Sharif Digital Repository

In recent years, the technological advancement of supercapacitors has been increasing exponentially due to the high demand in electronic consumer products. As so, researchers have found a way to meet that demand by fabricating graphene. As developments are made toward the future, two big advancements to be made are large-scale fabrication of graphene and fabricating graphene as a flexible electrode. This would allow for use in larger products and for manipulation of the unique properties of graphene to accommodate superior design alternatives. While large scale production is still mentioned, this review is specifically focusing on different methods used to fabricate graphene as a flexible... 

Novel molybdenum complex, cis-[MoO2(phox)2] has been synthesized and characterized by IR, 1H NMR, elemental analyses (CHN), and X-ray molecular structure determination methods. This complex was found to be an efficient, selective catalyst for the oxidation of various sulfides to sulfoxides with urea hydrogen peroxide (UHP) in excellent yields (100% for diallylsulfide) and short reaction times (20 min) at room temperature. The catalytic system oxidizes diallylsulfide chemoselectively to its corresponding sulfoxide without any over oxidation in double bond. © 2007 Elsevier B.V. All rights reserved  

Cupric oxide (CuO) nanostructures are grown on fluorine doped tin oxide (FTO) coated glass substrate using aqueous solution approach. The concentration of precursor's solution has significant impact on morphology of CuO nanostructure. By varying concentration of precursor, the growth of two different morphologies (oriented nanosheets and nanoleaves) is achieved. X-ray diffraction pattern and X-ray photoelectron spectroscopy reveals formation of pure CuO crystalline phase. Mott-Schottky characteristic confirms the p-type semiconducting nature. Ultrathin structures of nanoleaves lead to higher light trapping and light absorption in visible-NIR region. The nanoleaves film has lower bandgap in... 

Consider a binary-input memoryless outputsymmetric channel W. Such a channel has a capacity, call it I (W), and for any R < I (W) and strictly positive constant Pewe know that we can construct a coding scheme that allows transmission at rate R with an error probability not exceeding Pe. Assume now that we let the rate R tend to I (W) and we ask how we have to scale the blocklength N in order to keep the error probability fixed to Pe. We refer to this as the finite-length scaling behavior. This question was addressed by Strassen as well as Polyanskiy, Poor, and Verdu, and the result is that N must grow at least as the square of the reciprocal of I (W)- R. Polar codes are optimal in the sense... 

We propose a flexible four-wave mixing-based label recognition technique for low-weight spectral amplitude codes in optical packet-switched networks. We experimentally demonstrate label recognition, packet switching, and error-free transmission  

Tailored welded blanks (TWBs) technology can give the important possibilities to obtain components in the automobile industry. Friction stir welding (FSW) is a joining approach, which can adhere parts well with desired properties in weld zone. In this article, the main aim is investigation the effect of weld zone orientation on forming limit diagram (FLD) of the TWBs using experimental and finite element model. Three TWBs are produced FSW with three different orientations of weld zones including 00, 450 and 900 against major stress direction. The microstructure of the weld zones is divided and then observed via metallography procedures. Tensile tests are carried out to determine the... 

Stimulated devices are highly demanded for actuators and artificial muscles in the recent era but susceptible to low deformation at an applied voltage. In the present work, ionic liquids (ILs) based gel films were prepared from the polyvinyl chloride (PVC), dibutyl adipate (DBA), 1-butyl, 3-methimidazolium chloride, and 1-pentyl-3-methylimidazolium hexafluorophosphate by a simple solvent evaporation method. The structural, morphological, optical, and mechanical properties of the composite PVC/ILs gel were characterized by Fourier-transform infrared spectroscopy (FTIR), Large Angle X-ray scattering (LAXS), UV–visible (UV–vis) absorption spectroscopy, scanning electron micrpscopy (SEM) and... 

Stimulated devices are highly demanded for actuators and artificial muscles in the recent era but susceptible to low deformation at an applied voltage. In the present work, ionic liquids (ILs) based gel films were prepared from the polyvinyl chloride (PVC), dibutyl adipate (DBA), 1-butyl, 3-methimidazolium chloride, and 1-pentyl-3-methylimidazolium hexafluorophosphate by a simple solvent evaporation method. The structural, morphological, optical, and mechanical properties of the composite PVC/ILs gel were characterized by Fourier-transform infrared spectroscopy (FTIR), Large Angle X-ray scattering (LAXS), UV–visible (UV–vis) absorption spectroscopy, scanning electron micrpscopy (SEM) and... 

The specific adsorption of citrate from perchloric acid electrolytes, has been investigated using in-situ FTIR spectroscopy at Au(1 1 1) electrodes. For comparison IR spectra for formate adsorption are also presented. Clear voltammetric peaks have been observed positive of the pzc and these are shown by FTIR spectroscopy to be associated with the adsorption of citrate. Models for the surface co-ordination of the citrate anion are discussed. © 2002 Elsevier Science B.V. All rights reserved  

This work develops a systematic uncertainty quantification framework to assess the reliability of prediction delivered by physics-based material models in the presence of incomplete measurement data and modeling error. The framework consists of global sensitivity analysis, Bayesian inference, and forward propagation of uncertainty through the computational model. The implementation of this framework on a new multiphase model of novel porous silica aerogel materials is demonstrated to predict the thermomechanical performances of a building envelope insulation component. The uncertainty analyses rely on sampling methods, including Markov-chain Monte Carlo and a mixed finite element solution of... 

Abstract: Surface-nanostructured TiO2 nanorods were synthesized hydrothermally at 180 °C. Such nanorods have ‘crack-like’ surfaces that resemble burnt charcoal. Compared to nanorods with relatively smoother surfaces, the charcoal-like nanorods have higher-specific surface areas. By using the nanorods as a light-scattering layer in double-layered dye-sensitized solar cells, the cells based on the charcoal-like nanorods have 20 % higher dye loading and also higher diffuse reflectance compared with cells utilizing ‘smooth’ nanorods. The efficiency of a screen-printed double-layer dye-sensitized solar cell based on the charcoal-like nanorods is higher at 7.29 %. Electrochemical... 

Morphology tailored TiO2 nano assemblies consisting of nanorods with and without nanoparticle attachments were hydrothermally synthesized and their characteristics and light scattering properties were determined by x-ray diffraction (XRD), nitrogen sorption analysis, scanning electron microscopy (SEM), transmission electron microscopy (TEM), electrochemical impedance spectroscopy (EIS) and ultraviolet-visible spectroscopy (UV-Vis). The nanorod-nanoparticles (NR-NP) assemblies and smooth nanorod (NR) double layers were screen printed onto fluorine doped tin oxide coated glass underlayers to fabricate dye-sensitized solar cell (DSSC) photoanodes. The double layer heterogeneous... 

Study of the plastic deformation in polymeric honeycombs can pave the way for understanding the deformation localization in more complex cellular structures, which have received progressive attention in the past few years. This study compares the strain localization in deforming honeycombs made by two cost-effective 3D-printing technologies. Hexagonal honeycombs and their unit cell models were 3D-printed by both PolyJet™, using a photo-crosslinkable polymer, and fused deposition modeling (FDM) using a thermoplastic material. The state of the art digital image correlation (DIC) technique was employed as the experimental route in order to calculate the strain field during the deformation of... 

Four derivatives of hyaluronic acid (HA) bearing thiol (HA-SH), hydrazide (HA-hy), 2-dithiopyridyl (HA-SSPy), and aldehyde groups (HA-al) respectively were synthesized. Thiol and 2-dithiopyridyl as well as hydrazide and aldehyde make up two chemically orthogonal pairs of chemo-selective functionalities that allow in situ formation of interpenetrating (IPN) disulfide and hydrazone networks simultaneously upon the mixing of the above derivatives at once. The formation of IPN was demonstrated by comparing it with the formulations of the same total HA concentration but lacking one of the reactive components. The hydrogel composed of all four components was characterized by a larger elastic... 

In this study, Ni-Fe/SiC nanocomposite coatings with smooth and crack-free surface were successfully prepared by means of the conventional electrodeposition in the presence of saccharin in electrolyte. The goal of this work was to investigate the effect of SiC nanoparticles and saccharin on the structure and properties of permalloy nanocomposite coatings. The nanocomposite coatings were characterized using optical and scanning electron microscopy, energy dispersive X-ray (EDX) analysis and X-ray diffraction (XRD) technique. The significant variation in the crystallographic texture of the coatings was observed due to the addition of SiC nanoparticles and saccharin in the electrodeposition... 

Although the role of individual ingredients of hot mix asphalt (HMA) such as asphalt binder and aggregates on its performance is readily recognized, there is only limited understanding about the interactions between these components and the properties of binder-aggregate interface. In order to study the interactions between asphalt binder and mineral aggregates, an interfacial test method was developed and its effectiveness was evaluated. Interfacial interactions were evaluated by testing thin films of an asphalt binder interfaced with the surface of aggregates under two different modes of loading in shear: sinusoidal oscillation and monotonically increasing. An Interaction Parameter (IP)... 

Infrastructure as a Service (IaaS) is one of the most significant and fastest growing fields in cloud computing. To efficiently use the resources of an IaaS cloud, several important factors such as performance, availability, and power consumption need to be considered and evaluated carefully. Evaluation of these metrics is essential for cost-benefit prediction and quantification of different strategies which can be applied to cloud management. In this paper, analytical models based on Stochastic Reward Nets (SRNs) are proposed to model and evaluate an IaaS cloud system at different levels. To achieve this, an SRN is initially presented to model a group of physical machines which are... 

Infrastructure as a Service (IaaS) is one of the most significant and fastest growing fields in cloud computing. To efficiently use the resources of an IaaS cloud, several important factors such as performance, availability, and power consumption need to be considered and evaluated carefully. Evaluation of these metrics is essential for cost-benefit prediction and quantification of different strategies which can be applied to cloud management. In this paper, analytical models based on Stochastic Reward Nets (SRNs) are proposed to model and evaluate an IaaS cloud system at different levels. To achieve this, an SRN is initially presented to model a group of physical machines which are... 

Resonant sensors based on micro- A nd nano-electro mechanical systems (M/NEMS) are ubiquitous in many sensing applications due to their outstanding performance capabilities, which are directly proportional to the quality factor (Q) of the devices. We address here a recurrent question in the field: Do dynamical techniques that modify the effective Q (namely parametric pumping and direct drive velocity feedback) affect the performance of said sensors? We develop analytical models of both cases, while remaining in the linear regime, and introduce noise in the system from two separate sources: Thermomechanical and amplifier (read-out) noise. We observe that parametric pumping enhances the... 

Warm-up period is considered as the most critical phase in the operation of any device that converts the energy of a fuel into heat, electricity, and other products, including power generation units since the system efficiency and environmental pollution levels are much worse than the normal operation in that phase. Considering this point, in this study, applying the zero-flow coolant strategy to reduce the warm-up period is suggested for power generation units and it is investigated in details. An internal combustion engine is selected as the case-study and implementation of the method to enhance the performance of that from both energy and environmental aspects are studied comprehensively....