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tahmasebi-garavand--nemat
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Pt and Pd as catalyst deposited by hydrogen reduction of metal salts on WO3 films for gasochromic application
, Article Applied Surface Science ; Volume 273 , May , 2013 , Pages 261-267 ; 01694332 (ISSN) ; Mahdavi, S. M ; Iraji Zad, A ; Sharif University of Technology
2013
Abstract
In this study, tungsten oxide films were deposited by pulsed-laser deposition (PLD) technique. The as-deposited films were annealed at 250 °C in air for 1 h. The surface morphology, microstructure, crystalline phase, and chemical composition of the films were characterized by SEM, XRD and XPS techniques. Pt nanoparticles were deposited onto the tungsten oxide films through a two-step process. First of all, a layer of PtCl2 was coated on the WO3 surface by drop-drying the PtCl2 solution onto the WO3 surface at 60 °C. Consequently, the reduction of the PtCl2 into the metallic Pt nanoparticles was performed at 200 °C. In this study, the effect of the temperature during hydrogen reduction of...
Colouration process of colloidal tungsten oxide nanoparticles in the presence of hydrogen gas
, Article Applied Surface Science ; Volume 258, Issue 24 , 2012 , Pages 10089-10094 ; 01694332 (ISSN) ; Ranjbar, M ; Mahdavi, S. M ; Iraji Zad, A ; Sharif University of Technology
Elsevier
2012
Abstract
In this study, tungsten oxide nanoparticles were fabricated by pulsed laser ablation (PLA) of tungsten target using the first harmonic of a Nd:YAG laser (1064 nm) in deionized water. After ablation, a 0.2 g/lit PdCl 2 solution was added to activate the solution against the hydrogen gas. Dynamic light scattering and X-ray photoelectron spectroscopy were used to measure the average size and the surface chemical composition of the synthesized nanoparticles, respectively. The aim is to investigate the influence of hydrogen exposure time on colouration process of colloidal nanoparticles. According to optical measurements, hydrogen bubbling into the produced colloidal Pd-WO 3 led to formation of...
Physical Investigation of Gasochromic Phenomena Mechanism in Tungsten Oxide Nanostructure
, Ph.D. Dissertation Sharif University of Technology ; Mahdavi, Mohammad (Supervisor) ; Iraji Zad, Azam (Supervisor)
Abstract
In the present thesis the fabrication of various tungsten oxide nanostructures (films and colloidal nanoparticles) with coverage of catalyst on their surfaces has been investigated which show gasochromic properties. Tungsten oxide films and nanoparticles were synthesized by pulsed laser abalation technique in vacuum and liquid environment, respectively. To activate the synthesized films and nanoparticles against hydrogen gas, the catalyst nanoparticles (Pd or Pt) were deposited onto their surface through hydrogen reduction of metal salt and electroless methods, respectively. The products were characterized by XPS, UV-Vis., AFM and DLS techniques. The prepared samples show significant color...
Investigation of Palladium Growth on Nanostructured Tungsten Oxide Films
, M.Sc. Thesis Sharif University of Technology ; Mahdavi, Mohammad (Supervisor) ; Iraji Zad, Azam (Supervisor)
Abstract
We have studied making and characterization of gasochromic thin films that are used as gas sensors. Gasochromic films consist of an electronchromic layer and a catalyst layer. Addition of palladium to the surface , increased the sensitivity and decreased the working temperature. The used electrochromic layer was tungsten oxide. WO3 films were fabricated by (PLD) method. The substrates were slide glasses. Structure, morphology and composite of tungsten oxide and optical property of films depend on condition of deposition. The pressure of oxygen gas in chamber and temperature of substrate are two factors that can affect in deposition. We can make layers with different morphology by variation...
Weak differentiability of solutions to SDEs with semi-monotone drifts
, Article Bulletin of the Iranian Mathematical Society ; Volume 41, Issue 4 , Sep , 2015 , Pages 873-888 ; 10186301 (ISSN) ; Zamani, S ; Sharif University of Technology
Iranian Mathematical Society
2015
Abstract
In this work we prove Malliavin differentiability for the solution to an SDE with locally Lipschitz and semi-monotone drift. To prove this formula, we construct a sequence of SDEs with globally Lipschitz drifts and show that the p-moments of their Malliavin derivatives are uniformly bounded
Simulation of HEMT (High Electron mobility Transistor) for Communication Applications
, M.Sc. Thesis Sharif University of Technology ; Sarvari, Reza (Supervisor)
Abstract
In this thesis, the simulation of HEMT for high frequency applications has been explored. It has been tried to examine the changes such as: gate recess, T-shaped gate, changing the channel length and doping of buffer layer on the performance of the proposed device. Simulation results show that the best way to improve the device performance, in particular its cut-off frequency, is increase in buffer layer doping density. Because it significantly increase the saturation current, electron mobility inside the channel, the transconductance and the cut-off frequency. If we need to lower the noise, the T-shaped gate can also be used. Also, by change in doping of donor layer, amount of 1017 cm-3 is...
Electrochemical Deposition of Zinc/Nickel Multilayer Coating and Investigating the Effect of Morphology and Phase Structure on the Dissolution of Zinc/Nickel Alloy Coating
, M.Sc. Thesis Sharif University of Technology ; Ghorbani, Mohammad (Supervisor)
Abstract
The multilayer coating (Zn-Ni)1/(Zn-Ni)2 is deposited from a single bath with a zincate-sulfate compound and by changing the current density. The effect of current density and the number of layers on the chemical composition, surface morphology, roughness, phase structure, and corrosion resistance of multilayer coatings respectively using atomic absorption spectroscopy, FE-SEM microscope, roughness tests, X-ray analysis, and electrochemical techniques such as Tafel polarization and impedance was investigated and compared with single-layer coatings. Because the amount of nickel in the composition of the coatings is less than 27%, in all the studied currents, the deposition is anomalous. The...
Effect of Efficient Management on Reconstruction of Apartment Buildingsi n Region 1 of Tehran City Using Hierarchical Analytical Model
, M.Sc. Thesis Sharif University of Technology ; Mofid, Massoud (Supervisor)
Abstract
Nowadays population growth, people housing demand and urbanization tendency has increased the land and house prices. So the constructers tend to build apartments. Time consuming and heavy costs of building and renovation has made the owners to rebuild the damages of their houses in case of an accident. Time and cost are the main factors in construction which includes rebuilding. Buildings and especially apartments renovation is expensive and prolonged. So the rebuilding tendency has been noted more than ever. In this study it has been tried to control costs and time by efficient management to save the rebuilding time and money. Two kinds of questionnaire has been applied to study different...
Scalable Architecture Based on Fog Computing and Blockchain for IoT Device Management
, M.Sc. Thesis Sharif University of Technology ; Habibi, Jafar (Supervisor)
Abstract
With the recent considerable developments in the Internet of Things (IoT), billions of resource-constrained devices are interconnected through the internet. Monitoring this huge number of IoT devices that are heterogeneous in terms of underlying communication protocols and data format is challenging. The majority of existing IoT device monitoring solutions heavily rely on centralized architectures. Since using centralized architectures comes at the expense of trusting an authority, it has several inherent drawbacks, including vulnerability to security attacks, lack of data privacy, and unauthorized data manipulation. Hence, a new decentralized approach is crucial to remedy these drawbacks....
Simulation of Imaging in Trolling Mode Atomic Force Microscopy by Molecular Dynamics Method
, M.Sc. Thesis Sharif University of Technology ; Nejat Pishkenari, Hossein (Supervisor)
Abstract
Atomic force microscopy (AFM), as an indispensable tool for nanoscale characterization, has major drawback for operation in a liquid environment arising from the large hydrodynamic drag on the vibrating cantilever. The newly introduced “Trolling Mode” (TR-Mode) AFM resolves this complication utilizing a specialized nanoneedle cantilever that keeps the cantilever outside of the liquid. Herein, a mechanical model with a lumped mass was developed to capture the dynamics of such cantilever with a nanoneedle tip. This new developed model was applied to investigate the effects of the needle – liquid interface on the performance of the AFM, including the imaging capability in liquid. Also...
Pd 2+ reduction and gasochromic properties of colloidal tungsten oxide nanoparticles synthesized by pulsed laser ablation
, Article Applied Physics A: Materials Science and Processing ; Volume 108, Issue 2 , 2012 , Pages 401-407 ; 09478396 (ISSN) ; Mahdavi, S. M ; Iraji Zad, A ; Sharif University of Technology
Springer
2012
Abstract
Tungsten oxide nanoparticles were fabricated by a pulsed laser ablation method in deionized water using the first harmonic of a Nd:YAG laser (λ = 1064 nm) at three different laser pulse energies (E1 = 160, E2 = 370 and E3 = 500 mJ/pulse), respectively. The aim is to investigate the effect of laser pulse energy on the size distribution and gasochromic property of colloidal nanoparticles. The products were characterized by dynamic light scattering (DLS), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and UV-Vis spectroscopy. The results indicated that WO 3 nanoparticles were formed. After ablation, a 0.2 g/l PdCl 2 solution was added to activate the solution against...
Synthesis and optical properties of Au decorated colloidal tungsten oxide nanoparticles
, Article Applied Surface Science ; Volume 355 , November , 2015 , Pages 884-890 ; 01694332 (ISSN) ; Mahdavi, S. M ; Sharif University of Technology
Elsevier
2015
Abstract
In this study, colloidal tungsten oxide nanoparticles were fabricated by pulsed laser ablation of tungsten target using the first harmonic of a Nd:YAG laser (1064 nm) in deionized water. After ablation, a 0.33 g/lit HAuCl4 aqueous solution was added into as-prepared colloidal nanoparticles. In this process, Au3+ ions were reduced to decorate gold metallic state (Au0) onto colloidal tungsten oxide nanoparticles surface. The morphology and chemical composition of the synthesized nanoparticles were studied by AFM, XRD, TEM and XPS techniques. UV-Vis analysis reveals a distinct absorption peak at ∼530 nm. This peak can be attributed to the surface plasmon resonance (SPR) of Au and confirms...
A novel adaptive approach to fingerprint enhancement filter design
, Article Signal Processing: Image Communication ; Volume 17, Issue 10 , 2002 , Pages 849-855 ; 09235965 (ISSN) ; Kasaei, S ; Sharif University of Technology
2002
Abstract
A novel procedure for fingerprint enhancement filter design is described. Fingerprints are best used as unique and invariant identifiers of individuals. Identification of fingerprint images is based on matching the features obtained from a query image against those stored in a database. Poor quality of fingerprint images makes serious problems in the performance of subsequent matching process. The main contribution of this work is to quantify and justify the functional relationship between image features and filter parameters. In this work, the enhancement process is adapted to the input image characteristics to improve its efficiency. Experimental results show the superiority of the...
Synthesis of sodium tungsten oxide nano-thick plates
, Article Materials Letters ; Volume 82 , September , 2012 , Pages 214-216 ; 0167577X (ISSN) ; Mahdavi, S. M ; Irajizad, A ; Ahadi, K ; Sharif University of Technology
Elsevier
2012
Abstract
In this letter a simple procedure to synthesize sodium tungsten oxide nano-thick plates from WO 3 films has been reported. WO 3 films were grown by pulsed-laser deposition method and then heat treated at temperatures up to 560 °C and times up to 120 min. Slide glass was used as both substrate and sodium source simultaneously. XRD analysis revealed presence of an amorphous structure for as-deposited WO 3 films. On the other hand, XRD showed formation of a monoclinic WO 3 structure with annealing in lower temperatures and a triclinic Na 0.5WO 3.25 structure with annealing at higher temperatures. Intensity of the triclinic phase peaks enhanced drastically by rising annealing temperature and...
Evaluation of Urban Water Distribution Network Resilience and Development of New Software based on Resilience Criteria Using Concurrent Discrete Event and Hydraulic Simulation(Case Study: Eslamshahr Water Distribution Network)
, M.Sc. Thesis Sharif University of Technology ; Mortaheb, Mohammad Mehdi (Supervisor) ; Hassani, Nemat (Co-Advisor)
Abstract
This dissertation proposes a new platform and a new software for evaluation of urban Water Distribution Network (WDN) resilience. Resilience is considerd as the ability of an infrastructure to come back to steady state after being affected by any environmental or man-made disturbance. WDN, as an essential infrastructure, has major role on resilience and sustainability of cities and communities. Today, uninterrupted performance of WDN is a basic need of people who live in cities. This uninterrupted performance becomes bolder in face of man-made or natural disasters like earthquake. The uninterrupted performance of a system is dependent on the system’s resilience. Majority of researchers...
Private sequential function computation
, Article 2019 IEEE International Symposium on Information Theory, ISIT 2019, 7 July 2019 through 12 July 2019 ; Volume 2019-July , 2019 , Pages 1667-1671 ; 21578095 (ISSN); 9781538692912 (ISBN) ; Maddah Ali, M. A ; Sharif University of Technology
Institute of Electrical and Electronics Engineers Inc
2019
Abstract
In this paper, we introduce the problem of private sequential function computation, where a user wishes to compute a composition of a sequence of K linear functions, in a specific order, for an arbitrary input. The user does not run these computations locally, rather it exploits the existence of N non-colluding servers, each can compute any of the K functions on any given input. However, the user does not want to reveal any information about the desired order of computations to the servers. For this problem, we study the capacity, defined as the supremum of the number of desired computations, normalized by the number of computations done at the servers, subject to the privacy constraint. In...
A Scalable architecture for monitoring IOT devices using ethereum and fog computing
, Article 4th International Conference on Smart Cities, Internet of Things and Applications, SCIoT 2020, 16 September 2020 through 17 September 2020 ; 2020 , Pages 66-76 ; Habibi, J ; Shamsaie, A ; Sharif University of Technology
Institute of Electrical and Electronics Engineers Inc
2020
Abstract
With recent considerable developments in the Internet of Things (IoT), billions of resource-constrained devices are interconnected through the Internet. Monitoring this huge number of IoT devices which are heterogeneous in terms of underlying communication protocols and data format is challenging. The majority of existing IoT device monitoring solutions heavily rely on centralized architectures. Since using centralized architectures comes at the expense of trusting an authority, it has several inherent drawbacks, including vulnerability to security attacks, lack of data privacy, and unauthorized data manipulation. Hence, a new decentralized approach is crucial to remedy these drawbacks. One...
A Fast and Scalable Network-on-Chip for DNN Accelerators
, M.Sc. Thesis Sharif University of Technology ; Sarbazi Azad, Hamid (Supervisor)
Abstract
Deep Neural Networks (DNNs) are widely used as a promising machine learning method in different applications and come with intensive computation and storage requirements. In recent years, several pieces of prior work have proposed different accelerators to improve DNNs processing. We observe that although the state-of-the-art DNN accelerators effectively process some network layers of certain shapes, they fail to keep computation resources fully utilized for many other layers. The reason is twofold: first, the mapping algorithm is unable to employ all compute cores for processing some layer types and dimension sizes, and second, the hardware cannot perform data distribution and aggregation...
The effect of operating temperature on gasochromic properties of amorphous and polycrystalline pulsed laser deposited WO 3 films
, Article Sensors and Actuators, B: Chemical ; Volume 169 , July , 2012 , Pages 284-290 ; 09254005 (ISSN) ; Mahdavi, S. M ; Zad, A. I ; Ranjbar, M ; Sharif University of Technology
2012
Abstract
In this study, tungsten oxide films were synthesized by pulsed laser deposition (PLD) method. The as-deposited films were annealed at a temperature of 250 and 350°C in air for 1 h. The surface morphology, microstructure, crystalline phase and chemical composition of the as-prepared and annealed films were characterized by SEM, XRD and XPS techniques, respectively. Deposition of Pd nanoparticles onto the tungsten oxide surface was performed by hydrogen reduction of a drop-drying PdCl 2 solution onto a WO 3 surface at 60°C. The influence of the annealing temperature on microstructure and gasochromic performance as well as the effect of operating temperature is presented in this work. Results...
Electroless plating of palladium on WO3 films for gasochromic applications
, Article Solar Energy Materials and Solar Cells ; Volume 94, Issue 2 , 2010 , Pages 201-206 ; 09270248 (ISSN) ; Tahmasebi Garavand, N ; Mahdavi, S. M ; Iraji Zad, A ; Sharif University of Technology
2010
Abstract
Nowadays, gasochromic Pd/WO3 coatings as optically switchable materials during H2 absorption have become more interesting due to their novel applications in smart windows and gas sensor devices. In this study, WO3 films were fabricated by Pulsed Laser Deposition (PLD) on glass substrates. Using an electroless method, Pd nanoparticles were deposited on the surface of the produced films. The effect of Pd growth time on coloring/bleaching rate was studied for different submerging times (1, 2, 5, 10, 15, 20 and 40 min). The best coloring/bleaching velocity was attained with a growth time of 2 min. The effect of growing time and growth feature of Pd particles was further studied using Scanning...