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    Numerical Simulation of Residual Stress Formation During Selective Laser Melting Process

    , M.Sc. Thesis Sharif University of Technology Maleki, Pedram (Author) ; Tavakoli, Rouhollah (Supervisor)
    Abstract
    One of the major challenges in Additive Manufacturing is the creation of residual stresses due to the high temperature gradient in the solidification zone. This will cause problems such as cracks in the structure, metallurgical defects as well as deformation and dimensional accuracy reduction in the finished product. The purpose of this study is to perform mathematical modeling and computer simulation of the selective laser melting process (SLM) to predict these stresses as well as identify the effective parameters on this phenomenon. The conditions were adjusted in this model with the actual coefficients of the device. Additionally, the powder used in this project is Ti6Al4V material. By... 

    Phase Field Simulation of Microstructure Ternary Eutectic Solidification

    , M.Sc. Thesis Sharif University of Technology Dalvand, Mehdi (Author) ; Tavakoli, Rouhollah (Supervisor)
    Abstract
    Physical and mechanical properties of cast alloys is partly a function of the morphology and volume fraction of phases from freezing. The microstructure of the eutectic solidification is function of physical properties (especially mobility and surface tension) and the volume fraction of phases involved in the evolution. The prediction of solidification microstructures will be very helpful for improving the mechanical properties of casting alloys and designing of new families of alloys. The theoretical study of the formation of eutectic microstructures is very difficult and almost impossible in general cases and empirical studies are expensive. The purpose of this study is to predict the... 

    A Phase-Field Model for Inhomogeneous Multiferroic Materials

    , M.Sc. Thesis Sharif University of Technology Jafari, Bahram (Author) ; Tavakoli, Rouhollah (Supervisor)
    Abstract
    In this thesis, by deliberately embedding “emplacements” in the system to locally break the inversion and the time reversal symmetries, the manifold of all possible microstructures is navigated in pursuit of the one that can give rise to maximal magnetoelectric effect mediated by elastic energy of piezoelectric-piezomagnetic phases via their interface --- needless to mention the low intensity of such an effect in single-phase multiferroics. The configuration with the maximal coupling is sought within the context of phase-field modeling. In order to numerically track the conserved dissipative dynamics of the interface (namely, the Cahn-Hilliard equation) --- that is nonlocal by the nature of... 

    Simulation of the Effect of Cooling Rate and Chemical Composition on the Atomic Structure of Bulk Metallic Glass Iron-Phosphorus and Nickel-Phosphorus

    , M.Sc. Thesis Sharif University of Technology Hosseinzadeh, Danial (Author) ; Tavakoli, Rouhollah (Supervisor)
    Abstract
    bulk metallic glass Unlike metal materials that have a crystalline structure, amorphous glass is an amorphous material with an irregular atomic structure that simultaneously has the same physical properties as metals. Due to the absence of crystal defects such as dislocation and grain boundaries, these materials show unique mechanical properties such as high strength and elastic strain, abrasion resistance and proper corrosion. However, their plastic deformation is heterogeneous, concentrated, and accompanied by sudden failure. Unlike metals, these materials do not have a long-range crystalline order, and their atomic structure includes short-range and mid-range order. The short-range order... 

    Thermal Optimization of Plain-Carbon Steel Continuous Casting Process

    , M.Sc. Thesis Sharif University of Technology Khosroabadi, Mohammad Reza (Author) ; Tavakoli, Rouhollah (Supervisor)
    Abstract
    Continuous casting is one of the ingot production methods in which the product has uniform chemical structure, low defects and high production rates. These days, carbon steel and nonferrous alloys are mainly produced by this special method. The design of continuous casting process includes a lot of difficulties due to its technological complexity. One of the most important aspects of this process is the heat transfer during solidification. In the present study, a new mathematical model and its corresponding numerical solution method have been introduced to establish the condition of directional solidification along the major ingot’s axis. The controlling parameters used in the model are... 

    Molecular Dynamics Study of Tungsten and Iron Addition on the Glass Formability of Cobalt-based Electrodeposited Coatings

    , M.Sc. Thesis Sharif University of Technology Bayati, Mohammad Baher (Author) ; Tavakoli, Rouhollah (Supervisor)
    Abstract
    Recent research suggests that the electrochemical deposition of cobalt-based binary alloys, such as cobalt-tungsten and cobalt-iron, can lead to the formation of amorphous structures in the coatings. Theoretical studies suggest that these structures are equivalent to structures created by the melt cooling of the alloy at speeds of about 〖10〗^10 Kelvin per second. The formation of a glass phase can significantly increase the abrasion resistance and corrosion resistance of these coatings. Empirical studies show that the ability of the glass to become glassy, or more precisely, the transition from crystalline to amorphous, is largely a function of the chemical composition. Simulation of... 

    A Phase Field Model for Simulating the Pitting Corrosion

    , M.Sc. Thesis Sharif University of Technology Hosseinali Arhani, Faezeh (Author) ; Tavakoli, Rouhollah (Supervisor)
    Abstract
    Corrosion is an electrochemical process that results in the degradation of metallic materials in a corrosive environment. Localized corrosion is a destructive form of corrosion that can lead to catastrophic failure of structures. In developed countries, corrosion costs more than 3% of gross national product every year, much more than the costs arisen from all-natural disasters combined. It is very important to understand this process to prevent sudden accidents and also develop high strength corrosion resistant metallic materials. This study presents the formulation and implementation of a phase field model for simulating the activation- and diffusion-controlled pitting corrosion phenomena... 

    Investigating the Effect of Chemical Composition on the Anisotropy of Solid-Liquid Interfacial Energy of Nickel-Niobium Alloy

    , M.Sc. Thesis Sharif University of Technology Ehsani, Mohammad Hossein (Author) ; Tavakoli, Rouhollah (Supervisor)
    Abstract
    Although the anisotropy of the solid-liquid interfacial free energy for most metal alloys is small, this anisotropy plays a significant role in the growth rate, morphology, and preferred crystallographic directions in dendritic growth. In recent research, the binary nickel-niobium alloy has been suggested as a suitable substitute for studying the solidification behavior of the superalloy Inconel 718. In this study, using molecular dynamics simulation with the LAMMPS software, pure nickel and Ni-%1Nb, Ni-%5Nb, and Ni-%10Nb alloys were examined (composition is based on atomic percent). After equilibrating the liquid and solid phases at the melting temperature, the interfacial phase was studied... 

    Energy Management through Topology Optimization of Microstructure of Tow Phase Functionally Graded Materials (FGMs) under Dynamic Loading

    , M.Sc. Thesis Sharif University of Technology Homayounfar, Zohreh (Author) ; Bagheri, Reza (Supervisor) ; Tavakoli, Rouhollah (Co-Advisor)
    Abstract
    A numerical algorithm is proposed to design microstructure of a two-phase functionally graded material under dynamic loading. In order to direct energy propagation through the desired regions in the domain, we introduced a regularized Heaviside function, H(x), in our objective functional, namely the time-averaged sum of the elastic strain energy and the kinetic energy. Real-life systems are however, not undamped, but possess some kind of energy dissipation mechanism or damping. In order to apply modal analysis of undamped systems to damped systems, we use Rayleigh damping model in our formulations. To generate a well-posed topology optimization, we used homogenization via a solid isotropic... 

    Numerical Simulation and Optimal Design in Gating System

    , M.Sc. Thesis Sharif University of Technology Shariatdoust, Mirali (Author) ; Tavakoli, Rouhollah (Supervisor) ; Davami, Parviz (Supervisor)
    Abstract
    A gating system is network of canals which leads molten metal to mold cavity. Fluid flow during mold filling is highly complex, involving transients, combined and divided flows at junctions, simultaneous heat transfer during fluid flow, turbulence, momentum exchange and energy loss. In case of non-uniform fluid flow at ingates, it causes week mechanical properties, and non-directional solidification. Accordingly, it cause riser insufficiency . In this Work by solving Bernoulli equations, fluid flow at each ingate was obtained and Genetic Algorithm was utilized for fluid flow optimization. Using this optimization method leads to reach to ideal design, simultaneously SUTCAST software was used... 

    Investigating the Microstructure, Mechanical Properties and Corrosion Resistance of Biodegradable Mg-Li-Zn Alloys

    , M.Sc. Thesis Sharif University of Technology Zohrevand, Mohammad (Author) ; Alizadeh, Reza (Supervisor) ; Tavakoli, Rouhollah (Co-Supervisor)
    Abstract
    Due to its biodegradability, magnesium can be a good option for making degradable medical implants that disappear in the body over time and thus there would be no need for secondary surgery. However, high rate of corrosion of magnesium in the body environment and low formability at room temperature are the two main problems of magnesium, which lead to rapid destruction of the sample in a short time and serious problems. For these reasons, much research is currently being done to improve the corrosion behavior and mechanical properties of magnesium alloys through microstructure modification. In this regard, special attention has been paid to Mg-Li alloys as the lightest magnesium alloys. The... 

    Three Dimentional Printing of Highly Porous Metamaterials Based on Polyurethane/Tricalcium Phosphate Composite for Tissue Engineering

    , M.Sc. Thesis Sharif University of Technology Hosseini, Danial (Author) ; Simchi, AbdolReza (Supervisor) ; Tavakoli, Rouhollah (Supervisor)
    Abstract
    In the last decade, mechanical metamaterials have attracted more attention due to new design principles that combine the concept of hierarchical architecture with material size effects at the micro or nano scale. This strategy shows extraordinary mechanical performance that we use in unknown parts of the material property space, including strength-to-density ratios, extraordinary flexibility, and the ability to absorb energy with brittle components. The aim of this research was to print metamaterial scaffolds from a combination of biocompatible and bioactive to be used as scaffolds in bone tissue engineering. In addition to the biological properties appropriate to the host tissue, the... 

    Corrosion Behavior of TLP Bonded 304 Stainless Steel Using Cobalt Base Interlayer

    , M.Sc. Thesis Sharif University of Technology Sadooghi, Sajjad (Author) ; Ekrami, Ali Akbar (Supervisor) ; Tavakoli, Rouhollah (Supervisor)
    Abstract
    The transient liquid phase bonding is a combination of penetration bonding and hard soldering processes. This method is based on the diffusion in the solid state of the melting point reducing elements from the joint zone into the base metal and isothermal solidification that the kinetics of this reaction are controlled by diffusion in the solid state. In this study, we investigate the bonding of 304 stainless steel with cobalt base interlayer by transient liquid phase method and studies of microstructural and corrosion resistance of the joint. Three different temperatures are considered for the bonding and after each bonding, the microstructure is examined with a optical and scanning... 

    Sprue-well Design Optimization by Means of Computer Simulation and Experimental Tests

    , M.Sc. Thesis Sharif University of Technology Yari Dehkaboudi, Ali (Author) ; Tavakoli, Rouhollah (Supervisor) ; Davami, Parviz (Co-Advisor)
    Abstract
    In many casting experiments, a well is used in the bottom of downsprue, which causes smooth flow in the runner. When the well is not properly designed, sand erosion happens in the runner and some oxide films and gaseous trap within the melt. These oxide films enter into the cast and decrease its strength and fatigue resistance. In addition, the gaseous trapped in the melt turn into solidification voids within the casting part which deteriorate its mechanical properties. The purpose of this research is to enhance casting efficiency by eliminating the mentioned defects. Modified design of sprue-well is proposed by the means of simulation with ProCAST software. Effective variables considered... 

    Study and Controlling Microstructure of Rapidly Solidified Multiprinciple Fe, Co and Ni Alloy

    , M.Sc. Thesis Sharif University of Technology Ghiasi Afjeh, Mohammad Bagher (Author) ; Tavakoli, Rouhollah (Supervisor) ; Aashuri, Hossein (Supervisor)
    Abstract
    Multi-principle alloys exhibit microstructure and different properties from most conventional alloys due to their high entropy, very slow diffusion and distorted crystal structure properties. Heat treatment, thermomechanical treatment, addition of alloying elements and control of solidification process are common methods of microstructure modification and property improvement. Among the solidification parameters, undercooling and cooling rate is one of the most suitable methods to obtain semi-stable and fine-grained phases. These parameters have been less studied in multi-principle alloys, while in the case of ferrous and cobalt alloys has been much studied. The main purpose of this type of... 

    Study of Structural and Mechanical Properties of Zr-, Ti- and La-based bulk Metallic Glasses

    , Ph.D. Dissertation Sharif University of Technology Asadi Khanouki, Mohammad Taghi (Author) ; Aashuri, Hossein (Supervisor) ; Tavakoli, Rouhollah (Supervisor)
    Abstract
    Bulk metallic glasses (BMGs), in contrast to conventional crystalline materials, are defined as metals with an amorphous and disordered atomic-scale structure. Due to the absence of dislocations and grain boundaries, BMGs have considerably unique mechanical properties such as high strength and elastic strain, high wear resistance and desirable corrosion resistance. However, they generally suffer from poor plasticity caused by an inhomogeneous deformation which leads to catastrophic failure by localization of strain into narrow regions, known as shear bands. This factor has extremely restricted their application as advanced structural materials. Furthermore, the recently discovered phenomenon... 

    Synthesis and swelling behavior of a new superabsorbent hydrogel network based on polyacrylamide grafted onto salep [electronic resource]

    , Article Journal of Applied Polymer Science ; Volume 112, Issue 5, pages 2625–2633, 5 June 2009 Pourdjavadi, A. (Ali) ; Rezanejad Barajee, Ghasem ; Soleyman, Rouhollah ; Sharif University of Technology
    Abstract
    Synthesis and swelling behavior of a new superabsorbent hydrogel based on natural salep grafted with polyacrylamide is described. The new superabsorbent hydrogel biopolymer was synthesized via radical crosslinking and graft copolymerization of acrylamide monomer onto salep backbones. Regarding to the water absorption of hydrogel, the best synthesis condition is reported. FTIR spectroscopy and thermogravimetric analysis were used to confirm the structure of the final product and a mechanism for superabsorbent hydrogel formation was also suggested. After preparing the desired hydrogels based on optimum condition, several factors affecting the swelling behavior of hydrogel including pH of... 

    Optimal Design of Parting Line in the Shape Casting Processes

    , M.Sc. Thesis Sharif University of Technology Pourfathi, Ali (Author) ; Tavakkoli, Rouhollah (Supervisor)
    Abstract
    More than 70 weight percentage of using parts in diverse industries (such as military, civil, automobile productions and etc.) are produceed by the casting processes. For each one of the casting procceses, mold cavity is requisite for arrived molten metal in the mold cavity to get eventuated as a solidified part. Based on mold ilk, if the mold is permanent, the cast part must be capable to be remoeved from the the mold inside. For the non-permanent mold (asssuming multi-piece and non-monolithic), if the model requires to be removed from the mold inside after molding and before casting, only model (no cast part) has to be moldable (why for removing the solidified cast part from the... 

    Production of Sn Base Composite Solder Reinforced by Nanoparticles Via Melt-spinning Technique

    , M.Sc. Thesis Sharif University of Technology Mohammadyari, Saeid (Author) ; Tavakkoli, Rouhollah (Supervisor)
    Abstract
    Lead-containing solder alloys in particular Sn-37Pb is the most common alloy used in electronics industry, this alloy has the good mechanical properties and excellent wetting properties and low prices. Recently, increasing environmental and health concerns over the toxicity of lead combined with strict legislation to ban the use of lead-based solders have provided an inevitable driving force for the development of lead-free solder alloys. A group of these lead-free solders are nanocomposite solders that because of having the reinforcement nano particles exhibit lots of unique properties, such as good mechanical and thermal properties. The aim of this research produce a new tin base... 

    Organic halides and nanocone plastic structures enhance the energy conversion efficiency and self-cleaning ability of colloidal quantum dot photovoltaic devices

    , Article Journal of Physical Chemistry C ; Volume 121, Issue 18 , 2017 , Pages 9757-9765 ; 19327447 (ISSN) Tavakoli, M. M ; Simchi, A ; Tavakoli, R ; Fan, Z ; Sharif University of Technology
    American Chemical Society  2017
    Abstract
    This paper presents solid-state ligand exchange of spin-coated colloidal lead sulfide quantum dot (PbS QD) films by methylammonium iodide (MAI) and integration of them in depleted heterojunction solar (DHS) devices having an antireflecting (AR) nanocone plastic structure. Time-resolved photoluminescence measurements determine a shorter lifetime of the charge carries on a semiconductor (TiO2) electron transfer layer for the MAI-passivated QD films as compared with those with long-chain aliphatic or short thiol ligands. Consequently, the DHS device yields improved power conversion efficiency (>125%) relative to oleic-acid-passivated PbS QD films. Using anodized aluminum oxide templates, an...