Sharif Digital Repository

In the present paper, new H2S gasochromic nanomaterial of mixed silver nickel ammonium phosphomolybdate synthesized by microwave assisted technique is reported. The microwave treatment was performed in the solid phase using urea and ammonium nitrate as the promoter and oxidizer agents. The designed process allows rapid synthesis of large amounts of this product in nanosized particulate morphology. Morphological and structural features of the prepared products were studied in detail. Chemical analyses indicated a stoichiometry of (NH4)0.5Ni0.75AgPMo12O40·4H2O revealing a Keggin-type framework with substitution of silver and nickel cations in its secondary structure. A home-made set-up was... 

In this work, we report the synthesis of silver decamolybdate, Ag6Mo10O33, nanostructure by a simple mechanochemical process followed by calcination treatment using acetamide as driving agent. Morphological study by scanning electron microscopy (SEM) images revealed bundles of rods grown closely together with an average diameter of 92 nm for Ag6Mo10O33 sample. Ni-substituted Ag6Mo10O33 compound was prepared via introducing nickel cation to precursor system in mechanical milling step. The particle size decreased to 87 nm by incorporating nickel units in substituted polymolybdate. It was concluded that the suitable selection of reagents can direct solid phase reaction towards producing... 

A green mechanochemical technique has been developed for the synthesis of mixed ammonium silver phosphomolybdate salt, (NH4)1.6Ag1.4PMo12O40.4H2O with sheet-like nanostructure. The reaction was prompted using acetamide/NH4NO3 at room temperature. The change of driving agent to urea at the same conditions led to an epitaxial growth of hierarchical microstructure of this polyoxoanion. The morphological and structural features of the prepared specimens were discussed in detail. The photocatalytic performance of the resulting nanosheets for removing 4-nitrophenol (4-NP) in water under visible light... 

An easy method for preparing CuO nanoparticles incorporated in a mesoporous structure was presented based on the thermal decomposition of a copper complex. The novel copper coordination compound of [Cu(anic)2]·0.75H2O (anic= 2-aminonicotinate) with the microflake morphology was synthesized through the reaction of 2-aminonicotinic acid (Hanic) and copper(II) nitrate. Using elemental analysis and Fourier transform infrared (FTIR) spectroscopy, the chemical composition of CuC12H11.5N4O4.75 was proposed. Calcination process at 550 °C for 4 h transformed the microflakes into CuO nanoparticles incorporated in a mesoporous structure. The FTIR peaks assigned to 2-aminonicotinate were completely... 

TiO2 nanoparticles were synthesized by sol-gel method using titanium tetraisopropoxide. Sulfate ions were introduced on the titania by impregnation method using sulfuric acid as precursor of sulfate ions. Fourier transform infrared and energy-dispersive X-ray spectroscopy, X-ray fluorescence as well as X-ray diffraction, scanning electron microscopy, and BET methods were used for the characterization of the obtained nanoparticles. The esterification of isoamyl alcohol with acetic acid was investigated to prove the catalytic activity of the TiO2 nanoparticles under solvent-free conditions. Response surface methodology was applied to optimize the effect of some parameters such as the molar... 

BiOCl was synthesized using bismuth nitrate pentahydrate and sodium chloride via ball milling for 15 (B15), 30 (B30), and 60 (B60) min. Scanning electron microscopy studies revealed the isolated nanoplate morphology for B15, an aggregated structure composed of nanoplates for B30, and a special three-dimensional morphology for B60. The X-ray diffraction patterns showed the purity and crystallinity of the products improved by increasing the milling time. Fourier transform infrared spectroscopy, photoluminescence spectroscopy, and nitrogen adsorption-desorption analysis using the Brunauer-Emmett-Teller technique were also used to study the products. Diffuse reflectance spectroscopy studies... 

A novel intelligent semi-active control system for an eleven degrees of freedom passenger car's suspension system using magnetorheological (MR) damper with neuro-fuzzy (NF) control strategy to enhance desired suspension performance is proposed. In comparison with earlier studies, an improvement in problem modeling is made. The proposed method consists of two parts: a fuzzy control strategy to establish an efficient controller to improve ride comfort and road handling (RCH) and an inverse mapping model to estimate the force needed for a semi-active damper. The fuzzy logic rules are extracted based on Sugeno inference engine. The inverse mapping model is based on an artificial neural network... 

Using CNG as an additive for gasoline is a proper choice due to higher octane number of CNG enriched gasoline with respect to that of gasoline. As a result, it is possible to use gasoline with lower octane number in the engine. This would also mean the increase of compression ratio in SI engines resulting in higher performance and lower gasoline consumption. Over the years, the use of simulation codes to model the thermodynamic cycle of an internal combustion engine have developed tools for more efficient engine designs and fuel combustion. In this study, a thermodynamic cycle simulation of a conventional four-stroke spark-ignition engine has been developed. The model is used to study the... 

With the declining energy resources and increase of pollutant emissions, a great deal of efforts has been focused on the development of alternatives for fossil fuels. One of the promising alternative fuels to gasoline in the internal combustion engine is natural gas [1-5]. The application of natural gas in current internal combustion engines is realistic due to its many benefits. The higher thermal efficiency due to the higher octane value and lower exhaust emissions including CO2 as a result of the lower carbon to hydrogen ratio of the fuel are the two important feature of using CNG as an alternative fuel. It is well known that computer simulation codes are valuable economically as a cost... 

Gaining insight into possible vibratory responses of dynamical systems around their stable equilibria is an essential step, which must be taken before their design and application. The results of such a study can significantly help prevent instability in closed-loop stabilized systems by avoiding the excitation of the system in the neighborhood of its resonance. This paper investigates nonlinear oscillations of a rotary inverted pendulum (RIP) with a full-state feedback controller. Lagrange’s equations are employed to derive an accurate 2-DoF mathematical model, whose parameter values are extracted by both the measurement and 3D modeling of the real system components. Although the governing... 

A suction-controlled ring device has been developed to continuously measure the coefficient of lateral soil pressure in deformable unsaturated soil samples from the at-rest to the active condition under application of increasing vertical pressure and controlled matric suction. The device incorporates a thin aluminum specimen ring equipped with horizontal strain gages for recording the lateral soil strains. In addition, a sensor recording water volume changes is utilized to continuously monitor the degree of saturation of the soil sample during tests. The matric suction within the soil texture is controlled using the axis translation technique. In order to verify the performance of the ring... 

We introduce a new smooth, non-toxic, biocompatible method for cross-linking of gum tragacanth (GT), a polysaccharide of natural origin, in order to serve as a new supporting matrix for immobilization systems. The modified gum is used as a matrix for the catalysis of the conversion of benzyl penicillin to 6-aminopenicillanic acid (6-APA) by means of Escherichia coli ATCC11105 with penicillin G acylase (PGA) activity. The results show that GT beads can not only serve as a proper matrix for immobilization, but show enhanced hydrolysis rate and stability compared to other immobilization systems used for this reaction. This signifies the potential of GT as a biocompatible matrix for... 

The Class-E power amplifier has been widely studied and formulated in the literature. Although the majority of reported inductive coupling wireless power transfer (WPT) systems use a class-E power amplifier for driving the primary coil, still there is a lack of a comprehensive study on class-E circuit dedicated to WPT, providing a set of closed form design equations for proper class-E operation. This paper presents the required design equations needed to design a 'true' class-E circuit for WPT applications. Equations for the series-tuned secondary coil WPT system are presented, as well as two different design procedures for the parallel-tuned secondary coil. The derived equations have been... 

Pole Side Impact Tes is one out of three crash tests described by Euro NCAP standard for star rating of a vehicle and is required for assessing the Adult Occupant Protection. In this paper the goal is to determine the crashworthiness of side doors and B pillar in a Pole Side Impact Test based on Euro New Car Assessment Program (Euro-NCAP) using computer and simulation method. In this matter, a vehicle model has been prepared and meshed using Hypermesh and CATIA. The velocity of 29 km/h has been assigned to the vehicle which was on top of a cart while the pole has been assigned as a rigid static object based on Euro NCAP requirements specifically. Results show that different amounts of energy... 

To assess a car under the Euro New Car Assessment Program (Euro-NCAP), Adult Occupant Protection is one out of three parameters which need to be calculated with a weight factor of 50% while the other parameters, Child Occupant Protection and Pedestrian Occupant Protection, have a weight factor of 20%. The Pole Side Impact Test, beside two other tests, Side and Front Impact, is also required to calculate the Adult Occupant Protection. It shows how important the Pole Side Impact Test is and what an effective role it has in the car rating assessment. In this paper, the objective is to evaluate the effect of thickness on the energy absorbed by the side doors and the B pillar and its... 

In Euro NCAP standard, adult protection is one of the most important rating scores with 50% weight factor while child protection and pedestrian protection are accounted into consideration with 20% weight factor. For adult protection testing, three tests are required to perform: (1) side impact, (2) pole impact, (3) front impact. In the side impact test, dummy's head, chest, shoulder, thorax, ribs, abdomen, pelvic and femur must be studied to evaluate the rating score. Crashworthiness of a car during side impact can describe the score rated for that car. In this paper the goal is to determine the crashworthiness of side doors and B-pillar in side impact crash est by simulation using LS DYNA... 

In side impact test which is one out of three tests of Euro NCAP standard, front and rear doors and B pillar are most absorbance parts among vehicle body parts. Passengers are highly in danger while side crash, because of the distance between passenger's head and vehicle body. In this paper effect of material and thickness of doors and B-pillar and their absorbed energy during crash and improvement of its crashworthiness with respect to light weight design are studied using LS DYNA solver. The objective of this paper is to propose a material for doors and B-pillar with a specified thickness to achieve maximum absorbed energy and minimum weight. The shape of the doors and B-pillar remains... 

In this study, the influence of CO2 and CH4 on the performance and selectivity of Co-Ru/Al2O3 catalyst is investigated by injection of these gases (0-20 vol.% of feed) to the feed stream. The effect of temperature and feed flow rate are also inspected. The results show that low amounts of CO2 in the feed stream do not change the catalyst activity, but increasing the amount of CO2 (more than 10 vol.%), causes the CO conversion to decrease and the selectivity of heavy components to increase. Methane acts as an inert gas and does not affect the catalyst performance. Increasing feed flow rate has a negative effect on both CO conversion and heavy component selectivity. By raising the temperature,... 

In this paper, we present a nano-quantum photonic approach for the calculation of normal dispersion phenomena in organic crystals such as N-(4-nitrophenyl)-L-prolinol(NPP). We assume that a laser beam consists of a flow of energetic particles that interact with the distorted π-electron system. We approximate the distorted π-electron cloud by an ellipse to simplify calculations. By the precise analysis of photon interaction with the π-electron system of benzene ring in the NPP crystal, we obtain the refractive index in any wavelength by Monte Carlo simulation. The maximum error between our simulation results and the measurement data is 0.058, which is agreeable. © 2007 IOP Publishing Ltd  

We investigate the effect of wall roughness on water electrolyte transport characteristics at different temperatures through carbon nanotubes by using nonequilibrium molecular dynamics simulations. Our results reveal that shearing stress and the nominal viscosity increase with ion concentration in corrugated carbon nanotubes (CNTs), in contrast to cases in smooth CNTs. Also, the temperature increase leads to the reduction of shearing stress and the nominal viscosity at moderate degrees of wall roughness. At high degrees of wall roughness, the temperature increase will enhance radial movements and increases resistance against fluid motion. As the fluid velocity increases, the particles do not...