Sharif Digital Repository

Pure polypyrrole (PPy), PPy/Al2O3 and PPy/SiO2 nanocomposites synthesized galvanostatically using different polymerization charges. Electrochemical impedance measurements of pure polypyrrole revealed that the film thickness affected the impedance responses. The characteristic frequencies vs. film thickness that obtained using Cole-Cole plots showed that electrodeposition mechanism changed from 3D to 1D after nuclei overlapping for pure PPy. Analysis of the nanocomposites impedance spectrums revealed no changes during the film growth, i.e. deposition continues 3D even after nuclei overlapping. Scanning electron microscopy (SEM) confirmed the impedance results and showed that the morphology of... 

An efficient algorithm for the design optimization of the compressible fluid flow problem through a flexible structure is presented. The methodology has three essential parts: first the behavior of compressible flow in a supersonic diffuser was studied numerically in quasi-one-dimensional form using a flux splitting method. Second, a fully coupled sequential iterative procedure was used to solve the steady state aeroelastic problem of a flexible wall diffuser. Finally, a robust Genetic Algorithm was implemented and used to calculate the optimum shape of the flexible wall diffuser for a prescribed pressure distribution. © 2006 Elsevier Ltd. All rights reserved  

The properties of Functionally Graded Materials (FGM) are characterized by gradual variation of volume fraction of their constituents or phases over the thickness direction. They are normally ceramic in one side and metal in the other side. This kind of material has been employed as thermal barrier and also as coatings in many applications including turbine blades. Thermal stress behavior of FGMs is normally studied by simulating the material as a composite laminate where the properties ofeach layer are found by averaging the properties and volume fraction of FGM constituents through the thickness of the layer. However, it should be mentioned that the grains of FGM constituents are usually... 

The electrodeposition of nickel was studied using electrochemical techniques in different electrolytes and various agents. The voltammetry analysis clearly showed that the electrodeposition of nickel was a diffusion-controlled process associated with a typical nucleation process. The current transients represented instantaneous nucleation with a typical three-dimensional (3D) growth mechanism. Scharifker's equations were derived for instantaneous and progressive nucleation of the 3D growth of the spherical centers under diffusion-controlled condition. The number of nucleation sites increased with the increment in overpotential and Ni 2+ concentration. Atomic force microscopy was used to... 

Nickel nanostructure thin films were electrodeposited on copper plates to investigate the fractal study. Scharifker's equations were derived for instantaneous and progressive nucleation and 3D growth of hemispherical centres under diffusion-controlled condition to calculate in situ change of fractal dimension of surface. It was assumed that the layer could be formed completely when fractal dimension of surface inclined to 2. Moreover, the fractal analysis of atomic force microscopy (AFM) images has confirmed the presumed model. Also, the power values of power spectral density (PSD) of the AFM images were determined using fast Fourier transform (FFT) algorithms. The PSD plots are approximated... 

Overwhelming number of control laws has been studied for control of robot manipulators with rigid links and joints. However controllers designed under this assumption may not accurately control the manipulator link due to visco-elastic properties that appear in the link behavior. In this study, a novel approach for robust control of a single-link manipulator is presented to force the link to have rigid motions, while it has visco-elastic behavior. In this regard, initially robot dynamics is extracted, followed by the design of four appropriate controllers through the loop-shaping approach. The obtained model is first represented in state space, however later converted to transfer function... 

In this paper, a new algorithm for solving the shortest loop design problem is presented. The shortest loop design problem is to find the shortest loop for an automated guided vehicle covering at least one edge of each department of a block layout. In this paper, first it is shown that this problem can be represented as a graph model. The properties of the presented model enable us to design a meta-heuristic based on ant colony system algorithm for solving the shortest loop design problem. Computational results show the efficiency of our algorithm in compare to the other techniques  

In this research, we investigate a three-stage supply chain with one supplier, several manufacturers and multiple retailers where the supplier provides a common raw material to each manufacturer, who in turn uses a single stage production facility to convert it into final products that are delivered at fixed lot sizes to retailers. An integrated economic procurement, production, and delivery model is developed whose objective is to find the common production cycle length, production sequences of final products at manufacturers and delivery frequencies of final products to retailers minimizing the total costs of considered supply chain. We propose an analytical solution procedure and an...