Sharif Digital Repository

The recently reported UNIversal QUAsiChemical Segment Activity coefficient (UNIQUAC-SAC) model [developed by Haghtalab and Yousefi Seyf Ind. Eng. Chem. Res. 2015, 54, 8611] provides a practical thermodynamic framework to be used in VLE, LLE, and SLE calculations. The UNIQUAC-SAC model has the advantage of being independent of area (q) and volume (r) structural parameters used in the combinatorial part. While the UNIFAC or UNIFAC-DMD could not apply to the 47% (44 of 94) of the studied molecules because of the undefined groups. Here, the numbers of solvents with identified segment numbers were extended from 82 to 130 with a slight refinement to the previous values. The model parameters... 

The perturbed chain-statistical associating fluid theory equation of state (PC-SAFT EoS) is one of the state-of-the-art thermodynamic models used in the phase equilibrium calculation of associating mixtures, in particular, in the pharmaceutical industry. Accordingly, parametrization of the PC-SAFT EoS for approved solvents reviewed for use in pharmaceutical process design by the International Conference on Harmonization of Technical Requirements for Registration of Pharmaceuticals for Human Use (ICH) was done in the present study. First, the PeC-SAFT EoS model parameters for 41 pure solvents were regressed (of 62 solvents). The available high-quality binary vapor-liquid equilibrium (VLE)... 

The non-randomness two-liquid (NRTL) activity coefficient model and its variants are widely used in phase equilibria calculations. In the present study, the number of main groups of the NRTL-FAC (GC-NRTL) model (Fluid Phase Equilibria, 541:113088, 2021), was extended from 50 to 66 (including 125 subgroups). 160 molecules containing 3318 binary vapor–liquid-equilibrium (VLE) data sets (54,689 data points) were used in the extension of the model. That is, the main groups including DOH, ACRY, ClC = C, COO, ACCN, NCO, Anhydrides, ACCHO, ACCOOH, OCCOH, Lactames, Lactones, Peroxides, CF3H, CF3Cl, and CF4 were added to the main group list of the GC-NRTL model. In addition, the temperature... 

Numerical investigation on the application of nanofluids in Micro-Pin-Fin Heat Sinks (MPFHSs) has been presented in this paper. To investigate flow and heat transfer behavior in MPFHS the three-dimensional steady Navier-Stokes and energy equations were discretized using a finite volume approach and have been solved iteratively, using the SIMPLE algorithm. DI-water is used as a base coolant fluid while the nanoparticles used in the present study are CuO nanoparticles with mean diameters of 28.6 and 29 nm and Al 2O 3 nanoparticles with mean diameters of 38.4 and 47 nm. The results show that (i) a significant enhancement of heat transfer in the MPFHS due to suspension of CuO orAl 2O 3... 

In future smart grids, energy storage systems (EESs) are expected to play an indispensable role in balancing continuous load changes arising from customers' life-style as well as varying output of intermittent energy resources. This, however, needs significant investment that should be justified prior to their implementation. This paper presents a model to find the optimal capacity for ESSs in distribution systems. The model aims at maximizing system owner profit by reducing total electricity procurement costs. The model is formulated as a mixed integer non-linear programming problem. Due to the complexity and large size of the problem, a decouplebased method is proposed wherein optimal... 

In future smart grids, energy storage systems (EESs) and demand response (DR) are expected to have an important role in balancing load changes arising from life-style of consumers and varying output of some renewable energy resources. However, activating DR and installing ESSs need huge investment forcing system owner to justify their effectiveness prior to any implementation. This paper presents a model to find the optimal capacity of EESs in distribution systems with demand responding to electricity price changes. The model aims at maximizing system owner profit by lessening total electricity provision costs. The model is formulated as a mixed integer non-linear programming problem. Due to... 

Thermal conductivity, thermal dispersion, and structural effects in resin transfer molding (RTM) process are studied numerically. The injection part of the RTM process is modeled as a transport of resin flow through a fibrous porous medium in a long rectangular channel. The fluid flow is modeled using the Darcy-Brinkman-Forchheimer model and the heat transfer process using the energy equation based on local thermal equilibrium assumption. Both isotropic and anisotropic heat transfer in porous media are investigated. The governing equations are solved numerically for the isotropic heat transfer case and analytically for the anisotropic case. The numerical results are fitted to the available... 

Burr in drilling plays an important role on product quality, so analysis the burr height is essential at the final production. This paper presents the application of Taguchi method for survey the burr height by adding ultrasonic vibration to the process. In this paper L18 orthogonal array based on Taguchi techniques was used in the design of experiments. Analysis of Variance (ANOVA) was used to determination the effect of drilling parameter on burr formation. Influence of spindle speed, feed rate and percentage of SiC particle was investigated in with and without ultrasonic assisted drilling. In this paper drilling of Al/SiCp MMCs with 5, 15 and 20 wt% of particulate SiC in dry drilling... 

In this study two-dimensional finite element models of Al/SiC metal matrix composites (MMC) by using of ABAQUS Explicit software are investigated. Chip formations and machining forces for three types of MMC with 5, 15 and 20% of SiC reinforcement particles were studied and compared with experimental data. The resulted chips in simulation and the generated chips in experiments have both continuous and saw tooth in appearance. On the other hand, the variation of the cutting forces with the cutting time in simulation and experiment have fluctuating diagram. This is due to the interaction between cutting tool and SiC particles during chip formation. ABAQUS explicit software was used for... 

Deep excavation in urban areas can cause instability problems due to significant settlement at the ground surface and large movements at the excavation facing walls. One of the most popular methods used to stabilise these excavations is utilising soil-nailing method. This method has also been widely used to stabilise natural slopes and earth retaining structures. Because of the complexity involved in the mechanism of this stabilising system due to interacting effects of the soil, nails, grout and shotcrete, numerical modelling with high accuracy should be used to analyse the behaviour of the soil-nailed walls. Considering all aspects of soil-structure interaction in the present research, a... 

Deep excavation in urban areas can cause instability problems due to significant settlement at the ground surface and large movements at the excavation facing walls. One of the most popular methods used to stabilise these excavations is utilising soil-nailing method. This method has also been widely used to stabilise natural slopes and earth retaining structures. Because of the complexity involved in the mechanism of this stabilising system due to interacting effects of the soil, nails, grout and shotcrete, numerical modelling with high accuracy should be used to analyse the behaviour of the soil-nailed walls. Considering all aspects of soil-structure interaction in the present research, a... 

Deep excavation in urban areas can cause instability problems due to significant settlement at the ground surface and large movements at the excavation facing walls. One of the most popular methods used to stabilise these excavations is utilising soil-nailing method. This method has also been widely used to stabilise natural slopes and earth retaining structures. Because of the complexity involved in the mechanism of this stabilising system due to interacting effects of the soil, nails, grout and shotcrete, numerical modelling with high accuracy should be used to analyse the behaviour of the soil-nailed walls. Considering all aspects of soil-structure interaction in the present research, a... 

Herein, a novel Pt-APA composite (APA = pyridinium bromide salt) based on magnetic graphene oxide was synthesized and used as an effective catalyst. In this way, Fe3O4 nanoparticles are grown on graphene oxide (GO) nanosheets by a simple and practical method which creates a unique nanostructure (Fe3O4/GO) through dispersing uniformly among graphene nanosheets. The resulted Pt-APA composite was obtained via adding PtCl2 to an ethanol solution of Fe3O4/GO and α-keto stabilized pyridinium ylide in related conditions. The synthesized nanocomposite structure was identified using field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), energy dispersive... 

Metal matrix composites (MMCs) have received considerable attention due to their excellent engineering properties. However, poor machinability has been the main deterrent to their substitution for metal parts. The hardness and abrasive nature of reinforcement phase causes rapid tool wear during machining which results in high machining costs. In this study, the effect of SiC particles (5, 15 & 20 percent) on tool wear in turning process is experimentally investigated. Continuous dry turning of Al/SiC particulate metal matrix composite produced by powder metallurgy and utilizing titanium carbide inserts has been achieved as the test method. The influence of machining parameters, e.g. cutting... 

The problem of motion detection has received considerable attention due to the explosive growth of its applications in video analysis and surveillance systems. While the previous approaches can produce good results, the accurate detection of motion remains a challenging task due to the difficulties raised by illumination variations, occlusion, camouflage, sudden motions appearing in burst, dynamic texture, and environmental changes such as weather conditions, sunlight changes during a day, and so on. In this paper, a novel per-pixel motion descriptor is proposed for motion detection in video sequences which outperforms the current methods in the literature particularly in severe scenarios.... 

The main problem with airway segmentation methods which significantly influences their accuracy is leakage into the extra-luminal regions due to thinness of the airway wall during the process of segmentation. This phenomenon potentially makes large regions of lungparenchyma to be wrongly identified as airways. A solution to this problem in the previous methods was based on leak detection followed by reducing leakage during the segmentation process. This has been dealt with adjusting the segmentation parameters and performing the re-segmentation process on the pre-segmented area. This makes the algorithm very exhaustive and more dependent on the user interaction. The method presented here is... 

Preciseness and finished surface quality are the significant factors of final products, especially in a number of drilling processes. Burr is usually considered a negative outcome in assembly procedures. One way to reduce or remove burr and improve surface roughness in metal cutting is to employ ultrasonic vibration in the drilling process. In this paper, the effects of ultrasonic vibration on burr size reduction, drilling force and surface roughness with two different vibration systems are investigated. To this end, two vibration structures were built, one to excite the workpiece (the workpiece vibration system) and the other to vibrate the tool (the tool vibration system). Besides, the... 

Graphitic carbon nitride (g-C3N4) is promising as adsorbent for water remediation as its chemical structure allows a variety of mechanisms to interact with wastewater pollutants. However, several issues, such as low specific surface area and insufficient dispersibility in water, have to be tackled to achieve a competitive performance in such use. Previous attempts to improve the features of g-C3N4as an adsorbent have relied on carbon doping and exfoliation in the solid phase by thermal expansion. Here, we demonstrate that exfoliation in the liquid phase by a combination of oxidation and sonication allows preparing g–C3N4–based materials with improved dispersibility in water, increased...