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Numerical Investigating of the Methane Pyrolysis for Hydrogen Production Using Rotating Detonation Combustion Products
, M.Sc. Thesis Sharif University of Technology ; Farshchi, Mohammad (Supervisor) ; Salehi, Mohammad Mahdi (Supervisor)
Abstract
This study evaluates hydrogen production from methane cracking driven by the hot products of a rotating detonation combustor. A 2-D axisymmetric, steady, adiabatic Fluent model (ideal gas, no-slip; SST turbulence; species with GRI-3.0) used two inlets: H₂/air detonation products at 100 g/s and 2000 K, and methane at 7.342 g/s and 700 K with steam-to-methane = 3. In the base case, a central recirculation and a shear layer govern mixing and heat transfer: temperature peaks near the reactor inlet and then drops due to mixing and endothermic reactions. The outlet shows 1750 K mean temperature, hydrogen production of 1.4 g/s, and 1.3 g/s residual methane, indicating high conversion. Sensitivity...
Design and Implementation of a DC/AC Converter with High Step up and High Efficiency in Wide Output Power Range for Photovoltaic Applications
, M.Sc. Thesis Sharif University of Technology ; Zolghardi, Mohammad Reza (Supervisor)
Abstract
Solar power is expensive, so engineers are encouraged to put effort on increasing efficiency of solar power equipments. Since photovoltaic panels usually output a low voltage, variable direct current electricity, a boost converter and a suitable inverter are required to use this energy for ordinary commercial appliances. In this project, high step up, high efficiency converters are investigated, and the best converter with high efficiency and limited switch stress which achieves high voltage gain by capacitor multipliers and coupled inductors is illustrated. Afterwards, methods for improving efficiency such as modifying the converter structure and its control strategy are suggested. The...
An Improved I/O Scheduler for SSD-Based Redundant Array of Independent Disks
, M.Sc. Thesis Sharif University of Technology ; Asadi, Hossein (Supervisor)
Abstract
Solid-State Disks (SSDs) offer advantages such as no mechanical parts, low power consumption, and constant read latency. SSDs, however, suffer from shortcomings such as erase-before-update requirement and limited endurance.Redundant Array of Independent Disks (RAID) are commonly used in storage servers to enhance performance and reliability. To further enhance system performance, one can employ efficient Input/Output (I/O) scheduling algorithms suitedto the disk structure in RAID-based systems.In this thesis, we present an I/O scheduling method to improve endurance and performance of SSD-based RAID systems. In the proposed I/O scheduling algorithm, read requests are sent directly to SSDs and...
Urban Transportation Platform Startups and Labour Market in Iran
, M.Sc. Thesis Sharif University of Technology ; Keshavarz Haddad, Gholamreza (Supervisor)
Abstract
Urban mobility platforms introduced as an innovation in matching suppliers and demanders to each other in the transportation market in recent years. In this research, we applying synthetic control method to analyze the impact of this kind of platforms on labor market variables like work hours, income and number of employed persons in affected activity group. We use the ISIC correspondence tables for versions 3.1 and 4 and also Iran labor force survey and household survey to making activity control groups. The results show that work hours for main work in the related group were reduced. As well as the number of employees in the group increased 100 thousand people and the number of earners...
Design and thermodynamic analysis of a standing wave thermoacoustic superheater
, Article Applied Thermal Engineering ; Volume 249 , 2024 ; 13594311 (ISSN) ; Mazaheri, K ; Sharif University of Technology
2024
Abstract
The main objective here is to introduce and analyze a novel design to provide heat at higher temperatures, via a thermoacoustic super-heater, supplied by industrial wasted heat. The system includes two standing wave thermoacoustic engines with a symmetric configuration inside a resonator tube, with a constant linear temperature distribution (500–300 K) on stack plates. A high-temperature heat exchanger (HTHX) is placed in the middle of the resonator tube to extract heat at very high temperatures. This system is numerically simulated in which all non-linear terms are preserved. Two configurations were studied, the first includes an insulated HTHX which reached a high temperature of 800 K,...
Design and Construction of Large-scale Laminar Shear Box for Study of the Behavior of Deep Foundations Subjected to Lateral Loads due to Lateral Spreading using 1-g Shake Table Tests
, M.Sc. Thesis Sharif University of Technology ; Haeri, Mohsen (Supervisor)
Abstract
Using appropriate box as an artificial boundary condition is one of the critical tasks in geotechnical physical modeling of the soil mass especially under cyclic loading such as earthquakes. In general there are two types of boxes which can simulate boundary conditions of scaled models as rigid or flexible conditions. Main purpose of this study is design and construction of a flexible box in a way that effects of boundary condition have been minimized during tests. Construction of this box is the first step of an investigation project which concern to evaluate the effect of lateral spreading as a result of liquefaction on deep foundations of bridges, piers, harbors by using shake table test...
A 35 Step Reduced Mechanism for Methane-Air Combustion to Estimate Pollutants
, M.Sc. Thesis Sharif University of Technology ; Mazaheri, Karim (Supervisor)
Abstract
A novel reduced mechanism is introduced which aimed to predicts NOx and CO generation in advanced industrial gas turbine combustors. The survey is initially conducted by considering 25 species in GRI-3 mechanism of Methane oxidation and continued to choose nine of the most important species based on the quasi-steady state analysis. Finally, a new skeletal reduced mechanism with 35 reactions and 20 species is derived using sensitivity analysis, reaction path analysis, and some physical reasons. The overall validity of this mechanism is clearly confirmed by comparing the present predicted results with GRI-3 full mechanism in a PSR reactor. The adiabatic flame temperature and all of the main...
Numerical Analysis of Standing Wave Thermoacoustic Nonlinear Processes with Flow Field Investigation
, Ph.D. Dissertation Sharif University of Technology ; Mazaheri, Karim (Supervisor)
Abstract
This dissertation investigates and analyzes the nonlinear effects within standing wave thermoacoustic systems. These effects, often overlooked, can play a crucial role in the behavior of such systems. Two-dimensional numerical simulations of the Navier-Stokes equations were conducted using a commercial software, leading to the identification and discovery of new nonlinear physics governing the interaction of heat transfer and hydrodynamic oscillations of fluid particles. The numerical solution method and mesh quality were validated against a similar problem with a well-established numerical solution. Furthermore, a parametric study was performed on a stationary-wave thermoacoustic...
Modification of carbohydrate polymers via grafting in air. 1. Ceric-Induced synthesis of starch-g-polyacrylonitrile in presence and absence of oxygen [electronic resource]
, Article Starch - Starke ; Volume 54, Issue 3-4, pages 140–147, April 2002 ; Zohurian Mehr, Mohammad J
Abstract
Monomer grafting, a unique technique for polysaccharide modification, is always performed under inert (e.g., N2) atmosphere. This work is the first report related to evaluating the possibility and efficiency of the grafting of acrylonitrile (AN) onto starch in presence of oxygen. Thus, corn starch (in both granular and gelatinized states) as well as soluble starch were grafted by AN using a ceric-carbohydrate redox initiating system. Graft copolymerizations were performed under nitrogen, air, and oxygen atmospheres at similar conditions. Grafting occurrence was verified using chemical and spectral proofs. The polymerization mechanism and kinetics were investigated by recording the...
Modification of carbohydrate polymers via grafting in Air. 2. Ceric-Initiated graft copolymerization of acrylonitrile onto natural and modified polysaccharides [electronic resource]
, Article Starch - Stärke ; Volume 54, Issue 10, pages 482–488, October 2002 ; Zohuriaan-Mehr, Mohammad J
Abstract
Acrylonitrile (AN) was grafted onto various natural and modified polysaccharides (i.e., gum arabic, gum tragacanth, xanthan gum, sodium alginate, chitosan, sodium carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose) by using ceric-carbohydrate redox initiating system. After overcoming practical problems, mainly from the high viscosity of the aqueous solutions of the different substrates, the graft copolymerization reactions were run either in air or in N2 atmosphere under similar conditions. Grafting was confirmed using chemical and spectral (FTIR) proofs. The reactions were kinetically investigated using semi-empirical expressions and time-temperature profiles. An anomalous...
Current density in the intermediate state of superconductors
, Article Superconductor Science and Technology ; Volume 17, Issue 10 , 2004 , Pages 1189-1191 ; 09532048 (ISSN) ; Alizad, R ; Sharif University of Technology
2004
Abstract
In this investigation we have taken the viewpoint of the Landau theory for the normal state and have suggested a covariant equation for current density. This suggestion is based on the exact analysis of electrodynamic relations in the intermediate state of superconductors. Our analysis is restricted to the simplest electrodynamic relations. At first we have employed Maxwell's equations with the general Ohm-London equation and have found the general covariant current which takes a covariant form after Lorentz transformation. Finally we have checked it by considering two inertial frames in a simple state
The Political Economy Aspects of the Redistributive Role of Government in a General Equilibrium Micro-founded Macro Model
, M.Sc. Thesis Sharif University of Technology ; Nili, Masoud (Supervisor)
Abstract
The role of government in economy has been a controversial subject in economics. Lately, there has been some fundamental change in evaluating this subject. One could mention two of these as 1) realizing the importance of micro-founded macro model for evaluating policy, and 2) taking into consideration the rent-seeking behavior of politicians. In this research, a general equilibrium in a micro-founded macro model will be discussed and then in political economics framework, the effect of government on this equilibrium will be investigated. Only the redistribution role of government has been considered. First, the model in which a benevolent government is seeking optimal policy is Discussed....
Molecular Dynamics Simulation of Electroosmotic Flow in Nano scales
, M.Sc. Thesis Sharif University of Technology ; Darbandi, Masoud (Supervisor)
Abstract
Due to important applications and benefits of mass transfer in engineering and especially in nano-scales engineering, nano-science researchers have focused on this field. Considerably, in classical fluid dynamics applications, the fluid can be transported using differential pressure gradient. But the classical methods require moving components, which are usually expensive and not applicable in nano-sizes. To avoid these problems in nano-size transportation, we can use electro-osmotic process to perform mass transfer in low transfer rates. In electro-osmotic process, we can move electrolyte solvent with the aid of an external electrical field. Due to importance of this process in...
Modeling of in Plane Behavior of Retrofitted Adobe Walls with Finite Element Method under Cyclic Loading
, M.Sc. Thesis Sharif University of Technology ; Bakhshi, Ali (Supervisor) ; Ghannad, Mohammad Ali (Co-Advisor)
Abstract
Statistical studies indicate the fact that in Iran, like many other developing countries, a significant percentage of buildings are made of traditional materials and most of them are adobe buildings especially in rural areas. Furthermore, geological data indicates that Iran is located in alps-Himalayas seismic zone and exposed by destructive earthquakes and adobe buildings suffer the most damages comparing with other type of the structures. According to these explanations, this research deals with adobe buildings behavior and provides solutions for reinforcing them and improving the seismic response of these buildings. These studies include numerical modeling with finite elements methods by...
Silica chloride/wet SiO2 as a novel heterogeneous system for the deprotection of acetals under mild conditions [electronic resource]
, Article Phosphorus, Sulfur, and Silicon and the Related Elements ; Volume 178:2667-2670, Issue 12, 2003 ; Pourjavadi, Ali ; Zolfigol, Mohammad Ali ; Bamoniri, Abdolhamid
Abstract
A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition
A semiclassical approach for the phase matching effect in the nonlinear optical phenomena
, Article Journal of Optics A: Pure and Applied Optics ; Volume 10, Issue 12 , 2008 ; 14644258 (ISSN) ; Kaatuzian, H ; Amjadi, A ; Sharif University of Technology
2008
Abstract
In this paper we present a semiclassical model for explanation of the nonlinear optical effect and phase matching. We calculate momentary quantities of the delay time of photon-electron interaction in each layer. We show that for phase matching, the average delay time for the fundamental photons must be equal to the average delay time for the harmonic photons. Additionally, we calculate the number of layers that the harmonic photon needs to be absorbed or converted to fundamental photons. This calculation applies to different wavelengths with different phase matching angles. Our simulation results are in good agreement with experimental data. © 2008 IOP Publishing Ltd
Monte Carlo simulation of temperature-programmed desorption CO/Cu(110) and CO2/Cu(100) systems
, Article Surface Review and Letters ; Volume 11, Issue 2 , 2004 , Pages 137-143 ; 0218625X (ISSN) ; Dashti, A ; Sharif University of Technology
2004
Abstract
In this investigation, we have studied the kinetics and mechanism of desorption of CO from the Cu(110) surface using a new Monte Carlo simulation and putting emphasis on high order lateral interaction. According to our simulated TPD spectra, for β 0 = 10 K/s the maximum desorption rate occurs at Tm = 218.6 K. Furthermore, analysis of simulated TPD spectra of CO desorption shows that it is strongly lateral-interactive and results an activation energy of CO desorption from Cu(110) that is Ed = 66.6 Kj/mol. These simulated results are compared with other reported results and show excellent agreement. After that we have investigated the kinetics and mechanism of desorption of CO2 from the...
Distributed Fault-tolerant Computation for Massive Data
, M.Sc. Thesis Sharif University of Technology ; Maddah-Ali, Mohammad Ali (Supervisor)
Abstract
In this thesis we consider the problem of distributed computation by many processors.We mainly concentrate on matrix multiplication problem in this thesis because of its importance. A distributed system consists of N worker processors and one master processor. The master processor should distribute the computation between workers and after computation in each of them, collect the results. In this thesis, we are going to mitigate the effect of straggler processors by using coding methods. Straggler processors can cause delays in the computation time.In this thesis, we firstly introduce a method to multiply any number of matrices in each other. The proposed method occurred in one shot without...
Incomplete Reduction of Iron Ore in a Fluidized Bed Reactor
, M.Sc. Thesis Sharif University of Technology ; Halali, Mohammad (Supervisor)
Abstract
The main goal of current investigation was partial reduction of Fe2O3 available in Hematite-rich ore to Magnetite by Fludization Bed method. The reductive gas, CO, was produced by incomplete combustion of Acetylene and Airmixed in inappropriate ratio. X-Ray Diffraction and X-Ray Florescence analyses were implemented in order to conducting qualitative analysis of present phases before and after reduction of the ore. Quantitative analysis of the same phases was also conducted by Titration. The latter analysis revealed the precise magnitude of available iron in each of the oxide containing phases. The chemical composition of the reactor gas was also determined before and after reduction...
Sequential Competitive Facility Location In Continuous Geometric Space
, M.Sc. Thesis Sharif University of Technology ; Abam, Mohammad Ali (Supervisor)
Abstract
Abstract The problem of competetive facility location can be defined as follows: There are a number of customers in the form of points in space, and two players arrange a number of facilities in the form of points in space, given some limitations, respectively. Each customer’s connection to each facility has a cost for the customer and an advantage for the facility, and each customer wants to be connected to at most one of the facilities which has the lowest cost for him. The goal is to find the strategy of placing the facilities and determining the cost which the facility receives from the customer, in such a way that the player’s profit is maximised.In this thesis, we first sought to...