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    Preparation of Host-Guest Hydrogels Responsive to Environmental Stimuli based on Diazo Compounds for Drug Release

    , M.Sc. Thesis Sharif University of Technology Yousefi Adlsadabad, Samaneh (Author) ; Pourjavadi, Ali (Supervisor)
    Abstract
    Conventional chemotherapy methods impact both normal and cancerous cells; therefore, it is essential to design novel drug delivery systems in order to reduce drugs’ side effects. Having high retention time in blood and the capability of crossing blood-brain barriers are the characteristics of nano-scaled drug delivery systems.The research thesis is about the synthesis and characterization of the light-sensitive biocompatible nanogels with the core-shell structure with the intention of Doxorubicin anti-cancer drug delivery. These smart nanogels possess a hydrophobic core coated with hydrophilic starch polymeric chain modified with beta-cyclodextrin. The formation of the core-shell structure... 

    Improvement of nanosilica effects on the performance of mechanically processed styrene-butadiene rubber by rational hybridization with nanodiamond

    , Article Diamond and Related Materials ; Volume 130 , 2022 ; 09259635 (ISSN) Mohammadi, A ; Shojaei, A ; Khasraghi, Samaneh Salkhi ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    Hybrid nanoparticle comprising of nanosilica (NS) and nanodiamond (ND), denoted by ND@NS, was synthesized by a two-step chemistry route and then incorporated into styrene-butadiene rubber (SBR) at low concentrations up to 5 phr by a two-roll mill. Physical hybrids of NS and ND, i.e., ND&NS, with a weight ratio similar to chemical hybrid (80:20 for NS:ND), were also incorporated into SBR. Field emission scanning electron microscopy observations revealed very fine dispersion of nanoparticles in the case of physical hybrids (ND&NS). In contrast, agglomerations and aggregation of nanoparticles were evidenced for ND@NS. Tensile and dynamic mechanical analyses exhibited a higher reinforcing effect... 

    An Investigation on the Role of Silica Hybrid Nanoparticles on the Properties of Styrene Butadiene Rubber (SBR)

    , M.Sc. Thesis Sharif University of Technology Mohammadi, Ali (Author) ; Shojaei, Akbar (Supervisor) ; Salkhi Khasraghi, Samaneh (Co-Supervisor)
    Abstract
    Hybrid nanoparticle comprising of nanosilica (NS) and nanodiamond (ND), as denoted by ND@NS, was synthesized by a two-step chemistry route and then incorporated into styrene-butadiene rubber (SBR) at low concentrations up to 5 phr by a two-roll mill. Physical hybrids of NS and ND, i.e., ND&NS, with a weight ratio similar to chemical hybrid (80:20 for NS:ND), were also incorporated into SBR. Field emission scanning electron microscopy observations revealed very fine dispersion of nanoparticles in the case of physical hybrids (ND&NS); whereas, agglomerations and aggregation of nanoparticles were evidenced for ND@NS. Tensile and dynamic mechanical analyses exhibited a higher reinforcing effect... 

    Synthesis and Investigation of Properties of Biocompatible Polyurethane Acrylate Based Nanocomposites/Cellulose Nanocrystals

    , M.Sc. Thesis Sharif University of Technology Beik Mohammadi, Mahbubeh (Author) ; Shojaei, Akbar (Supervisor) ; Salkhi, Samaneh (Co-Supervisor)
    Abstract
    Bio-based shape memory polymers with fast-response have high potential for use in medical applications. In this study, biocompatible and biodegradable nanocomposites based on shape memory polyurethane acrylates (SMPUA)/cellulose nanocrystals (CNC), were synthesized by in-situ polymerization. CNC is a natural and renewable nanoparticle that has been considered for medical applications due to its excellent mechanical and biological properties and surface chemistry. At the first phase of this study, in order to synthesize UV-curable shape memory polyurethane acrylate, polycaprolactone diol (PCL-Diol), hexamethylene diisocyanate (HDI) and hydroxyethyl methacrylate (HEMA) were used as an reactive... 

    Synthesis and Evaluation of Poly(lactic Acid)/Polyurethane Nano-composites based on Cellulose Nano-particles, with Biomedical Applications

    , M.Sc. Thesis Sharif University of Technology Mohammadian Ahrabi, Taha (Author) ; Shojaei, Akbar (Supervisor) ; Salkhi Khasraghi, Samaneh (Co-Supervisor)
    Abstract
    Shape memory polymers have the potential to use in the field of biomedical applications. In this research, polyurethane structures have been synthesized based on the Diol mixtures, consisting of polycaprolactane diol (PCL-diol) and poly (lactic acid) diol (PLA-diol). Aim of reasearch is about evaluating poly (lactic acid) effect in structure of the polyurethane. At the same time, cellulose nanocrystals (CNC) have been added to polymer matrix to improve properties. The synthesis of acrylated polyurethane, included the synthesis of polyurethane acrylate prepolymer. Next, this prepolymer has been cured by adding the reactive diluent and some polyol. The cured systems were investigated, finally,... 

    Synthesis and Investigation of Metal–Organic Framework (MOF) on Properties of Biocompatible Polyurethane Acrylate

    , M.Sc. Thesis Sharif University of Technology Salavati, Ali (Author) ; Shojaei Segherlou, Akbar (Supervisor) ; Salkhi Khasraghi, Samaneh (Co-Supervisor)
    Abstract
    The objective of this research is to evaluate different morphologies of UiO-66 structures (pristine state and UiO-66 structure chemically supported on graphene oxide (UiO-66@GO)), on the rheology of polyurethane acrylate nanocomposites prior to UV-curing. The synthesized nanoparticles were characterized by FTIR, FESEM, TGA, XRD, and BET analysis. Rheological investigations, including large amplitude oscillatory sweep, small amplitude oscillatory sweep, steady shear flow, and thixotropic analysis were utilized. Moreover, the obtained rheological results were fitted using the Carreau–Yasuda model, the power-law model, and the Herschel–Bulkley model for quantitative interpretations. The results... 

    Investigation the Rule of Carbon-Based Quantum Dot on Biocompatible Polyurethane Acrylate

    , M.Sc. Thesis Sharif University of Technology Fahimifar, Hamid Reza (Author) ; Shojaei, Akbar (Supervisor) ; Salkhi Khasraghi, Samaneh (Supervisor)
    Abstract
    Biocompatible materials play a fundamental role in the advancement of medical science and provide groundbreaking solutions for tissue engineering and various therapeutic applications. Among these materials, polyurethane acrylate has attracted attention due to its biocompatibility, versatility, and suitability for creating complex medical scaffolds. This research investigates an innovative approach to reinforce polyurethane acrylate by incorporating graphene quantum dots, with the aim of developing advanced scaffolds for tissue engineering. The incorporation of graphene quantum dots is designed to take advantage of their exceptional properties to improve the mechanical strength, thermal... 

    Wide-band high-efficiency Ku-band power amplifier

    , Article IET Circuits, Devices and Systems ; Vol. 8, issue. 6 , December , 2014 , p. 583-592 ; 1751858X Yousefi, A ; Medi, A ; Sharif University of Technology
    2014
    Abstract
    A 37 dBm power amplifier (PA) is designed on a 0.25 μm optical T-gate pseudomorphic high electron mobility transistor (pHEMT) technology. The design of this two-stage PA along with a step-by-step design procedure is presented in this paper. This methodology can be used for design of PA in different technologies and frequencies. The PA delivers 5 W output power over the frequency band of 13-19 GHz. It shows average power-added efficiency of 37% and large signal gain of 15 dB in measurements which is consistent with simulation results. The output power and efficiency of the realised amplifier reach maximums of 37.6 dBm and 45%, respectively. Considering output power, bandwidth, chip area and... 

    Effects of free quartz on mechanical behaviour of kaolinite based geopolymers

    , Article Materials Technology ; Volume 26, Issue 2 , Jul , 2011 , Pages 96-99 ; 10667857 (ISSN) Yousefi, E ; Majidi, B ; Sharif University of Technology
    2011
    Abstract
    Quartz is usually detected as an impurity of kaolinite clays. The present work attempts to evaluate the role and behaviour of quartz particles in geopolymerisation and its probable effects on mechanical behaviour of geopolymeric products. Two kaolinite clays with different free quartz contents were used as raw materials to produce geopolymers. Results showed that using high content quartz kaolin causes higher compressive strength. Scanning electron microscopy studies confirmed that quartz does not participate in geopolymerisation and completely remains in the structure as fine particles. High hardness quartz particles by retarding crack growth in the geopolymer matrix enhance mechanical... 

    A Task-Based Greedy Scheduling Algorithm for Minimizing Energy of MapReduce Jobs

    , Article Journal of Grid Computing ; Volume 16, Issue 4 , 2018 , Pages 535-551 ; 15707873 (ISSN) Yousefi, M.H.N ; Goudarzi, M ; Sharif University of Technology
    Springer Netherlands  2018
    Abstract
    MapReduce and its open source implementation, Hadoop, have gained widespread adoption for parallel processing of big data jobs. Since the number of such big data jobs is also rapidly rising, reducing their energy consumption is increasingly more important to reduce environmental impact as well as operational costs. Prior work by Mashayekhy et al. (IEEE Trans. Parallel Distributed Syst. 26, 2720–2733, 2016), has tackled the problem of energy-aware scheduling of a single MapReduce job but we provide a far more efficient heuristic in this paper. We first model the problem as an Integer Linear Program to find the optimal solution using ILP solvers. Then we present a task-based greedy scheduling... 

    The double dividend of a joint tariff and VAT reform: Evidence from Iran

    , Article World Bank Economic Review ; Volume 37, Issue 2 , 2023 , Pages 331-349 ; 02586770 (ISSN) Yousefi, K ; Vesal, M ; Sharif University of Technology
    Oxford University Press  2023
    Abstract
    This paper provides empirical evidence on a novel complementarity between VAT and trade taxes. Downstream domestic firms require VAT receipts from importers to claim VAT on purchases, increasing incentives for honest reporting of imports. Trade gap, the difference between mirror and domestic trade reports in Iran at 6-digit HS disaggregation, is used to measure this complementarity. Iran introduced VAT in 2008 and, since then, has increased its rate from 3 to 9 percent. Difference-in-differences estimates show that a 1 percentage point increase in the VAT rate reduces the trade gap by about 2 percent. Consistent with the compliance mechanisms for VAT, a smaller effect for consumer products... 

    Design of Power Amplifier in Ku Band in the Process of GaAs-pHEMT

    , M.Sc. Thesis Sharif University of Technology Yousefi, Alireza (Author) ; Medi, Ali (Supervisor)
    Abstract
    Power amplifiers are used as the last block of transmitters. This block can be categorized as the one of most important part in communication systems. However, in transmitter systems which require high power to create stable link with the receivers, fabrication process like CMOS are unable to provide such level of power. Thus, designers employ another group of integrated circuits which names MMIC that offers this capability to designers. MMIC is the abbreviation of Microwave Integrated Circuit which is implemented in compound substrates like GaAs. Monolithic microwave integrated circuits enable the implementation of amplifiers in small size, large number, with high precision and appropriate... 

    Electrodepositon of Platinum Nanotubes

    , M.Sc. Thesis Sharif University of Technology Yousefi, Elahe (Author) ; Dolati, Abolghasem (Supervisor)
    Abstract
    Platinum nanotubes were deposited inside the pores of polycarbonate template with the pore size of 200 nm by electrochemical methods. In this regard a solution containing of 0.05 M H2PtCl6 and 0. 1 M H2SO4 in doubly distilled water was utilized. The electrodeposition process was studied by electrochemical techniques such as voltammetry and chronoamperometry methods. It was observed that the process was conducted in several stages including; nucleation and growth in steady state regime. Furthermore, it was concluded that electrodeposition was affected by mass transport restriction and was controlled by a diffusion process. In this regard, all the voltammograms were shifted to more negative... 

    A Comparison between Virtual Private LAN Service (VPLS)and P2MP IP-only LAN Service (IPLS)

    , M.Sc. Thesis Sharif University of Technology Yousefi, Dariush (Author) ; Ajorloo, Hossein (Supervisor)
    Abstract
    Today Ethernet is the predominant technology for implementing Local Area Networks. Its privileges encourage service providers to extend Ethernet from Local Area Networks to Metropolitan Area Networks or even Wide Area Networks. Ethernet benefits such as low operational costs, well interoperability, plug-n-paly characteristic and rapid provisioning on demand make Ethernet ideal for Metropolitan Area Networks.But Ethernet by itself has some weakness like flat structure that makes it unfit for use in Metropolitan Area Networks. A suitable solution for taking advantages of Ethernet benefits in service provider network is using Ethernet in access network and applying multi-point to multi-point... 

    A Framework for Formal Analysis of Warning Message Dissemination Schemes in VANETs Using an Extension of Rebeca

    , M.Sc. Thesis Sharif University of Technology Yousefi, Farnaz (Author) ; Movaghar, Ali (Supervisor)
    Abstract
    Vehicular ad-hoc networks have attracted the attention of many researchers during the last years due to the emergence of autonomous vehicles and the safety concerns regarding their use in near future. One of the major applications in this domain is the usage of vehicle to vehicle communication for warning message dissemination in dangerous situations to prevent more damage. A number of schemes have been proposed regarding the selection of forwarding nodes in this application and there is a need for developing frameworks for analysis and comparison of the schemes in fair situation. Most of the proposed frameworks make use of simulation techniques for the analysis of schemes. However, due to... 

    Optimization of the Pulp and Paper Mill Wastewater Treatment System from Recycling with the Aim of Reducing COD by Conducting a Laboratory Pilot Plant

    , M.Sc. Thesis Sharif University of Technology Yousefi, Farid (Author) ; Raie, Mohammad (Supervisor)
    Abstract
    Paper and cardboard waste pulping consume large volumes of water, so the discharge of this effluent without proper treatment can have far-reaching environmental consequences. The color and variable COD concentration of wastewater in this industry make treating this wastewater complicated. Therefore, this study aims to reduce the COD of the wastewater treatment plant of a pulp and paper mill under different laboratory conditions to achieve environmental standards in Iran.In this study, coagulation-flocculation and the Fenton process on the wastewater entering the treatment plant were investigated first. It was found that coagulation and flocculation by 750-1250 ppm of alum coagulant and ten... 

    Optimal Model of Industrial Waste Heat Application in Desalination System: A Case Study of Hormozgan Province

    , M.Sc. Thesis Sharif University of Technology Yousefi, Paria (Author) ; Avami, Akram (Supervisor)
    Abstract
    Increasing population growth and scarcity of fresh water resources have created the challenge of water supply, especially in the Mena region. Thus, many countries in the region have turned to innovation in the development of high-energy seawater desalination technologies. Utilizing the waste heat of refineries in the desalination industry can reduce costs and preserve the environment. In this article, effective ways to use the waste heat of other flue recovery steam of Bandar Abbas oil refinery are investigated. The integration of the heat recovery system consisting of recuperative heat exchangers and heat pipes with thermal desalination plants is investigated by multi-stage flash and... 

    investigation of the Effect of Piezo-Electric Patch on the Modal Properties and Flutter Speed of Turbomachine Blade

    , M.Sc. Thesis Sharif University of Technology Yousefi, Masoud (Author) ; Haddadpour, Hassan (Supervisor)
    Abstract
    In order to investigaton of dynamics behavior and determination of the aeroelastic stability of the turbomachine blade. the turbomachine blade is modeled by using the beam model, taking into account all degrees of freedom, the effect of warping, rotation and seting angle. For aerodynamic modeling, the Smith and Whitehead models are used which are valid in subsonic flow. The validity of the derived formulation is confirmed through comparison with those obtained from the finite element software and the available results in the literature. Then, by using the state feedback controller, the effect of sensor and piezoelectric actuator on the vibrations reduction of the structure and increasing the... 

    Efficient and practical protocol for silylation of hydroxyl groups using reusable lithium perchlorate dispread in silica gel under neutral condition [electronic resource]

    , Article Journal of Organometallic Chemistry ; 2006, Volume 691, Issue 5, Pages 817–820 Azizi, N. (Najmodin) ; Yousefi, R ; Saidi, M. R ; Sharif University of Technology
    Abstract
    A very efficient and mild procedure for the trimethylsilylation of a wide variety of alcohols, including primary, allylic, benzylic, secondary, hindered secondary, tertiary, and phenols with hexamethyldisilazane on the surface of silica gel dispersed with LiClO4 in room temperature at few minutes in excellent yields under neutral conditions is reported. This procedure also allows the excellent selectivity under LP-SiO2 system for silylation of alcohols in the presence of amine and phenolic hydroxy groups  

    Statistical analysis for enzymatic decolorization of acid orange 7 by Coprinus cinereus peroxidase

    , Article International Biodeterioration and Biodegradation ; Volume 64, Issue 3 , 2010 , Pages 245-252 ; 09648305 (ISSN) Yousefi, V ; Kariminia, H. R ; Sharif University of Technology
    2010
    Abstract
    Enzymatic decolorization of the monoazo dye, acid orange 7 (AO7) by the fungal peroxidase from Coprinus cinereus NBRC 30628 is a complex system, which is greatly affected by temperature, pH, enzyme activity and the concentrations of H2O2 and dye concentration. The study of these factors and investigating the combined interactions between them by applying one-factor-at-a-time (OFAT) method and two other statistical methods including 2-factorial method and response surface methodology (RSM) were aimed in this work. Through OFAT analysis the optimized conditions were a temperature of 25 °C, pH 9.0 with H2O2 concentration of about 3.9 mM and AO7 concentration of 40 mg/l. A complete...