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    Experimental Investigation for Enhancing the Lifetime of Co,Ru/La(γ-Al2O3) Catalyst in Fischer Tropsch Synthesis

    , Ph.D. Dissertation Sharif University of Technology Hemmati Mahmoudi, Mohammad Reza (Author) ; Kazemeini, Mohammad (Supervisor) ; Khorasheh, Farhad (Supervisor) ; Zarkesh, Jamshid (Co-Advisor)
    Abstract
    Fischer-Tropsch synthesis (FTS) is the main part of a Gas to Liquid (GTL) process. In this reaction which shall be done based upon iron or cobalt catalysts, H2 and CO molecules (namely Syngas) transform to long hydrocarbon chains. Regarding all of the advantages of cobalt catalysts in comparison with iron counterparts, Research Institute of Petroleum Industry (RIPI) began investigations since two decade ago. The present catalyst comprised of cobalt as active metal, ruthenium as activity promiter and lanthanum as support (gamma alumina) modifier. By the way, still some areas such as its lifetime duration and deactivation needs to be improved by complimentary researches. The present... 

    Failure Modes Analysis and Mechanisms for Life Extension of Gas Turbines

    , M.Sc. Thesis Sharif University of Technology Jamshid Doost, Asghar (Author) ;
    Abstract
    Currently, the relatively long time of the turbine life passes and their parts and equipment damage are different, that loss optimum performance and thus reducing their efficiency and may lead to faults and other unexpected stops in their production cycle. Process used to estimate the remaining life of the various components of this turbine is an important tool for improving the efficiency of these units to perform preventive maintenance. In the present thesis, the types of damages in different parts of gas turbines and various methods for detection of critical points, particularly finite element method, high cycle fatigue, modal analysis, methods to estimate the lifetime of a gas turbine... 

    Experimental Investigation of Mud-Induced Formation Damage in Fractured Reservoirs

    , M.Sc. Thesis Sharif University of Technology Bagheri, Abdolhossein (Author) ; Rashtchian, Davood (Supervisor) ; Moghadasi, Jamshid (Supervisor)
    Abstract
    Productivity reduction of oil and gas wells due to mud induced permeability impairment is one of challenging problems in drilling and production studies. This phenomenon is of prime importance in fractured reservoirs in which high permeability fracture networks act as conduits for feeding gas or oil from a tight matrix to the wellbore. Up to now, many experimental and modeling investigations have been done in formation damage in conventional reservoirs. But in spite of large contribution of fractured reservoirs in total hydrocarbon reserves, there is very little work reported in the literature investigating formation damage in such reservoirs. In this thesis, the effective parameters in... 

    Comparison of Rheological Properties of Slurry with International Standards to Evaluate the Successfulness of Gachsaran Oil Field Cementation and Proposing Experimental Solutions

    , M.Sc. Thesis Sharif University of Technology Abbasi, Ali (Author) ; Ghotbi, Sirous (Supervisor) ; Moghadasi, Jamshid (Supervisor)
    Abstract
    The rheology of oil well cement (OWC) slurries is generally more complicated than that of conventional cement paste. In order to contend with bottom hole conditions, a number of additives are usually used in the OWC slurries. The objective of this research is to develop a fundamental understanding of the important mechanisms that affect the properties of OWC slurry such as rheological properties, free water, compressive strength and thickening time incorporating various chemical and mineral admixtures. The partial replacement of OWC using different nanoparticle weight percent has been proved to be a promising method. The mechanisms underlying the effects of chemical admixtures on the... 

    Effect of lanthanum doping on the lifetime of Co/γ-Al 2O 3 catalysts in Fischer-Tropsch synthesis

    , Article Journal of the Taiwan Institute of Chemical Engineers ; Volume 43, Issue 5 , September , 2012 , Pages 704-710 ; 18761070 (ISSN) Hemmati, M. R ; Kazemeini, M ; Zarkesh, J ; Khorasheh, F ; Sharif University of Technology
    Elsevier  2012
    Abstract
    Cobalt-based catalysts were prepared on gamma alumina supports, and their behaviour for different Fischer-Tropsch synthesis (FTS) conditions was assessed. Although Co/γ-Al 2O 3 is a well-known FTS catalyst, its durability ought to be improved to make the industrial process economically feasible. The effect of lanthanum doping on the catalyst lifetime was examined utilising reactor tests and catalyst characterization techniques including TPR, ICP and N 2 porosimetry. Reactor test results revealed that an optimum amount of lanthanum improved catalyst activity and selectivity. Increasing amounts of lanthanum doping up to about 1.1wt% seemed to modify the chemical composition of the support... 

    Investigating the effect of calcination repetitions on the lifetime of Co/γ-Al2O3 catalysts in Fischer-Tropsch synthesis utilising the precursor's solution affinities

    , Article Journal of the Taiwan Institute of Chemical Engineers ; Volume 44, Issue 2 , 2013 , Pages 205-213 ; 18761070 (ISSN) Hemmati, M. R ; Kazemeini, M ; Khorasheh, F ; Zarkesh, J ; Sharif University of Technology
    2013
    Abstract
    Cobalt-based catalysts were prepared on different alumina supports, and their behaviour for different Fischer-Tropsch synthesis (FTS) conditions assessed. Although Co/γ-Al2O3 is a well-known FTS catalyst, its durability ought to be improved to make the industrial process economically feasible. Here calcination repetitions effects on the catalyst lifetime were examined utilising reactor tests and characterisation techniques including XRD, TPR, ICP and N2 porosimetry. Results revealed that fewer calcination repetitions improved catalyst activity and selectivity. Based upon the XRD results, these findings appeared to be due to the improved size of cobalt crystals on the pore surfaces. These... 

    Thermal and catalytic hydrocracking of Iranian Paraffin: A unique lumped kinetic model

    , Article Scientia Iranica ; Volume 6, Issue 5 , 2000 , Pages 92-97 ; 10263098 (ISSN) Zarkesh, J ; Akbarnejad, M. M ; Badakhshan, A ; Khorasheh, F ; Sharif University of Technology
    Sharif University of Technology  2000
    Abstract
    In this paper, thermal and catalytic hydrocracking of liquid paraffin hydrocarbons, from Tehran refinery, is studied using a pilot plant reactor. The experimental system consisted of a vertical tubular flow reactor where hydrogen and liquid products were fed from the top of the reactor and after passing through a bed of catalyst (or quartz beads in the case of thermal hydrocracking experiments), the liquid and gaseous products were separated and sampled for subsequent analyses. The reaction temperature was in the range of 410-430°C for catalytic hydrocracking and 440-470°C for thermal hydrocracking experiments. The space velocities for both sets of experiments varied between 0.5 to 1.5... 

    Preparation and Characterization of Chitosan-Gelatin/Polyanilne-Graphene-CNT Nanocomposite for Neural Tissue Engineering

    , M.Sc. Thesis Sharif University of Technology Aein Jamshid, Mohammad (Author) ; Ramazani Saadatabadi, Ahmad (Supervisor)
    Abstract
    Repairing and regeneration of neural tissues have attracted considerable attention due to its direct effect on the quality of patients’ lives. Recent developments in nanotechnology and tissue engineering have facilitated their comprehensive applications in the treatment of neurological diseases, and several effective ways have been proposed to repair defects in neural tissues. The main objective of the researches in this field is to regulate cellular behavior and tissue progression through the design and development of synthetic extracellular matrices, such as novel biomaterials, that enhance cell culture and tissue regeneration. Natural polymers, such as chitosan and gelatin, are suitable... 

    Improving Security and Integrity of Healthcare Data Using Blockchain

    , M.Sc. Thesis Sharif University of Technology Akbari Zarkesh, Mahdi (Author) ; Movaghar Rahimabadi, Ali (Supervisor)
    Abstract
    The rapid adoption of the Internet of Things (IoT) has led to significant advancements in healthcare digitization and modernization. However, given the sensitive nature of medical data, security and privacy of such data have always posed major challenges. Moreover, resource constraints of IoT devices have necessitated the use of cloud resources for handling massive amounts of data in traditional approaches, introducing issues like single points of failure, processing delays, and security vulnerabilities. In this context, blockchain technology shows promise for enhancing security, decentralization, and returning data ownership. A robust solution should maintain confidentiality, enable access... 

    EdgeLinker: practical blockchain-based framework for healthcare fog applications to enhance security in Edge-IoT data communications

    , Article 2024 5th CPSSI International Symposium on Cyber-Physical Systems (Applications and Theory), CPSAT 2024 ; 2024 ; 979-833152928-4 (ISBN) Zarkesh, M. A ; Dastani, E ; Safaei, B ; Movaghar, A ; Sharif University of Technology
    IEEE  2024
    Abstract
    The pervasive adoption of Internet of Things (IoT) has significantly advanced healthcare digitization and modernization. Nevertheless, the sensitive nature of medical data presents security and privacy challenges. On the other hand, resource constraints of IoT devices often necessitates cloud services for data handling, introducing single points of failure, processing delays, and security vulnerabilities. Meanwhile, the blockchain technology offers potential solutions for enhancing security, decentralization, and data ownership. An ideal solution should ensure confidentiality, access control, and data integrity while being scalable, cost-effective, and integrable with the existing systems.... 

    Calcination effects on texture and porosimetric properties of regular and nano-structured alumina utilized as catalyst support for the FT Synthesis

    , Article Advanced Materials Research ; Volume 468-471 , 2012 , Pages 87-92 ; 10226680 (ISSN) Mahmoudi, M. R. H ; Kazemeini, M ; Zarkesh, J ; Khorasheh, F ; Sharif University of Technology
    2012
    Abstract
    Samples of regular gamma and nano-structured alumina were prepared and their porosimetric properties evaluated by N 2 porosimetry method. Moreover, cobalt based catalysts for Fischer-Tropsch (FT) Synthesis were prepared by loading cobalt under two calcinations using these alumina supports. Then the porosimetric properties of these materials as well as; their reactor behaviors assessed. Although the nano-structured favored the gamma alumina from pore volume and surface points of view, comparison of porosimetric properties of fresh alumina samples with corresponding catalysts prepared revealed that calcination effect in decreasing those factors was more pronounced for the nano-structured... 

    Experimental Investigation of Factors Affecting Formation Damage through Aqueous Phase Trapping in Gas Reservoirs

    , M.Sc. Thesis Sharif University of Technology Mirzaei Paiaman, Abouzar (Author) ; Masihi, Mohsen (Supervisor) ; Moghadasi, Jamshid (Supervisor)
    Abstract
    Aqueous phase trapping (APT) in many of the oil and gas reservoirs is a significant mechanism of formation damage during drilling, completion, work over, and stimulation operation. APT can limit the productivity of the well to a high extent, especially in low permeable gas reservoirs. Experimental investigation of factors affecting APT is vital to recognize extends of associated damage and contribution of each factor. Albeit many experimental studies have been conducted as regards factors affecting removal of phase traps in understudy mechanism of formation damage, but up to date no experimental data has been published regarding effect of different factors on reservoir’s potential for APT.... 

    CFD Simulation of Slurry Bubble Column for Heavy Crude Oil Hydrocracking

    , M.Sc. Thesis Sharif University of Technology Azimi Yancheshme, Amir (Author) ; Rashtchian, Davood (Supervisor) ; Zarkesh, Jamshidi (Supervisor)
    Abstract
    In this project, for hydrodynamic simulation of RIPI experimental bubble column with concerning chemical reaction, first only hydrodynamic simulation and then hydrodynamic with reaction was done. For complete knowledge about bubble columns hydrodynamic, all common flow regimes were studied. First of all a rectangular semi-batch bubble column with bubbly flow regime and gas flow of 0.26 m3/h was simulated with commercial CFD software, FLUENT v. 14.5. Euler-Euler approach in 2D and 3D was used and because of bubbly flow regime a mean constant diameter was assumed for dispersed gas phase. Effect of interfacial forces (e. g drag, lift and virtual mass) was studied and compared with experimental... 

    Cobalt supported on CNTs-covered γ- and nano-structured alumina catalysts utilized for wax selective Fischer-Tropsch synthesis

    , Article Journal of Natural Gas Chemistry ; Volume 21, Issue 6 , 2012 , Pages 713-721 ; 10039953 (ISSN) Hemmati, M. R ; Kazemeini, M ; Khorasheh, F ; Zarkesh, J ; Rashidi, A ; Sharif University of Technology
    2012
    Abstract
    Cobalt supported on carbon nanotubes (CNTs)-covered alumina has been recently developed and successfully utilized as a catalyst in Fischer-Tropsch synthesis (FTS). Problems associated with shaping of Co/CNTs into extrudates or pellets as well as catalyst attrition rendered these materials unfavorable for industrial applications. In this investigation regular γ- and nano-structured (N-S) alumina as well as CNTs-covered regular γ- and N-S-alumina supports were impregnated by cobalt nitrate solution to make new cobalt-based catalysts which were also promoted by Ru. The catalysts were characterized and tested in a micro reactor to evaluate their applicability in FTS. γ-Al2O3 was prepared by... 

    Energy-aware workflow scheduling in fog computing using a hybrid chaotic algorithm

    , Article Journal of Supercomputing ; Volume 79, Issue 16 , 2023 , Pages 18569-18604 ; 09208542 (ISSN) Mohammadzadeh, A ; Akbari Zarkesh, M ; Haji Shahmohamd, P ; Akhavan, J ; Chhabra, A ; Sharif University of Technology
    Springer  2023
    Abstract
    Fog computing paradigm attempts to provide diverse processing at the edge of IoT networks. Energy usage being one of the important elements that may have a direct influence on the performance of fog environment. Effective scheduling systems, in which activities are mapped on the greatest feasible resources to meet various competing priorities, can reduce energy use. Consequently, a hybrid discrete optimization method called HDSOS-GOA, which uses the Dynamic voltage and frequency scaling (DVFS) approach, is proposed to handle scientific workflow scheduling challenges in the fog computing environment. HDSOS-GOA combines the search qualities of Symbiotic Organisms Search (SOS) and the... 

    Deep Compositional Captioner

    , M.Sc. Thesis Sharif University of Technology Jahangiri, Saman (Author) ; Esfahani Zadeh, Mostafa (Supervisor) ; Kamali Tabrizi, Mostafa (Co-Supervisor) ; Moghadasi, Jamshid (Co-Supervisor)
    Abstract
    One of the most important applications of artificial intelligence, and especially deep learning is image captioning. Given an image, the task is to automatically produce a sentence, describing the image. Image captioning has several real world applications like helping the blind understanding the images, generating automatic captions for the social media, etc. In the past, several different methods for image captioning have been used, but after the emergence of deep learning, like many other areas, image captioning algorithms have been improved significantly. In this thesis, I talk about a specific method for image captioning, called ”Deep Compositional Captioning. In this method, at first... 

    Experimental Investigation for FINDING a Suitable Additive (Nanoparticle) to Design Required Elastic Cement for Iranian Oil/Gas Wells

    , M.Sc. Thesis Sharif University of Technology Khojastefar, Abdorahim (Author) ; Taghikhani, Vahid (Supervisor) ; Soltanian, Hamid (Supervisor) ; Moghadasi, Jamshid (Supervisor) ; Samsam Sokheiravi, Mohammad (Co-Advisor)
    Abstract
    Previous studies indicate that increasing cement compressive strength can’t prevent loss of zonal isolation and casing collapse in worse case during well operations or formation loading. Since standard cements with high compressive strength can’t solve these problems, so application of elastic cements with low Young’s modulus and high Poisson’s ratio becomes important. These cements sustain generated stresses during well operations and prevent creation of point loads when formation creep occurs. For this purpose, a new additive was designed in order to improve the cement elasticity and tensile strength. It is a nanoparticle and named EX-RIPI (by Research Institute of Petroleum Industry,...