooghi, Neda (Supervisor)
Abstract
Quantum Chromodynamics (QCD) is the theory of strong interaction. Two main properties of QCD in low energies are chiral symmetry breaking and confinement. At finite temperature, QCD exhibits a certain transition from a chirally broken phase to a chirally restored phase and liberation of color charge. Lattice QCD at finite temperature shows a crossover transition at vanishing or small chemical potential while the model-dependent studies, e.g. the Nambu-Jona--Lasinio model predicts a first-order phase transition at large chemical potentials. The first order and crossover transition lead to the existence of a critical point in the phase diagram of QCD. Determining the nature of the phase...
New polysaccharide-g-polyacrylonitrile copolymers: synthesis and thermal characterization [electronic resource]
, Article Polymers for Advanced Technologies ; Volume 14, Issue 7, pages 508–516, July 2003 ; Pourjavadi, Ali ; Sharif University of Technology
Abstract
Various natural and modified polysaccharides (i.e. arabic gum, tragacanth gum, xanthan gum, sodium alginate, chitosan, sodium carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose) were modified using ceric-initiated graft polymerization of acrylonitrile under inert atmosphere. Grafting was confirmed using spectral (FT-IR) proofs. The grafting parameters were determined by conventional methods. Thermal characteristics of the homopolymer-free copolymers were studied using differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) under nitrogen atmosphere. The major thermal transitions as well as the activation energy of the major decomposition stages were...
Novel azo-containing polymethacrylates bearing spiroacetal-norbornene moiety and methylene spacers: synthesis and characterization [electronic resource]
, Article European Polymer Journal ; Volume 37, Issue 10, October 2001, Pages 2111–2121 ; Mirjalili, Bibi Fatemeh ; Entezami, Ali A ; Zohuriaan-Mehr, Mohammad J ; Sharif University of Technology
Abstract
An eight-step synthetic strategy was followed to prepare a series of novel azobenzene-containing methacrylate monomers bearing spiroacetal-norbornene moiety and methylene spacers. Thus, the adduct 2, obtained from cyclopentadiene and acrolein, was converted to 1,3-diol 3. The diol was acetalized with nitrobenzaldehyde 4 under microwave irradiation to obtain nitro compound 5 that was then reduced to amino compound 6. Diazonium salt of 6 was coupled with phenol to produce phenolic compound 7 which was then reacted with n-dibromoalkanes (n=2, 4, 6, 8, 10) to yield bromo compounds 9a–e. Nucleophilic substitution reaction of the bromo compounds with lithium methacrylate produced the methacrylic...
, M.Sc. Thesis Sharif University of Technology ; Pourjavadi, Ali (Supervisor) ; Zohurian Mehr, Mohammad Jalal (Supervisor)
Abstract
Polyampholyte hydrogels are hydrophilic networks that contain both positively- and negatively-charged functional groups on their structure. Polysulfobetaines are the most important type of polyampholytes, which have been extensively studied. However, these hydrogels exhibited poor gel strength causing limitation of their applications. Consequently, much attention has been focused on the preparation of nanocomposite hydrogels with high gel strength and lower cost using organomodified clays. In this project, Novel polyampholytic superabsorbing nanocomposites based on the zwitterionic sulfobetaine monomer [3-(methacrylamido)propyl)]dimethyl(3-sulfopropyl) ammonium hydroxide (MPDSAH) were...
Temporal Congestion Games
, M.Sc. Thesis Sharif University of Technology ; Ghodsi, Mohammad (Supervisor)
Abstract
We consider a special class of Congestion Games enhanced with a notion of time.Network Routing problems, such as road traffic networks, computer neworks, and evacuation problems are some applications of this class of games. Two subclasses of these games, namely atomic and non-atomic is considered in this article, both of them introduced in 2009. Some of the existing results are Nash equilibria existence proof for “single-source single-sink” case, and a mechanism for improving price of anarchy in the non-atomic subclass. There are also some results in the atomic subclass of this game.We extend both models of atomic and non-atomic subclasses to “multi-source,multi-sink” configurations. We call...
Study on Chemical Durability of Vitrified High Level Waste in Borosilicate Glass Matrix
, M.Sc. Thesis Sharif University of Technology ; Samadfam, Mohammad (Supervisor) ; Sepehrian, Hamid (Supervisor) ; Yadollahi, Ali (Co-Supervisor)
Abstract
As nuclear energy continues to be used as a useful energy resource, waste management, especially management of high-level nuclear waste (HLW), will always be a major concern, as the future generations should not be deprived of the valuable benefits of this energy. Vitrification of liquid high-level radioactive waste (HLW) has received greater attention, worldwide, than any other high-level waste solidification process. The high solubility of HLW in borosilicate glass, the controllable temperature of this type of glass and its low leaching rate in repository environment, have introduced borosilicate glass as a suitable host for HLW immobilization. In this project, the immobilization of the...
Modified Chitosan. 2. H-chitoPAN, a novel pH-responsive superabsorbent hydrogel [electronic resource]
, Article Journal of Applied Polymer Science ; Volume 90, Issue 11, pages 3115–3121, 9 December 2003 ; Mahdavinia, G. R ; Zohuriaan-Mehr, M. J
Abstract
Chitosan was modified with polyacrylonitrile (PAN) through ceric-initiated graft copolymerization. The chitosan-g-PAN product was saponified using sodium hydroxide aqueous solution to prepare a novel superabsorbent hydrogel, H-chitoPAN. Duration of completing the saponification reaction as well as the water absorbency capacity of the hydrogel was decreased with increasing the alkaline concentration. Either chitosan-g-PAN or H-chitoPAN was characterized by FTIR spectroscopy and DSC, TGA, and DTG thermal methods. According to FTIR, all the nitrile groups were converted to carboxylate and carboxamide groups. Both modified chitosans exhibited enhanced thermal stability over chitosan. The...
Geochemical Simulation of Acidizing Sandstone Core Samples
, M.Sc. Thesis Sharif University of Technology ; Bazargan, Mohammad (Supervisor)
Abstract
Acidizing is one of the widely used practices of formation damage remediation. The success of this rather expensive job depends on the precise design and operation. Though, improper execution of an acid job, not only does not improve the formation damage but also can contribute to even more damage itself. For this purpose, it is critically important to thoroughly design an acidizing job conducting extensive lab experiments and utilizing numerical tools before operation in order for a successful acidizing. Unlike, carbonate acidizing, the chemistry of sandstone acidizing is very complex and challenging because of the wide variety of minerals and aqueous species present in the system. Hence, a...
Particle Production: From Inflationary Era to Reheating
, M.Sc. Thesis Sharif University of Technology ; Abolhassani, Ali Akbar (Supervisor)
Abstract
In this project, in general, we have studied the particle production during and after the Inflation.Today, the Inflation is considered as a part of the standard model of cosmology and it solves so-called two cosmological problems: flatness and horizon problem. According to it,the universe after the inflation becomes supercool; however, the thing we observe today is in contradiction with this theory. The Reheating era is a time period in which the inflationary field gets to its minimum of potential and starts to socialite. Actually, here is the place in which the phenomenon of the particle production occurs. This period is called the Reheating era. therefore, it seems all particles which we...
Modified CMC: part 1- optimized synthesis of carboxymethylcellulose-g-polyacrylonitrile [electronic resource]
, Article Iranian Polymer Journal ; Vol. 14, No 2, 131-138, 2005 ; Pourjavadi, A ; Sadeghi, M
Abstract
As the first part of a continued research on conversion of carboxymethyl cellulosesodium salt (CMC) to useful biopolymer-based materials, large numbers of cyanide functional groups were introduced onto CMC by grafting with polyacrylonitrile (PAN). The graft copolymerization reactions were carried out under nitrogen atmosphere using ceric ammonium nitrate (CAN) as an initiator. Evidence of grafting was obtained by comparing FTIR spectra of CMC and the graft copolymer as well as solubility characteristics of the products. The synthetic conditions were systematically optimized through studying the effective factors including temperature and concentrations of initiator, acrylonitrile monomer,...
Synthesis, chemical and thermal characterization of poly(cis-2-butenylene oxalate) [electronic resource]
, Article International Journal of Polymeric Materials and Polymeric Biomaterials ; Volume 46, Issue 3-4, 2000 ; Zohuriaan-Mehr, M. J ; Rezai, N ; Sharif University of Technology
Abstract
A non-terminated, low molecular weight, highly crystalline, linear aliphatic polyester was successfully synthesized via ester-interchange polycondensation of cis-2-butene-1,4-diol and diethyl oxalate by using of lead (II) oxide as the catalyst. No decarboxylation occurred during the optimized polymerization. Structural and Chemical identification was performed by elemental analysis, FTIR, 'H-NMR, and Mass spectroscopy. Some macrocyle species were detected in the product, according to GPC. Fragmentation patterns were suggested for the main m/e's of the mass spectrum. Thermal characterization was performed by DSC and TGA. It was found that the overall thermal stability of the polyester is...
Performance and Rheological Characteristics of Modified Binders
, M.Sc. Thesis Sharif University of Technology ; Tabatabaee, Nader (Supervisor)
Abstract
The ever increasing usage of modified binders in road construction requires that the effect of different modifiers on the performance characteristics of the asphalt binder be determined through laboratory testing. The current Superpave protocol for performance grading asphalt binders has proven to be insufficient to properly characterize modified binders, thus researchers have searched for other testing methods to complement or possibly replace some of the Superpave tests. Most notable are the time sweep test for fatigue resistance, the multiple stress creep and recovery test (MSCR) for rutting resistance and the direct tension test (DTT) for low temperature cracking characteristics. In the...
Evaluation of Rheological Properties of Modified Binders with Two Modifiers
, M.Sc. Thesis Sharif University of Technology ; Tabatabaee, Nader (Supervisor)
Abstract
Binder modification, to improve the rheological properties and meet the standard requirements, is a common practice. The modification is usually done by adding polymers like Ethylene Vinyl Acetate (EVA) and Styrene Butadiene Styrene (SBS), waste materials like crumb rubber, or acids like Poly phosphoric acid (PPA) or by air blowing techniques. High temperature rheological properties of modified binders are usually improved by using polymers while the low temperature rheological properties mostly depend on the original binder. Therefore, the rheological properties at low temperatures do not show clear improvements in the modified binder compared to the original binder. This indicates that a...
Micromechanical Modeling the Viscoelastic Performance of the Asphalt Concrete with Finite Element
, M.Sc. Thesis Sharif University of Technology ; Tabatabaee, Nader (Supervisor)
Abstract
Asphalt concrete is a composite mixture of three phases; aggregate, bitumen and air void. Stress and strain distributions obtained from macroscopic modeling yield different results due to distinctly different mechanical properties of the above-mentioned phases. In this study a more exact analysis of the stress and strain, were carried out by considering the mixture as a two-phase composite; aggregate and mastic phases. Asphalt concrete was considered a composite material consisted of sand mastic and aggregate. Aggregate and mastic phases were separated and response of the loaded asphalt mixture was investigated. Aggregates finer than 2.36 mm in diameter, filler and bitumen consist the...
Empirical and Numerical Modeling of Viscoelastic-Viscoplastic Constitutive Equation for Asphalt Mixture Compaction
, Ph.D. Dissertation Sharif University of Technology ; Tabatabaee, Nader (Supervisor)
Abstract
The numerical simulation of asphalt concrete and pavement has gained considerable attention in recent decades. Information about the response of asphalt pavements during construction and in-service traffic loading is required by pavement specialists for improvement of pavement analysis and design methods. The goal of this study was to propose a constitutive relationship and a numerical modeling method for asphalt concrete compaction in the laboratory and in situ. Asphalt binders exhibit rate-dependent viscoelastic and viscoplastic mechanical behavior in asphalt concrete. The current study examined the viscoelastic and viscoplastic mechanical behavior of asphalt concrete under various loading...
Dynamic Modeling and Guidance of Underwater Robots with Different Geometries and Configurations
, M.Sc. Thesis Sharif University of Technology ; Seif, Mohammad Saeed (Supervisor)
Abstract
Underwater robots are capable of performing a wide range of underwater operations such as research, sampling, hydrography, rescue, and more. These robots are generally categorized into two main types: remotely operated vehicles (ROVs) and autonomous underwater vehicles (AUVs). AUVs offer significant advantages due to their lack of reliance on human operators, including extended operational range, longer operational duration, and reduced human risk. In the design process of any underwater robot, a specific dynamic model is developed based on the robot’s geometric features and the specifications of its appendages, including control surfaces, thrusters, and buoyancy tanks. This involves...
Probabilistic Comparison of Sustainability of Pavement Maintenance Programs
, M.Sc. Thesis Sharif University of Technology ; Tabatabaee, Nader (Supervisor)
Abstract
With the increasing importance of the sustainable development perspective, coupled evaluation of the environmental, economic, and functional performance of pavement maintenance programs needs to be considered. This task requires the use of data and models from different sources, which introduce uncertainty in the analysis. The use of probabilistic analysis may allow decision-makers to reach more realistic conclusions. To this end, all phases of the pavement life cycle, including material production, construction, use, and salvage at the end of life, should be considered. The effect of pavement-vehicle interaction (PVI) in the operation phase has received less attention from researchers. In...