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Supercritical synthesis of a magnetite-reduced graphene oxide hybrid with enhanced adsorption properties toward cobalt & strontium ions
, Article RSC Advances ; Volume 6, Issue 17 , 2016 , Pages 13898-13913 ; 20462069 (ISSN) ; Outokesh, M ; Sharif University of Technology
Royal Society of Chemistry
2016
Abstract
The current study presents a supercritical synthesis of magnetite-reduced graphene oxide (M-RGO) in methanol media, in which Fe3O4 nanoparticles are simultaneously formed, surface modified and decorated on the surface of the reduced graphene oxide. Simulations using density functional theory, which were performed using the M06-2x/cc-pVDZ level of theory, indicate that upon adsorption of a Fe3O4 cluster on the graphene, the overall charge on the graphene surface becomes about -0.0236e, indicating charge transfer from the Fe3O4 cluster to the graphene surface. Instrumental and chemical analyses exhibited the formation of strong bonds between Fe3O4 and graphene, through C-O-Fe and C-Fe bridges....
Synthesis and Characterization of Graphene-based Material and Investigation of its Adsorption Properties for Radioactive Waste
, Ph.D. Dissertation Sharif University of Technology ; Outokesh, Mohammad (Supervisor)
Abstract
Nuclear power is a prominent alternative of fossil fuels that can effectively solve global warming, acid rains and other consequences of air pollutions, caused by combustion. Despite such obvious advantage, this highly compact form of energy suffers from a big problem corresponding to its nuclear waste. Graphene oxide (GO), a lamellar material with wide range of surface functional groups such as epoxy (C-O-C), hydroxyl, and carboxyl offers large surface area as well as high sorption capacity for the metallic cations. This thesis study presents a supercritical, and co-precipitation synthesis of magnetite- graphene oxide (M-GO) in which Fe3O4 nanoparticles are simultaneously formed, surface...
Numerical Analysis of a Supersonic Jet into a Subsonic Compressible Crossflow and the Effects on a Downstream Fin
, M.Sc. Thesis Sharif University of Technology ; Tayyebi Rahni, Mohammad (Supervisor)
Abstract
Jet into cross-flow interaction is one of the complex and fundamental problems in fluids dynamics and heat transfer, which is observed in various applications, such as pollutant discharges, film cooing of turbine blades, combustion chamber design of jet engines, trust vectoring systems, boundary layer control, and vertical short take-off and landing (VSTOL) aircrafts. One of the applications of this kind of flow is injection of supersonic jet into subsonic compressible cross-flow, which is used in trust vectoring systems of missiles. In this research, the two-dimensional interactions of supersonic jet into subsonic compressible cross-flow were investigated as two cases: "without a fin" and...
Computational Simulation of a 2D Sloshing Flow in a Rectangular Tank with Baffle, Using LBM
, M.Sc. Thesis Sharif University of Technology ; Tayyebi Rahni, Mohammad (Supervisor)
Abstract
In the this study, a numerical simulation of two-dimensional incompressible sloshing flow in a rectangular tank with baffle(s), using Lattice Boltzmann Method (LBM) is presented. Finite difference LBM and two-phase "Lee" model were used. The potential form of intermolecular forces is utilized to guarantee the stability of the numerical scheme and the discretization of the solution domain is performed by a two dimensional structured grid. Two different distribution functions are applied to obtain pressure, momentum, and composition of the particles. Furthermore, the Boltzmann transport equation is discretized, by using standard D2Q9 method. The "dropl" test case is simulated by the present...
Pore-scale Simulation of Flow around a Micro-porous Square Cylinder, Using Hybrid LBM-FVM, Considering Slip Condition Inside Porous Media
, M.Sc. Thesis Sharif University of Technology ; Tayyebi Rahni, Mohammad (Supervisor)
Abstract
In recent years, application of porous media is highlighted among researchers due to their wider use in micro-scale problems, such as in gas reservoirs, micro-filtering, and heat exchangers. In such applications, accurate description of flow behavior, using governing equations based on continuum assumption, is not valid, since mean free path has the same order as the characteristic length of the problem. In such cases, imposing appropriate slip condition on the fluid-solid interface of porous media (in pore-scale level), based on kinetics theory, is an appropriate approach. For this purpose, pore-scale simulation of flow inside porous media in slippery and transient regimes is carried out...
Two-phase Flow Modeling of Drop Impact on Moving Surfaces, Using Multiphase Lattice Boltzmann Flux Solver
, Ph.D. Dissertation Sharif University of Technology ; Tayyebi Rahni, Mohammad (Supervisor)
Abstract
Various situations of drop impact on solid surfaces occur widely in natural phenomena and industrial applications, as well as involve in the development of some new technologies, such as, 3D printers, interfacial materials, microfluidics, and biotechnology. Therefore, the relevant investigations have been increasing considerably in the last two decades. Most of these studies are related to the simple case of vertical drop impact on horizontal stationary surfaces, while in most cases vertical/oblique drop impact on horizontal/inclined stationary/moving surfaces in the absence/presence of a crossflow and their various combinations occur. One of the most important situations is drop impact on...
Dark silicon and the history of computing
, Article Advances in Computers ; Volume 110 , 2018 , Pages 1-33 ; 00652458 (ISSN); 9780128153581 (ISBN) ; Sarbazi Azad, H ; Sharif University of Technology
Academic Press Inc
2018
Abstract
For many years, computer designers benefitted from Moore's law and Dennard scaling to significantly improve the speed of single-core processors. The failure of Dennard scaling pushed the computer industry toward homogenous multicore processors for the performance improvement to continue without significant increase in power consumption. Unfortunately, even homogeneous multicore processors cannot offer the level of energy efficiency required to operate all the cores at the same time in today's and especially tomorrow's technologies. As a result of lack of energy efficiency, not all the cores in a multicore processor can be functional at the same time. This phenomenon is referred to as dark...
Temporal prefetching
, Article Advances in Computers ; 2021 ; 00652458 (ISSN) ; Sarbazi Azad, H ; Sharif University of Technology
Academic Press Inc
2021
Abstract
Many applications, including big-data server applications, frequently encounter data misses. Consequently, they lose significant performance potential. Fortunately, data accesses of many of these applications follow temporal correlations, which means data accesses repeat over time. Temporal correlations occur because applications usually consist of loops, and hence, the sequence of instructions that constitute the body of a loop repeats many times, leading to data access repetition. Temporal data prefetchers take advantage of temporal correlation to predict and prefetch future memory accesses. In this chapter, we introduce the concept of temporal prefetching and present two instances of...
Spatial prefetching
, Article Advances in Computers ; 2021 ; 00652458 (ISSN) ; Sarbazi Azad, H ; Sharif University of Technology
Academic Press Inc
2021
Abstract
Many applications extensively use data objects with a regular and fixed layout, which leads to the recurrence of access patterns over memory regions. Spatial data prefetching techniques exploit this phenomenon to prefetch future memory references and hide their long latency. Spatial prefetchers are particularly of interest because they usually only need a small storage budget. In this chapter, we introduce the concept of spatial prefetching and present two instances of spatial data prefetchers, SMS and VLDP. © 2021 Elsevier Inc
Preface
, Article Advances in Computers ; Volume 125 , 2022 , Pages ix-x ; 00652458 (ISSN); 9780323851190 (ISBN) ; Sarbazi Azad, H ; Sharif University of Technology
Academic Press Inc
2022
Temporal prefetching
, Article Advances in Computers ; Volume 125 , 2022 , Pages 31-41 ; 00652458 (ISSN); 9780323851190 (ISBN) ; Sarbazi Azad, H ; Sharif University of Technology
Academic Press Inc
2022
Abstract
Many applications, including big-data server applications, frequently encounter data misses. Consequently, they lose significant performance potential. Fortunately, data accesses of many of these applications follow temporal correlations, which means data accesses repeat over time. Temporal correlations occur because applications usually consist of loops, and hence, the sequence of instructions that constitute the body of a loop repeats many times, leading to data access repetition. Temporal data prefetchers take advantage of temporal correlation to predict and prefetch future memory accesses. In this chapter, we introduce the concept of temporal prefetching and present two instances of...
Spatial prefetching
, Article Advances in Computers ; Volume 125 , 2022 , Pages 19-29 ; 00652458 (ISSN); 9780323851190 (ISBN) ; Sarbazi Azad, H ; Sharif University of Technology
Academic Press Inc
2022
Abstract
Many applications extensively use data objects with a regular and fixed layout, which leads to the recurrence of access patterns over memory regions. Spatial data prefetching techniques exploit this phenomenon to prefetch future memory references and hide their long latency. Spatial prefetchers are particularly of interest because they usually only need a small storage budget. In this chapter, we introduce the concept of spatial prefetching and present two instances of spatial data prefetchers, SMS and VLDP. © 2022 Elsevier Inc
Synthesis, and Characterization of Binuclear Platinum (IV)with Coinage Metals
, M.Sc. Thesis Sharif University of Technology ; Jamali, Sirous (Supervisor)
Abstract
In this research binuclear platinum(IV) complexes with coinage metals have been synthesized and characterized. the trimethyl platinum(IV) complex [PtMe3(phthalazine)3]+X- has been prepared by the reaction of [PtMe3(THF)]4 with 3 equiv. phthalazine and used as initial material. The first complex, [PtMe3(µ-(phthalazine)2Cl)PtMe3], synthesized via reaction of 2 equiv. [Pt(Me)3(Phthalazine)3] with 1 equiv. [AuClSMe2]. The second complex, [PtMe3(µ-phthalazine)3Ag][BF4], synthesized by reaction of one equiv. of each compound [Ag(CH3CN)4]BF4 and [Pt(Me)3(Phthalazine)3] And the third complex, [PtMe3(µ-phthalazine)3Cu][PF6], synthesized like second one via reaction of [Cu(CH3CN)4]PF6 and...
Neuromorphic multiple-fault diagnosing system based on plant dynamic characteristics
, Article Industrial and Engineering Chemistry Research ; Volume 52, Issue 36 , 2013 , Pages 12927-12936 ; 08885885 (ISSN) ; Boozarjomehry, R. B ; Shahrokhi, M ; Sharif University of Technology
2013
Abstract
In many cases, multiple-fault diagnosis of plant-wide systems based on steady-state data is impossible. To solve this problem, a new diagnosis strategy based on neural networks has been proposed. In the suggested framework, the neural network is used as the diagnoser trained by a hybrid set of steady and dynamic characteristic data of the system. The dynamic characteristic data include overshoot and undershoot values of measured variables and their corresponding occurrence times. To evaluate its performance, the proposed scheme was used in the diagnosis of the concurrent faults of the Tennessee Eastman (TE) process. Various combinations of concurrent faults were considered in this...
Fault diagnosis in a yeast fermentation bioreactor by genetic fuzzy system
, Article Iranian Journal of Chemistry and Chemical Engineering ; Volume 29, Issue 3 , 2010 , Pages 61-72 ; 10219986 (ISSN) ; Shahrokhi, M ; Bozorgmehry Boozarjomehry, R ; Sharif University of Technology
2010
Abstract
In this paper, the fuzzy system has been used for fault detection and diagnosis of a yeast fermentation bioreactor based on measurements corrupted by noise. In one case, parameters of membership functions are selected in a conventional manner. In another case, using certainty factors between normal and faulty conditions the optimal values of these parameters have been obtained through the genetic algorithm. These two cases are compared based on their performances in fault diagnosis of a yeast fermentation bioreactor for three different conditions. The simulation results indicate that the fuzzy-genetic system is superior in multiple fault detection for the conditions where the minimum and...
Algebraic Sets and Their Minimal Polynomials in a Division Ring, a General Setting
, M.Sc. Thesis Sharif University of Technology ; Mahdavi-Hezavehi, Mohammad (Supervisor)
Abstract
A Weddernurn polynomial over a division ring K, is the minimal polynomial of an algebraic subset of K. Such a polynomial, always is a product of linear factors over K, but not all such products are Wedderburn polynomials, even if these linear factors are distinct. In this thesis, we give some properties and characterizatios of Wedderburn polynomials over the division ring K, which relates deeply to algebraic subsets of K. We work in the general setting of Ore skew polynomials with an indeterminate t over K, corresponding to S,D, where S is an endomorphism of K and D is an S-derivation over K. Also we give a survey of the structure of the skew polynomial ring K[t; S; D] and its relation with...
Optimization of Airfoil Design Using Low-dimensional POD Method
, M.Sc. Thesis Sharif University of Technology ; Tayyebi Rahni, Mohammad (Supervisor)
Abstract
The aim of this research was investigation, development and application of lowdimensional proper orthogonal decomposition method for simulation of flow field and airfoil design. Sine analytical methods have low accuracy and limitations and also experimental methods have other problems, researchers usually use computational approach, which mostly do not have acceptable efficiency and speeds of computational. The idea of application of reduced order modeling which originally comes from control theories and structural analysis, have attracted many researcher in recent years. In this research, we also used POD and flow data to obtain a fast module of aerodynamic airfoil design. The goals of...
Processing Thin Magnesium Tubes by TCAP Process with Trapezoidal Geometry and Fabrication of Magnesium Microtubes with a Novel Method
, M.Sc. Thesis Sharif University of Technology ; Assempour, Ahmad (Supervisor)
Abstract
Due to compability of Magnesium with the body, it is a suitable material for making biodegradable stents, Althogh, its mechanical properties are not desirable for stent application. Accordingly, lately, magnesium’s microstructure and mechanical properties have been improved using various methods, including the process of severe plastic deformation (SPD). Many severe plastic deformation methods have been introduced for the fabrication of ultrafine grain tubes till now, which the process of tubular channel angular pressing (TCAP) is the most effective one. In the first part of the research, Magnesium tubes with a thickness of 1 mm were processed using the TCAP with a trapezoidal channel, and...
Synthesis and characterization of ultrasound assisted "graphene oxide-magnetite" hybrid, and investigation of its adsorption properties for Sr(II) and Co(II) ions
, Article Applied Surface Science ; Volume 353 , 2015 , Pages 350-362 ; 01694332 (ISSN) ; Outokesh, M ; Moradi, S ; Doram, A ; Sharif University of Technology
Elsevier
2015
Abstract
Magnetite nanoparticles with a size distribution of 15-21 nm were synthesized and decorated onto surface of graphene oxide by ultrasound assisted precipitation. Size and size distribution of the obtained M-GO hybrid were appreciably finer than the hybrids prepared by stirring method. M-GO is a superparamagnetic material with saturation magnetization of 31 emu g-1. The Langevin equation was successfully applied for estimation of size of Fe3 O4 nanoparticles in M-GO hybrid, with maximum error of 17.5%. The study put forward a formation mechanism for M-GO, based on instrumental analyses. Adsorption isotherms of Sr2+ and Co2+ ions, which were fitted by Langmuir monolayer...
Synthesis and characterization of a bentonite-alginate microspherical adsorbent for removal of uranyl ions from aqueous Solutions
, Article Separation Science and Technology ; Volume 45, Issue 2 , 2010 , Pages 288-298 ; 01496395 (ISSN) ; Khanchi, A ; Ghofrani, M.B ; Outokesh, M ; Sharif University of Technogy
2010
Abstract
A novel microspherical adsorbent for the removal of uranium from aqueous solutions was developed by immobilizing of natural bentonite in the polymeric matrix of calcium alginate. Different uptake properties of the prepared microspheres were examined using batch, stirred and column methods. The adsorbent showed high affinity toward uranium ions, especially at pHs above 3. Major uptake mechanisms included ion exchange, chelating of the (UO2)2+ ions to the -OH groups of alginate, and surface complexation with bentonite. Surprisingly, the capacity of microspheres was higher than both its constituents, revealing that a synergetic effect occurs. Adsorption kinetics was controlled by slow chemical...