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tafazoli--mohsen
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Conformational Study of Lidocaine and Bupivacaine by Quantum Mechanical Methods
, M.Sc. Thesis Sharif University of Technology ; Tafazoli, Mohsen (Supervisor)
Abstract
In this thesis the structure and potential energy surfaces of Lidocaine and bupivacaine were studied by DFT method at B3LYD level calculation using 6-311++G basis set. Both compounds were calculated in water, dimetylsulfoxide, and carbontetracholoride as the solvent using the PCM model.Since the molecules meant to be studied were polar, level of energy in polar solvent is higher than non-polar solvent . The most considerable increase was observed in the amount of energy at 0.01 hartree for water compared with carbon tetracholoride. By changeing in solvent environment the most considerable difference in bond length was observed as 0.01 Ǻ.The spin spin coupling constants 1JCH, 2JCH, 2JHH,...
Theoritical Investigation of Metallic Cations and Gas Adsorption on Surface of Carbon Nanostructures
, Ph.D. Dissertation Sharif University of Technology ; Tafazoli, Mohsen (Supervisor) ; Shamkhali, Amir Nasser (Supervisor)
Abstract
Carbon nanostructures are of great importance in scientific and industrial research. Two case of the important two-dimensional carbon nanostructures are graphitic carbon nitride (g-C3N4) and graphene. In the first part of this work, adsorption of important heavy metal cations including Hg+2, Ag+, Cr+3, Pb+2, Cu+2, Ni+2, Cd+2, Tl+, Sb+3, Zn+2 and As+3 on the surface of (g-C3N4) was investigated by density functional theory (DFT). The main purpose of this theoretical study is to evaluate the ability of g-C3N4 to adsorb pollutant cations. The most prominent result of this work was the ability of g-C3N4 for effective adsorption of As+3 and Sb+3 ions from aqeous solutions. Also, another...
The role of a vapor-assisted solution process on tailoring the chemical composition and morphology of mixed-halide perovskite solar cells
, Article CrystEngComm ; Volume 20, Issue 31 , 2018 , Pages 4428-4435 ; 14668033 (ISSN) ; Timasi, N ; Nouri, E ; Mohammadi, M. R ; Sharif University of Technology
Royal Society of Chemistry
2018
Abstract
Herein, we report a modified two-step method to construct a uniform and pinhole-free polycrystalline perovskite film with large grains up to the microscale using lead mixed-halide (PbI2-PbCl2) precursor solutions to guarantee the device functioning. Commonly used sequential deposition methods based on dip- and spin-coatings are combined with a vapor-assisted solution process to improve the perovskite morphology and tune the residual lead mixed-halides. These can enhance the optical absorption and efficiency of perovskite solar cell (PSC) devices. The impact of the Cl content in the lead mixed-halide precursors and the employed preparation methods on the photovoltaic performance of PSCs are...
Investigating the behavior of cracks in welded zones of supporting structure of spherical pressure vessel under seismic loading
, Article Journal of Constructional Steel Research ; Volume 191 , 2022 ; 0143974X (ISSN) ; Ghazi, M ; Adibnazari, S ; Rofooei, F. R ; Sharif University of Technology
Elsevier Ltd
2022
Abstract
In this paper, the numerical studies on the semi-elliptical crack behavior in different locations of welded zones in the supporting structure of a spherical pressure vessel under an earthquake are presented. The cracks in the welded zones of supporting structures under earthquake effects may jeopardize the safety of spherical pressure vessels and result in catastrophic failure. A detailed finite element sub-modeling technique is carried out to compute the mixed-mode stress intensity factors along the crack front. Furthermore, crack behavior with different aspect ratios a/c: 0.25, 0.5, and 0.75 at the weld and the heat-affected zone of the supporting structure is evaluated. The...
The sloshing effects on the crack instability of the spherical tank under the simultaneous effect of internal pressure and earthquake
, Article Thin-Walled Structures ; Volume 185 , 2023 ; 02638231 (ISSN) ; Ghazi, M ; Adibnazari, S ; Rofooei, F. R ; Sharif University of Technology
Elsevier Ltd
2023
Abstract
Spherical tanks have an important function in the industry due to the internal pressure of their contents. Also, the supporting structure of the spherical tank controls stability and damage to the tank One of the damages that can lead to a critical situation is an unstable crack in the column-vessel joint. In this study, the sloshing effects on the instability of 10 mm and 20 mm long semi-elliptical cracks with three aspect ratios in the connection zones of the supporting structure under the effect of internal pressure and eleven earthquakes have been investigated. Furthermore, using the finite element sub-modeling method around the crack area and part of the structure, the effect of...
Chemical constituents from Salvia macrosiphon
, Article Chemistry of Natural Compounds ; Volume 44, Issue 4 , Volume 44, Issue 4 , 2008 , Pages 518-519 ; 00093130 (ISSN) ; Moridi Farimani, M ; Taheri, S ; Tafazoli, M ; Amin, G ; Sharif University of Technology
Springer New York
2008
Growth of Perovskite Film based on Lead Iodide by Controlling Deposition Parameters for Solar Cells Application
, M.Sc. Thesis Sharif University of Technology ; Mohammadi, Mohammad Reza (Supervisor) ; Seyed Reihani, Morteza (Supervisor) ; Riahi, Nastaran (Co-Advisor)
Abstract
Perovskite solar cells, with high efficiency operation, have been candidated as a cost-effective and environmentally friendly technology. Despite the great progress, there are some primarily issues remained regarding to the perovskite film and its fabrication methods. A very common perovskite cell structure is FTO/TiO2/CH3NH3PbI3/Spiro-OMeTAD/Au. Although, this structure has some advantages, lack of full surface coverage of perovskite film leads researchers to put much effort on finding other constructions. This surface inhomogeneity reduces the amount of light absorption and therefore efficiency. One way to produce a complete and uniform film is applying mixed-halide composition; such as...
Sole versus dual-sourcing under order dependent lead-times and prices [electronic resource]
, Article Computers And Operations Research, Published in: Elsevier Journals ; Volume 36, Issue 12, December 2009, Pages 3272–3280 ; Eshghi, Kourosh ; Sharif University of Technology
Abstract
In this paper, we consider a dual-sourcing model with constant demand and stochastic lead times. Two suppliers may be different in terms of purchasing prices and lead-time parameters. The ordering takes place when the inventory level depletes to a reorder level, and the order is split among two suppliers. Unlike previous works in the order splitting literature, the supply lead time between vendor and buyer as well as unit purchasing prices is considered to be order quantity dependent. The proposed model finds out the optimal reorder point, order quantity and splitting proportion, using a solution procedure. Numerical results show that neglecting the relationship between ordering batch size...
Human serum protein adsorption onto synthesis nano-hydroxyapatite
, Article Protein Journal ; Volume 31, Issue 2 , February , 2012 , Pages 150-157 ; 15723887 (ISSN) ; Massah Bidgoli, M ; Behrashi, M ; Mohsen Nia, A ; Sharif University of Technology
2012
Abstract
Adsorption of human serum proteins (Albumin and total protein) onto high purity synthesis nano-hydroxyapatite (HA), Ca 10(PO 4) 6(OH) 2, has been studied in a wide temperature range by UV-visible spectrophotometer. Adsorption isotherm is basically important to describe how solutes interact with adsorbent, andiscriticalinoptimizing the use of adsorbent. Inthe present study, the experimental results werefitted tothe Langmuir, Freundlich, Temkin and Dubinin-Radushkevich (DR) models to obtain the characteristic parameters of each model and square of the correlation coefficients (R 2). According to the results, the DR isotherm model had the best agreement with the experimental data. The effect of...
Effective Permeability of Isotropic Overlapping Sandbodies in 2D Using Percolation Theory
, M.Sc. Thesis Sharif University of Technology ; Masihi, Mohsen (Supervisor)
Abstract
Permeability is an essential parameter used for reservoir evaluation, simulation and management to optimize oil recovery. The conventional approach to estimate reservoir connectivity, conductivity, sweep efficiency and other critical information for decision-making is to build detailed geological models, which are then upscaled to a coarser grid where flow simulations are run. However, this takes many hours to be carried out even for a single realization practically. In practice, a very small number of realizations are considered and consequently the true uncertainty in the results is very poorly estimated. In this study, a statistical model of isotropic overlying sandbodies is used to...
A Metabonomics Study of Samples of Different Diseases: Investigation of Linear and Non-Linear Model by Nuclear Magnetic Resonance
, Ph.D. Dissertation Sharif University of Technology ; Tafazzoli, Mohsen (Supervisor)
Abstract
Metabonomics is a quantitative measurement of time dependent metabolic interactions for living systems in response to the pathological or genetic variations. NMR spectroscopy has emerged as a key tool for understanding metabolic processes in living systems. In this project, the study of metabolomics was performed as classification and regression on samples of parkinson’s disease, multiple sclerosis disease, celiac disease and crohn’s disease. In classification part, various methods were applied using optimal parameters.classification methods in Parkinson’s disease, multiple sclerosis disease, celiac disease and crohn’s disease were RF, CART, PLS-DA, RF and RF respectively. Based on the...
Determination of Parameters Affecting the Linear Seismic Evaluation of Gravity Dams Using Nonlinear Analysis
, M.Sc. Thesis Sharif University of Technology ; Ghaemian, Mohsen (Supervisor)
Abstract
Gravity dams are solid concrete structures that maintain their stability against design loads from the geometric shape and the mass and strength of the concrete. Because of their critical role in supplying portable and agricultural water and problems which would happen if they broke, it is required to consider their stability and keep them in safe conditions. They should be able to continue their function after a disaster such as earthquake. But most of them are aged dams with some have been built near faults. Indeed, there are some concerns regarding the performance of these dams under the effect of seismic loads. This research deals with performance evaluation of concerete gravity . The...
Numerical Analysis of Soil-Nailed Walls in Seismic Condition
,
M.Sc. Thesis
Sharif University of Technology
;
Haeri, Mohsen
(Supervisor)
Abstract
Soil nailing is an in-situ technique of mechanically stabilizing soil masses which has been used in France, Germany, United states, and recently in Iran. A review of literature shows that Soil-Nailed walls have performed well during strong ground motions in comparison with the gravity retaining structures. After the 1989 Loma Prieta earthquake, minor signs of distress or corresponding deformation were found on the Soil-Nailed walls, indicating excellent performance of such structures during moderate and strong shakings. These observations indicate that Soil-Nailed walls have an inherent satisfactory seismic response. This has been attributed to the intrinsic flexibility of the Soil-Nailed...
Collapsible Behavior of Gorgan Loess Using Odeometer
, M.Sc. Thesis Sharif University of Technology ; Haeri, Mohsen (Supervisor)
Abstract
In nature, there are types of soils that when goinging under stress at constant moisture, or increase of moisture at constant stress, or change of both characters, they show a sudden and high level decrease in their volume. These type of soils are named as Collapsible soils. Iran is one of the countries that at some parts of its land collapsible soils are found. In this research by using of laboratory equipments, the volume change behavior of collapsible loess soils of Gorgan plain (North of Iran) is evaluated under increase of water content and inundation stress. In these experiments, the usual odeometer cell has been used for exploring the behaviour of collapsibility and volume change of...
The Effect of Cementation by Lime on Collapsible Soils Behavior Using Suction Controlled Oedometer Device Case Study: Loess of Gorgan
, M.Sc. Thesis Sharif University of Technology ; Haeri, Mohsen (Supervisor)
Abstract
Collapsible soils such as loess, which are naturally found unsaturated, are kind of problematic soils that undergo sudden and noticeable decrease in volume under increasing stress at constant moisture, increasing moisture at constant stress, or increase in both of them. This kind of soil can be found in some parts of Iran such as plain of Gorgan. To fulfill the main purpose of this study, evaluating the effect of cementation on collapse behavior of loess of Gorgan, some oedometer tests under controlled matric suction were performed on reconstituted samples without and with lime. The lime was added for stabilizing of the collapsible materials and the amount was chosen to be %3 by weight of...
An Experimental Investigation of Three-Phase Flow of water-Oil-Gas Mixture Through Water-wet Sandstone
, M.Sc. Thesis Sharif University of Technology ; Masihi, Mohsen (Supervisor)
Abstract
Accurate prediction of relative permeability for various reservoir rocks at various saturation conditions has been of concern for a long time in petroleum industry. Relative permeability is known as one of the most significant parameters in simulation of actual multi-phase flow through porous media during life-time of a hydrocarbon reservoir. In addition, it plays important role in oil production and well completion. Direct experimental measurement in order to determine relative permeability of porous rock has long been recorded in petroleum related literature. However, empirical methods for determining relative permeability are becoming more widely used, particularly with the advent of...
Introducing a Set of Material Strain Measures in Non-Linear Kinematics of Micropolar Continuum Mechanics and Determining their Time Rates
, M.Sc. Thesis Sharif University of Technology ; Asghari, Mohsen (Supervisor)
Abstract
The concept of generalized strains is a well-established subject in the classical continuum mechanics. The characteristics and various applications of the generalized strains have been the point of interest of many researchers in the classical continuum mechanics. The aim of this thesis is the introduction of generalized strains in the micropolar theory, as a non-classical continuum theory. A set of generalized strains is suggested for the deformation of macro-elements. Moreover, a set of generalized strains is proposed for the micro-structures. Since the rate of strains possesses a significant importance in the constitutive equations of nonlinear analysis of solids, expressions for the rate...
Evaluation of the Behaviour of Collapsible Soils in Saturated and Unsaturated Oedometer Tests – Case Study of Gorgan Loess
, M.Sc. Thesis Sharif University of Technology ; Haeri, Mohsen (Supervisor)
Abstract
Collapsible soils are kinds of problematic soils which are susceptible to large and sudden reduction in volume upon wetting. A manifest kind of these soils is loess; catastrophic settlement of structures which are built upon it has been observed when the soil becomes wet. In this investigation the collapse potential of samples of loess taken from Gorgan, Golestan, Iran, has been studied by using unsaturated odometer tests under controlled matric suction. To this end, two modified odometer apparatus with the capability of controlling the matric suction, have been designed and developed. Undisturbed samples of soil have been tested under K0 condition, while the matric suction, volumetric...
Performance Evaluation of Concrete Gravity Dam Using Crest Displacement by Nonlinear Analysis
, M.Sc. Thesis Sharif University of Technology ; Ghaemian, Mohsen (Supervisor)
Abstract
Concrete gravity dams are one of the most important infrastructures therefore their performance under seismic load is an important issue of concern for dam owners. It is necessary that these infrastructures to be able to continue their function after a disaster such as earthquake, as any damage can cause huge cost. For analysis of dams linear and nonlinear analyses are used. Because even operating loads will create cracks in the body of the dam, dam behavior can not always be considered linear. It is remarkable that these surface cracks can join together under seismic loads and this question the safety of dams. It is important to note that nonlinear analysis of concrete gravity dams is...