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    Experimental and Numerical Study of SO2 Adsorption/desorption by NH2-MIL-53 Metal-organic Framework (MOF)

    , M.Sc. Thesis Sharif University of Technology Noushadi, Atefeh (Author) ; Fotovat, Farzam (Supervisor) ; Vahidi, Mahdi (Co-Supervisor) ; Hamzelouyan, Tayebeh (Co-Supervisor)
    Abstract
    Sulfur dioxide is known as an acidic gas and one of the standard pollutants in determining air quality. This gas mostly enters into the atmosphere by flue gas causing many environmental problems. In order to remove this gas, various methods are used. One of the suitable methods to reduce the emission of this pollutant in low concentrations is the use of Metal-Organic Frameworks (MOF) as an adsorbent. One of these Metal-Organic Frameworks is NH2-MIL-53(Al) that owing to its relatively good stability under wet and acidic conditions, has been chosen to adsorb sulfur dioxide in this research. In most studies on SO2 adsorption, often MOFs with a long synthesis time, high synthesis cost, and/or... 

    Polyethylene quality control in an industrial scale fluidized bed reactor

    , Article Indian Journal of Chemical Technology ; Volume 25, Issue 1 , January , 2018 , Pages 21-30 ; 0971457X (ISSN) Vahidi, O ; Shahrokhi, M ; Sharif University of Technology
    National Institute of Science Communication and Information Resources (NISCAIR)  2018
    Abstract
    Polymer quality control in an industrial scale polyethylene fluidized bed reactor has been addressed. Since online measurements of polymer properties (melt index and density) are not available, they must be controlled indirectly via other available measurements. In the present paper, two algebraic equations correlating polyethylene melt index and density with the measureable concentrations of chemical components are obtained. Having the desired polyethylene properties and using these correlations, desired concentrations of chemical components are calculated and used via corresponding control loops. By using the infrequently available polyethylene property measurements, the correlation... 

    Time-dependent estimation of origin–destination matrices using partial path data and link counts

    , Article Transportation ; 2023 ; 00494488 (ISSN) Vahidi, M ; Shafahi, Y ; Sharif University of Technology
    Springer  2023
    Abstract
    The precise estimation of time-varying demand matrices using traffic data is an essential step for planning, scheduling, and evaluating advanced traffic management systems. This paper presents an innovative method, based on the least squares approach, to handle the inherent complexities of estimating the dynamic characteristics of changing demand flow over time while considering congestion conditions. The time-dependent origin–destination (OD) demand matrices of the network are estimated by exploiting the received partial paths data from an automated vehicle identification system and vehicle counts data from loop detectors on a subset of the links. A traffic assignment approach based on... 

    Porous gelatin/poly(ethylene glycol) scaffolds for skin cells

    , Article Soft Materials ; Volume 15, Issue 1 , 2017 , Pages 95-102 ; 1539445X (ISSN) Vahidi, M ; Frounchi, M ; Dadbin, S ; Sharif University of Technology
    2017
    Abstract
    Biocompatible porous polymeric scaffolds provide a suitable environment for proliferation of stem cells in human body. In this research work, porous gelatin–poly(ethylene glycol), PEG, based scaffolds were prepared using combination of freeze-gelation and freeze-extraction methods. Effects of various parameters such as freezing temperature, cross-linking agent, concentrations of gelatin and PEG and their blending ratio on physical and mechanical properties, swelling ratio, porosity, pore size, and degradation rate of scaffolds were investigated. Also, proliferation of fibroblast skin cells on the scaffolds was examined by MTS assay to assess the suitability of the scaffolds in wound healing... 

    Control of a fluidized bed polyethylene reactor

    , Article Iranian Journal of Chemistry and Chemical Engineering ; Volume 27, Issue 3 , September and October , 2008 , Pages 87-101 ; 10219986 (ISSN) Vahidi, O ; Shahrokhi, M ; Mirzaei, A ; Sharif University of Technology
    2008
    Abstract
    In present paper, dynamic behavior and control of a fluidized bed reactor for polyethylene production has been considered. A double active sites model for Ziegler-Natta catalysts is used for simulation of polymerization reaction. Hydrodynamic behavior of the bed is modeled using a two phase model including bubble and emulsion phases in which bubble phase has plug flow pattern with differentially variable velocity and size through the bed and emulsion phase has the CSTR flow pattern. The reactor model is validated using industrial data. Conventional PID controllers with anti-windup are considered for control purposes. It has been shown that the control system has satisfactory performances... 

    Methods of reducing magnetic field near the transmission lines

    , Article Amirkabir (Journal of Science and Technology) ; Volume 14, Issue 55 A , 2003 , Pages 610-630 ; 10150951 (ISSN) Porkar, B ; Porkar, S ; Vahidi, B ; Sharif University of Technology
    2003
    Abstract
    Due to biological effects of magnetic fields of high voltage transmission lines and induceed effects on gas pipe line, telecommunication system and inteference with sensitive electronic equipment, many effort have been done to reduce transmission lines magnetic fields and several ideas have been introduced. In this paper we review three methods: phase split, shielded and compacted line methods. With aid of a developed software programme these methods are then applied to transmission lines and the results are analyzed  

    Synthetic Model Based in Viable System Model and System Dynamics for Analysis and Design of Systems

    , M.Sc. Thesis Sharif University of Technology Vahidi Monfared, Amin (Author) ; Shadrokh, Shahram (Supervisor)
    Abstract
    This is common for organizations to don't move in their specified mission statement direction, because of pressures for saving themselves in reaction to environment changes. This problem can be addressed as conflict between survival and identity. In this thesis we approach this problem by synthesizing "Viable System Model" and "System Dynamics". Basic of this model shaped on viable system model structure and system dynamics modeling. In literature there is only two such models. But they are not detailed enough for providing mathematical analysis. In this research, law of requisite variety (one of the key principles in cybernetics) has been quantified. In this synthetic model, appropriate... 

    Information Superiority between Individual and Institutional Traders in Tehran Stock Exchange

    , M.Sc. Thesis Sharif University of Technology Vahidi, Hamed (Author) ; Keshavarz Haddad, Gholamreza (Supervisor)
    Abstract
    Informational inequality between institutional and individual traders is one of the centric issues in financial markets. The preference of each of these groups to attain personal information may provide other traders important information. New traders could make a profit by addressing the preferable group and following its transactions. This study aims to determine the winner group at attaining more personal information, by breaking down the probability of informed trading (PIN), one of the most famous measures in informational risk to two main components: the probability of informed trading of individuals (DPIN) and the probability of informed trading of institutions (SPIN). Moreover, the... 

    Effect of particle size on the microstructure of rapidly solidified Al-20Si-5Fe-2X (X = Cu, Ni, Cr) powder

    , Article Journal of Alloys and Compounds ; Volume 466, Issue 1-2 , 2008 , Pages 111-118 ; 09258388 (ISSN) Rajabi, M ; Simchi, A ; Vahidi, M ; Davami, P ; Sharif University of Technology
    2008
    Abstract
    The effects of particle size and alloying elements on the size and morphology of secondary/intermetallic phases in gas atomized Al-20Si-5Fe-2X (X = Cu, Ni, Cr) powders were studied. The microstructure composed of particle-like primary Si with average diameter of 0.5-2.7 μm, δ-Al4FeSi2 intermetallic compound containing small amount of dissolved alloying elements with the size of 1.4-7.7 μm, and fine Al-Si eutectic matrix with 0.25-0.4 μm spacing. As the powder particle size decreases, the primary silicon becomes finer while its morphology is not affected. For instance, 58-75% reduction in the size of primary silicon was observed when decreasing the average particle size from 89 to 18 μm. A... 

    Microstructural features of rapidly solidified Al-20Si-5Fe-2X(X=Cu, Ni, Cr) powders

    , Article European Powder Metallurgy Congress and Exhibition, Euro PM 2007, Toulouse, 15 October 2007 through 17 October 2007 ; Volume 2 , 2007 , Pages 3-8 ; 9781899072293 (ISBN) Rajabi, M ; Simchi, A ; Vahidi, M ; Davami, P ; Sharif University of Technology
    European Powder Metallurgy Association (EPMA)  2007
    Abstract
    The size and morphology of secondary phase and intermetallic compounds in gas atomized Al- 20Si-5Fe-2X (X=Cu, Ni, Cr) powders were studied. It was shown that the microstructure compromised of fine particle-like primary Si, aciculate δ-Al9FeSi3 intermetallic compound containing small amount of dissolved alloying elements, and fine Al-Si eutectic matrix. Decreasing the powder particle size yields finer primary silicon but its morphology is not affected. Also, significant refinement in the size of δ-Al9FeSi3 intermetallic was observed as the particles become finer. This particle size effect on the microstructure of Al-20Si-5Fe alloy was found to be influenced by the presence of chromium. Here,... 

    Application of an amino-functionalized MIL-53(Al) MOF as an efficient, selective, and durable adsorbent for SO2removal

    , Article Journal of Environmental Chemical Engineering ; Volume 10, Issue 6 , 2022 ; 22133437 (ISSN) Noushadi, A ; Fotovat, F ; Hamzehlouyan, T ; Vahidi, M ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    Sulfur dioxide (SO2) is one of the acidic components found in the flue gas that can harm industrial facilities and the environment. SO2 adsorption by metal-organic frameworks (MOFs) is an emerging method to effectively remove SO2 in low concentrations from the gas mixtures. In this study, amino-functionalized MIL-53(Al), i.e., NH2-MIL-53(Al), was synthesized through the solvothermal method and examined for SO2 adsorption at relatively moderate pressure and temperature (up to 2 bar, 25-80 °). According to the results of XRD, FT-IR, TGA, and DSC analysis, NH2-MIL-53(Al) demonstrated appropriate water, acid, and thermal stability. The SO2 adsorption capacity of NH2-MIL-53(Al) was 5.21 mmol.g-1... 

    Mechanical response of single and double-helix SMA wire ropes

    , Article Mechanics of Advanced Materials and Structures ; Volume 29, Issue 26 , 2022 , Pages 5393-5406 ; 15376494 (ISSN) Vahidi, S ; Arghavani, J ; Choi, E ; Ostadrahimi, A ; Sharif University of Technology
    Taylor and Francis Ltd  2022
    Abstract
    In this paper, based on three-dimensional phenomenological model and using a user-defined material subroutine mechanical behavior of shape memory alloy (SMA) wire ropes (or cables) and their components have been studied through implicit solution method in Abaqus software. Material parameters have been extracted using available experimental data and numerical simulations. Due to the convoluted geometry and interwire contact status within a cable, a finite element analysis is firstly performed for a 1 × 37 steel wire rope to validate modeling and mechanical interactions of a wire rope. Afterwards, superelastic and shape memory effect cables with different constructions (7 × 7 and 1 × 27) are... 

    Fabrication of Porous Gelatin-based Scaffold and Evaluation of Effect of Gamma Irradiation

    , M.Sc. Thesis Sharif University of Technology Vahidi, Milad (Author) ; Forounchi, Massoud (Supervisor) ; Dadbin, Susan (Supervisor)
    Abstract
    Biocompatible porous polymeric scaffolds provide a suitable 3-D environment for proliferation of stem cells in human body. For instance, growth and proliferation concurrent with differentiation of stem cells in such scaffolds can regenerate the tissues or organs. In this attitude we fabricated a porous Gelatin-based scaffold using both of freeze-drying and freeze-extraction methods.Also, effect fo gamma irradiation on microstructure of scaffolds was investigated. In addition, poly(ethylene glycol) was employed to make the scaffold softer. Moreover, effects of various parameters including freezing temperature, cross-linking agent concentration, gelatin and PEG concentrations and their... 

    Nano\Micro-Structural Investigation during Rapid Solidification of Al-20Si-(5Fe) Alloys and Modeling of Solidification Parameters

    , M.Sc. Thesis Sharif University of Technology Vahidi, Mahmoud (Author) ; Simchi, Abdolreza (Supervisor) ; Davami, Parvez (Co-Advisor)
    Abstract
    Nano/Micro-structure of rapidly solidified (products of Atomizing and Melt Spinning processes) Al-20Si-(5Fe) alloys has been investigated at the present work. Moreover, the effect of cooling rate on microstructure and growth morphology of these alloys has been studied. Microstructure of the products was examined by using optical microscopy, scanning electron microscopy, transmission electron microscopy, and X-ray diffraction.At the present work some models have been proposed for driving a relationship between microstructure and rapid solidification parameters during Atomizing and Melt Spinning processes. These models are based on macroscopic heat transfer during the processes. Model for... 

    Effect of anode compositions on the current efficiency of zinc electrowinning

    , Article Proceedings - European Metallurgical Conference, EMC 2011 ; Volume 2 , 2011 , Pages 387-396 ; 9783940276377 (ISBN) Dashti, S ; Rashchi, F ; Vahidi, E ; Emami, M ; Khoshnevisan, A ; Sharif University of Technology
    2011
    Abstract
    The main goals in zinc electrowinning process are decreasing of power consumption and increasing of current efficiency. The purpose of this research was to investigate effect of different alloy compositions used in production of lead-based anodes on the zinc electrowinning process. The anode compositions prepared and examined in this study were binary alloys Pb - (0.5 and 2 %) Ag and quaternary alloys Pb - 0.5 % Ag - 1 % Ca - 2 % Sn, Pb - 0.5 % Ag - 1 % Ca - 1 % Sn - 1 % Sb and Pb - 0.5 % Ag - 1 % Ca - 1 % Sn - 1 % Bi. The electrowinning experiments were conducted using a laboratory-scale apparatus, at a plating time of 4 hours, a current density of 500 to 1000 A/m2, industrial zinc sulfate... 

    Blood Glucose Control for Type 1 Diabetes Patients with Explicit Model Predictive Control (MPC)

    , M.Sc. Thesis Sharif University of Technology Shahzadeh Fazeli, Ali (Author) ; Alasty, Aria (Supervisor) ; Vahidi, Omid (Co-Supervisor)
    Abstract
    Blood glucose regulation in type 1 diabetes patients requires the delivery of the proper amount of insulin from an external source. The literature of Blood Glucose Control signifies the superiority of model-based controllers over the other ones. Regarding its lack of need to complicated on-line calculations and the simplicity of its implementation on a micro-chip, the explicit Model Predictive Controller is preferred over the implicit MPC. Currently proposed explicit MPC controllers have employed relatively simple models representing human glucose-insulin dynamics. In this thesis, an explicit MPC controller is designed using mp-QP based on Sorensen’s 19-state comprehensive model which has... 

    MBBR and MBR Reactor Configuration for Better Performance

    , M.Sc. Thesis Sharif University of Technology (Author) ; Borgheei, Mahdi (Supervisor)
    Abstract
    Membrane bioreactors (MBRs) which are commonly understood as the combination of membrane filtration and biological treatment using activated sludge have several advantages, but membrane fouling reduces the membrane efficiency, permeability and lifetime. An alternative is replacing a moving bed biofilm reactor (MBBR) with the activated sludge system which may reduce the effect of membrane fouling. The sludge produced in MBBRs has poor settling characteristics, therefore, their efficiency is limited by the sedimentation tank performance and they require a larger settling surface. The combination of moving bed biofilm reactors and membrane bioreactors can compensate for the drawbacks of both of... 

    Complexity of computing the anti-ramsey numbers for paths

    , Article 45th International Symposium on Mathematical Foundations of Computer Science, MFCS 2020, 25 August 2020 through 26 August 2020 ; Volume 170 , 2020 Amiri, S. A ; Popa, A ; Roghani, M ; Shahkarami, G ; Soltani, R ; Vahidi, H ; Sharif University of Technology
    Schloss Dagstuhl- Leibniz-Zentrum fur Informatik GmbH, Dagstuhl Publishing  2020
    Abstract
    The anti-Ramsey numbers are a fundamental notion in graph theory, introduced in 1978, by Erdös, Simonovits and Sós. For given graphs G and H the anti-Ramsey number ar(G, H) is defined to be the maximum number k such that there exists an assignment of k colors to the edges of G in which every copy of H in G has at least two edges with the same color. Usually, combinatorists study extremal values of anti-Ramsey numbers for various classes of graphs. There are works on the computational complexity of the problem when H is a star. Along this line of research, we study the complexity of computing the anti-Ramsey number ar(G, Pk), where Pk is a path of length k. First, we observe that when k is... 

    Forecasting the effects of a Canada-US currency union on output and prices: A counterfactual analysis

    , Article Journal of Forecasting ; Volume 32, Issue 7 , 2013 , Pages 639-653 ; 02776693 (ISSN) Mahdi Barakchian, S ; Sharif University of Technology
    2013
    Abstract
    This paper is a counterfactual analysis investigating the consequences of the formation of a currency union for Canada and the USA: whether outputs increase and prices decrease if these countries form a currency union. We use a two-country cointegrated model to conduct the counterfactual analysis, where the conditional forecasts are generated based on the Gaussian assumption. To deal with structural breaks and model uncertainty, conditional forecasts are generated from different models/estimation windows and the model-averaging technique is used to combine the forecasts. We also examine the robustness of our results to parameter uncertainty using the wild bootstrap method. The results show... 

    Evaluation of Non-linear Combination Method (Neural Network) For Value-at-Risk Forecasting in Market

    , M.Sc. Thesis Sharif University of Technology Rashnavadi, Leila (Author) ; Barakchian, Mahdi (Supervisor)
    Abstract
    Value at risk of an asset, is the asset’s expected maximum loss for a certain period of time and at a specified confidence level. Value-at-Risk can be calculated in the bank with its inter-nal method or standardized method. when a method have more violation number then bank need to keep more daily capital requirements. under the Basel 2 agreement if the violation of method more than 10 times in year, the Bank uses the standardized method.
    There are trade off Between daily capital charge and violations. Therefore, existing methods for calculating the value at risk, usually lead to much daily capital charge or many violations. Studies show with combination of different methods to calculate...