Sharif Digital Repository

Nickel oxide (NiOx) is a promising hole transport material in inverted organic-inorganic metal halide perovskite solar cells. However, its low intrinsic conductivity hinders its further improvement in device performance. Here, we employ a trimercapto-s-triazine trisodium salt (TTTS) as a chelating agent of Ni2+ in the NiOx layer to improve its conductivity. Due to the electron-deficient triazine ring, the TTTS complexes with Ni2+ in NiOx via a strong Ni2+-N coordination bond and increases the ratio of Ni3+:Ni2+. The increased Ni3+ concentration adjusts the band structure of NiOx, thus enhancing hole density and mobility, eventually improving the intrinsic conductivity of NiOx. As a result,... 

Let G be a graph on n vertices with r := [n/2] and let γ 1 ≥ · · · ≥ γ n be adjacency eigenvalues of G. Then the Ḧuckel energy of G, HE(G), is defined as [Equation presented] The concept of Hückel energy was introduced by Coulson as it gives a good approximation for the π-electron energy of molecular graphs. We obtain two upper bounds and a lower bound for HE(G). When n is even, it is shown that equality holds in both upper bounds if and only if G is a strongly regular graph with parameters (n, k, γ, μ) = (4t2 + 4t + 2, 2t2 + 3t + 1, t2 + 2t, t2 + 2t + 1), for positive integer t. Furthermore, we will give an infinite family of these strongly regular graph whose construction was communicated... 

Zeolitic imidazole frameworks (ZIFs) provide an exciting platform to design and fabricate non-precious-metal carbon-based catalysts for oxygen reduction/evolution reaction (ORR/OER). Herein, we elaborately design a facile enzyme-assisted synthetic strategy that enables to tailor the ZIFs precursors into structural stable decussation shape, which derived Co nanoislands grafted on decussate N-doped carbon nanoleaves (D-Co@NC) can well retain the interpenetrating nanostructure. Benefiting from the combined advantages of compositions and interpenetrating nanostructures, D-Co@NC possesses 5.2 times higher exposed electrochemical active area than the conventional dodecahedral one, thus endowing... 

Hydroxyapatite (HA) coatings were deposited on commercially pure titanium plates using a hydrothermal-electrochemical deposition method in an electrolyte containing calcium and phosphate ions. The deposition conditions used in this study were the followings: electrolyte temperature (33-80 °C), current density (1-8 mA/cm2), and deposition time (10-120 min). Needle-like and granular crystals of apatite coating were created with different concentrations of calcium (0.0021-0.042 M) and phosphate (0.00125-0.025 M) salts. The size of HA crystals of the coating was considerably changed with different concentration of calcium and phosphate salts, temperature of the electrolyte, and deposition time.... 

Silica nanoparticles, which have a broad range of sizes and specific surface features, have been used in many industrial applications. This study was conducted to synthesize monodispersed silica nanoparticles directly from tetraethyl orthosilicate (TEOS) with an alkaline catalyst (NH3) based on the sol–gel process and the Stöber method. A central composite design (CCD) is used to build a second-order (quadratic) model for the response variables without requiring a complete threelevel factorial experiment. The process was then optimized to achieve the minimum particle size with the lowest concentration of TEOS. Dynamic light scattering and scanning electron microscopy were used to analyze the... 

Rapid assessment of structural safety and performance right after the occurrence of significant earthquake shaking is crucial for building owners and decision-makers to make informed risk management decisions. Hence, it is vital to develop online and pseudo-online health monitoring methods to quantify the health of the building right after significant earthquake shaking. Many Bayesian inference–based methods have been developed in the past which allow the users to estimate the unknown states and parameters. However, one of the most challenging part of the Bayesian inference–based methods is the determination of the parameter noise covariance matrix. It is especially difficult when the number... 

Online selection of the appropriate model and identifying its parameters based on measured vibrational data are among the challenging issues in dynamic system identification. After a severe earthquake, quick monitoring and assessment of structural health status play a crucial role in effective critical risk management for the building owners and decision-makers. The Bayesian multiple modeling approach is a suitable tool for optimal model class selection, which is used in this article mainly for improving data fitting precision, decreasing dimensions of structural unknown vector through removing unnecessary parameters, detecting the occurrence and type of predominant phenomenon related to... 

Online selection of the appropriate model and identifying its parameters based on measured vibrational data are among the challenging issues in dynamic system identification. After a severe earthquake, quick monitoring and assessment of structural health status play a crucial role in effective critical risk management for the building owners and decision-makers. The Bayesian multiple modeling approach is a suitable tool for optimal model class selection, which is used in this article mainly for improving data fitting precision, decreasing dimensions of structural unknown vector through removing unnecessary parameters, detecting the occurrence and type of predominant phenomenon related to... 

Rapid assessment of structural safety and performance right after the occurrence of significant earthquake shaking is crucial for building owners and decision-makers to make informed risk management decisions. Hence, it is vital to develop online and pseudo-online health monitoring methods to quantify the health of the building right after significant earthquake shaking. Many Bayesian inference–based methods have been developed in the past which allow the users to estimate the unknown states and parameters. However, one of the most challenging part of the Bayesian inference–based methods is the determination of the parameter noise covariance matrix. It is especially difficult when the number... 

Electrochemical co-deposition approach was expanded to prepare composite bio-ceramic coating of hydroxyapatite (HA)/polyvinyl acetate on the surface of titanium. The role is to improve the bioactive and crystallization properties. The results of XRD, XPS, SEM and TEM characterization showed that by increasing amount of vinyl acetate in the composite bio-ceramic coating before and after immersing in the simulated body fluid (SBF), an oriented growth of HA planes on the (0 0 2) direction had been observed on titanium substrate. Also significant surface morphology changes were obtained  

Dye-sensitized upconversion nanoparticles (UCNPs) have gained significant interest in biological applications. However, previous attempts to utilize these dye-sensitized UCNPs in the aqueous environment suffer from dramatic decline in the upconversion luminescence (UCL) intensity and problems with nanoparticles aggregation and water quenching. By employing indocyanine green (ICG) as a hydrophobic amplifier and energy harvester for UCNPs, we use a general, facile, and kinetically controlled mixing technology—flash nanoprecipitation (FNP)—to prepare aqueous stable ICG-sensitized UCNPs encapsulated by a biocompatible block copolymer poly (ethylene glycol)-b-poly (lactic-co-glycolic acid... 

Because of the compatibility with tandem devices and the ability to be manufactured at low temperatures, inverted perovskite solar cells have generated far-ranging interest for potential commercial applications. However, their efficiency remains inadequate owing to various traps in the perovskite film and the restricted hole blocking ability of the electron transport layer. Thus, in this work, a wide-bandgap n-type semiconductor, 4,6-bis(3,5-di(pyridin-4-yl)phenyl)-2-phenylpyrimidine (B4PyPPM), to modify a perovskite film via an anti-solvent method is introduced. The nitrogen sites of pyrimidine and pyridine rings in B4PyPPM exhibit strong interactions with the undercoordinated lead ions in... 

Traditional fluorescence switching molecules achieving the state change between on and off states commonly based on UV irradiation. However, it is worth noting that UV irradiation is harmful to both the cancer cells and the normal cells. To achieve fluorescence switching under visible wavelength and avoid complicate molecular design, a fluorophore of 2,4,5,6-tetrakis(carbazol-9-yl)-1,3-dicyanobenzene (4CzIPN) and a quencher of diarylethene (DAE) were physically incorporated within the biocompatible block copolymer poly(lactic-co-glycolic acid)-b-poly(ethylene glycol) (PLGA-b-PEG) to form 4CzIPN-DAE nanoparticles (NPs) through flash nanoprecipitation (FNP). By using the FNP method, the NPs... 

Pesticides are widely used to increase agricultural productivity, however, weak adhesion and deposition lead to low efficient utilization. Herein, we prepare a nanopesticide formulation (tebuconazole nanopesticides) which is leaf-adhesive, and water-dispersed via a rapid nanoparticle precipitation method, flash nanoprecipitation, using temperature-responsive copolymers poly-(2-(dimethylamino)ethylmethylacrylate)-b-poly(ε-caprolactone) as the carrier. Compared with commercial suspensions, the encapsulation by the polymer improves the deposition of TEB, and the contact angle on foliage is lowered by 40.0°. Due to the small size and strong van der Waals interactions, the anti-washing efficiency... 

The effect of moisture on Shengli lignite breakage behavior and energy efficiency was studied experimentally using a standard Hardgrove mill fitted with a wattmeter. The grinding process concerned both the inputs, namely the occurrence and content of water and instantaneous energy consumption and the outputs, size-reduction and product fineness. Results show that the energy-size reduction process for grinding lignite is markedly influenced by moisture occurrence and content. Removing surface moisture from 37.90% to 16.61% (the air-dried condition) resulted in a slight increase of input energy by 0.04 kWh.t−1 per 10 s. However, with further drying inherent moisture to 0%, the consumed energy... 

This paper reports on the NTIRE 2021 challenge on perceptual image quality assessment (IQA), held in conjunction with the New Trends in Image Restoration and Enhancement workshop (NTIRE) workshop at CVPR 2021. As a new type of image processing technology, perceptual image processing algorithms based on Generative Adversarial Networks (GAN) have produced images with more realistic textures. These output images have completely different characteristics from traditional distortions, thus pose a new challenge for IQA methods to evaluate their visual quality. In comparison with previous IQA challenges, the training and testing datasets in this challenge include the outputs of perceptual image... 

Sulfur-containing gaseous contaminant treatment is a key issue in the healthy and sustainable development of industry, especially SO2 and H2S occur with natural gas extraction and fossil fuel burning. Traditionally, the commercial method for H2S or SO2 requires numerous desiccants and enormous energy consumption. Encouragingly, electrochemical coupling system, which provide an efficient, sustainable, and economic pathway for sulfur-containing gaseous contaminants removal, can convert H2S and SO2 to recyclable substance in a moderate environment and simultaneously transfer the energy contained in them to other more valuable product. The current review discusses the mechanism and principle of... 

Previous research has reported a connection between urban green space and public health that ultimately contributes to happiness. Existing studies have mainly investigated green space over small areas. This paper revisits this significant correlation by examining the relationship between country-level happiness and the amount of urban green space as measured systematically from satellite images. Based on 2018 and 2013 data from 30 developed countries, we found that there is a correlation between urban green space and happiness, and this relationship becomes stronger among countries with higher GDP. We also found that the relationship between happiness and green space has grown stronger over... 

Over the last decades, several approaches have been proposed in the literature to incorporate users' perceptions of travel costs, their bounded rationality, and risk-taking behaviors into network equilibrium modeling for traffic assignment problem. While theoretically advanced, these models often suffer from high complexity and computational cost and often involve parameters that are difficult to estimate. This study proposes an alternative approach where users' imprecise perceptions of travel times are endogenously constructed as fuzzy sets based on the probability distributions of random link travel times. Two decision rules are proposed accordingly to account for users' heterogeneous... 

Considering the interaction of flexural moment and shear force in the steel frames with haunch or intermediate beam length and eccentrically braced frames with intermediate link length is a major concern of the structural analysis and design. This article contains two stages. In the first stage, to investigate the moment–shear interaction for the highly ductile steel I-sections, a study is carried out using finite element analysis and a simple and practical relationship is developed. In the second stage, a simple approach based on virtual work method for assemblage of interconnected rigid bodies is employed to consider collapse mechanisms with mixed hinges. Using this approach, the...