Sharif Digital Repository

A novel efficient and cost-effective heterogeneous catalyst for the production of biodiesel from transesterification of sunflower oil was prepared through the impregnation of K2CO3 upon the Talc material. The physicochemical features of the catalyst were studied through several characterization analyses. The effect of the K2CO3 loading was investigated by comparing the catalytic activity of various prepared catalysts. Moreover, the effect of the calcination temperature upon the catalytic activity was examined. To maximize the yield of the produced biodiesel fuel, reaction variables such as the reaction time and temperature, catalyst concentration, and methanol: oil molar ratio were... 

Kaolin clay material was loaded with potassium carbonate by impregnation method as a novel, effective, and economically heterogeneous catalyst for biodiesel production of sunflower oil via the transesterification reaction. The structural and chemical properties of the produced catalysts were characterized through several analyses including the X-ray diffraction, scanning electron microscopy, Fourier-transform infrared spectroscopy, and Brunauer–Emmett–Teller specific surface area. These revealed the best catalyst for the investigated reaction among different ones prepared based upon various impregnation extent of the potassium carbonate. The influence of this parameter was examined through a... 

In this contribution, spinel MgAl2O4 nanospheres prepared by the combustion method were coupled with thermally-exfoliated g-C3N4 nanosheets (TE-GCN) through an efficient isoelectric point-assisted calcination technique. Physical characteristics of the synthesized nanocomposite were understudied utilizing the XRD, FT-IR, FE-SEM, TEM, BET-BJH, UV–Vis DRS, PL, and EIS analyses. This material was used as a novel nano-photocatalyst for degradation of reactive red 195 (RR195) industrial dye contaminant. Results revealed that, a successful synthesis of a heterojunction between the components of the nanocomposite was achieved. This exhibited an enormously improved electron-hole separation leading to... 

Aromatic and cyclic organic compounds such as nitrobenzene (NB) are widely used in various industries and are present in their wastewater. In addition, the photocatalytic process has received considerable attention due to its lower chemical consumption and more efficient degradation of refractory pollutants. In this study, a CoFe2O4-ZnO (CFZ) composite was prepared and evaluated its efficiency in the degradation of NB from aqueous solution under UV light. The optical, structural, and physicochemical properties of catalysts were characterized using PL, UV–vis DRS, XRD, TEM, FESEM-EDS, and VSM techniques and then discussed in detail. It was found that not only does the use of CF facilitate the... 

Polymer-layered silicate nanocomposites have been observed to demonstrate enhanced mechanical properties particularly at low weight fractions of silicate. Experimental and theoretical investigations reveal that numerous structural parameters strongly influence the modulus of such nanocomposites. A multiscale micromechanical model is developed which considers a wide range of different affecting parameters including the particle aspect ratio, the number of silicate layers per stack, the d-spacing ratio between the layers, the penetration of polymer chains along silicate sheets, the intercalation feature, and the particle volume fraction. The developed model illustrates the accuracy and... 

The NP-hard single machine sequence-dependent group scheduling problem with minimization of total weighted earliness and tardiness is investigated. An arc-time-indexed formulation is presented and a Lagrangian-based branch-and-bound algorithm is proposed. The Lagrangian relaxation of the arc-time-indexed formulation is solved as a shortest path problem. The results of an extensive computational study demonstrate the efficacy of the proposed algorithm and establish characteristics of some hard to solve instances  

The NP-hard single machine sequence-dependent group scheduling problem with minimization of total weighted earliness and tardiness is investigated. An arc-time-indexed formulation is presented and a Lagrangian-based branch-and-bound algorithm is proposed. The Lagrangian relaxation of the arc-time-indexed formulation is solved as a shortest path problem. The results of an extensive computational study demonstrate the efficacy of the proposed algorithm and establish characteristics of some hard to solve instances  

The strengthening behavior of particle reinforced metal-matrix composites is primarily attributed to the dislocation strengthening effect and the load transfer effect. To account for these two effects in a unified way, a new multi-scale approach is developed in this paper incorporating the aspect ratio effect into the geometrically necessary dislocation strengthening relationships. By making use of this multi-scale approach, the deformation behavior of metal-matrix composites (MMCs) and metal-matrix nanocomposites (MMNCs) as a function of size, volume fraction, aspect ratio, etc. of the particles has been investigated. Comparison with the previously proposed models and the available... 

The flowshop sequence dependent group scheduling problem with minimization of makespan as the objective (F m |fmls, S plk, prmu|C max ) is considered in this paper. It is assumed that several groups with different number of jobs are assigned to a flow shop cell that has m machines. The goal is to find the best sequence of processing the jobs in each group and the groups themselves with minimization of makespan as the objective. A mathematical model for the research problem is developed in this paper. As the research problem is shown to be NP-hard, a hybrid ant colony optimization (HACO) algorithm is developed to solve the problem. A lower bounding technique based on relaxing a few... 

Over the past decades, Redundant Array of Independent Disks (RAIDs) have been configured based on mechanical characteristics of Hard Disk Drives (HDDs). With the advent of Solid-State Drives (SSDs), configurations such as stripe unit size can be far from the characteristics of SSDs. In this paper, we investigate the effect of stripe unit size on the endurance and the overall I/O performance of an SSD-based RAID array and compare the optimal stripe unit size with the suggested stripe unit sizes for HDD-based RAID. To this end, we first examine the number of extra page reads and writes imposed by write requests, and then observe the corresponding impact on the overall throughput and the... 

We have developed a mathematical programming model for minimizing total flow time of the flow shop sequence dependent group scheduling (FSDGS) problem, typically classified as Fm|fmls, Splk, prmu|∑Cj. As the problem is shown to be strongly NP-hard, a tabu search (TS) algorithm as well as a hybrid ant colony optimization (HACO) algorithm have been developed to heuristically solve the problem. A lower bounding (LB) method based on the Branch-and-Price algorithm is also developed to evaluate the quality of the metaheuristic algorithms. In order to compare the performance of metaheuristic algorithms, random test problems, ranging in size from small, medium, to large are created and solved by... 

The performance of cellular solids in biomedical applications relies strongly on a detailed understanding of the effects of pore topology on mechanical properties. This study aims at characterizing the failure mechanism of scaffolds based on nodal connectivity (number of struts that meet in joints) and geometry of the pores. Plastic models of scaffolds having the same relative density but different cubic and trigonal unit cells were designed and then fabricated via three dimensional (3-D) printing. Unit cells were repeated in different arrangements in 3-D space. An in-situ imaging technique was utilized to study the progressive deformation of the scaffold models. Different nodal... 

Rapid prototyping is a promising technique for producing tissue engineering scaffolds due to its capacity to generate predetermined forms and structures featuring distinct pore architectures. The objective of this study is to investigate the influences of different pore geometries and their orientation with respect to the compressive loading direction on mechanical responses of scaffolds. Plastic models of scaffolds with cubic and hexagonal unit cells were fabricated by three-dimensional (3-D) printing. An in situ imaging technique was utilized to study the progressive compressive deformation of the scaffold models. In both cubic and hexagonal geometries, organized buckling patterns relevant... 

Acyclic phase-type distributions form a versatile model, serving as approximations to many probability distributions in various circumstances. They exhibit special properties and characteristics that usually make their applications attractive. Compared to acyclic continuous phase-type (ACPH) distributions, acyclic discrete phase-type (ADPH) distributions and their subclasses (ADPH family) have received less attention in the literature. In this paper, we present the definition, properties, characteristics and PH representations of ADPH distributions and their subclasses with finite state space. Based on the definitions of geometric and shifted geometric distributions, we propose a distinct... 

Discrete Phase-Type (DPH) distributions have one property that is not shared by Continuous Phase-Type (CPH) distributions, i.e., representing a deterministic value as a DPH random variable. This property distinguishes the application of DPH in stochastic modeling of real-life problems, such as stochastic scheduling, in which service time random variables should be compared with a deadline that is usually a constant value. In this paper, we consider a restricted class of DPH distributions, called Mixed Shifted Negative Binomial (MSNB), and show its flexibility in producing a wide range of variances as well as its adequacy in fitting fat-tailed distributions. These properties render MSNB... 

Discrete Phase-Type (DPH) distributions have one property that is not shared by Continuous Phase-Type (CPH) distributions, i.e., representing a deterministic value as a DPH random variable. This property distinguishes the application of DPH in stochastic modeling of real-life problems, such as stochastic scheduling, in which service time random variables should be compared with a deadline that is usually a constant value. In this paper, we consider a restricted class of DPH distributions, called Mixed Shifted Negative Binomial (MSNB), and show its flexibility in producing a wide range of variances as well as its adequacy in fitting fat-tailed distributions. These properties render MSNB...