Sharif Digital Repository

The corrosion inhibition of glycine-based dithiocarbamates with benzyl (BDTC) and propyl (PDTC) groups were investigated for cold rolled carbon steel (CRS) in 0.5 M HCl, indicating that the compounds as mixed type inhibitors significantly reduced the corrosion rate of the CRS due to the formation of a stable protective film on the metal surface. As confirmed by ATR-FTIR, SEM, AFM, XPS and theoretical studies, chemically adsorbed BDTC molecule is a better corrosion inhibitor with higher corrosion efficiency of about 98% at room temperature and a better thermal stability attributed to the Fe-S and Fe-N bindings, and in addition, to the presence of the benzene ring in the molecular structure. ©... 

A high-power short-pulse generator based on the dual action of two coupled diodes, a high-voltage step recovery diode and a high-current diode, is presented. This is made possible using a gas discharge tube. Both analysis and SPICE simulation show about 20-dB peak power increment. This gives a high output power level of 5.7 MW with 1-ns pulsewidth and 450-kHz repetition rate obtained from an input average power of 7.1 kW. An efficiency of about 73% is obtained with more than 30 dB increase in the average power delivered to a 50-Ω load  

In this paper, a novel method for high-repetition-rate high-power radio frequency (RF) pulse generation, which involves only passive solid-state devices and is capable of being used for generating high power microwaves using a low-to-high power converting scheme based on nonlinear self-compression is proposed. The method is also expected to be of low jitter. In the proposed circuit, two high voltage diodes with proper reverse recovery characteristics are used. The simulation results show that the proposed circuit generates RF pulses, with central frequencies up to gigahertz range. By applying a sub-kilowatt power supply, the maximum output power was well over 10 kW. This power can be... 

The nonlinearity of a nonlinear transmission line (NLTL) may have a variety of forms. The Korteweg-de Vries (KdV) equation is the governing equation of a highly specific category of NLTLs having a C - V characteristic as C(V) = C0 (1-bV), but works as an approximate model in a general NLTL having any other kinds of nonlinearities. Here, the soliton response of a varactor-loaded NLTL is studied analytically. The presented analysis gives the exact nonlinear partial differential equation (PDE) governing these networks. It is shown that the obtained PDE, being different from the KdV equation, has soliton solutions showing the well-known properties of the KdV solitons. These obtained solitons... 

The input current of a nonlinear transmission line (NLTL), driven by a step voltage pulse, was analyzed theoretically. As specific results of the analysis, two basic parameters of NLTLs were formulated for the first time: the energy injected to NLTLs and their characteristic impedance. The energy delivered to an NLTL by a square voltage source, with a series resistance of RS, is given by a closed-form formula, which depends on the NLTL parameters and the input pulse characteristics. Considering the importance of the problem of the determining the injected energy content in a wide variety of the different applications of NLTLs, the obtained result will be of great importance, facilitating the... 

Aims: Our goal was the characterization of a new moderate thermophilic polycyclic aromatic hydrocarbon (PAH)-utilizing Nocardia strain. Methods and Results: A thermophilic bacterium, strain TSH1, was isolated from a contaminated soil. The macroscopic and microscopic features fit well with the description of Nocardia species. The results of 16S rRNA gene analysis showed 100% match to the type strain of N. otitidiscaviarum DSM 43242T. Strain TSH1 showed the same mycolic acid pattern as the type strain of N. otitidiscaviarum but its fatty acid profile did not permit identification to the species level. The carbon utilization profile of strain TSH1 was different from N. otitidiscaviarum. The... 

The thermophilic bacterium Nocardia otitidiscaviarum strain TSH1, originally isolated in our laboratory from a petroindustrial wastewater contaminated soil in Iran, grows at 50 °C on a broad range of hydrocarbons. Transformation of naphthalene by strain TSH1 which is able to use this two ring-polycyclic aromatic hydrocarbon (PAH) as a sole source of carbon and energy was investigated. The metabolic pathway was elucidated by identifying metabolites, biotransformation studies and monitoring enzyme activities in cell-free extracts. The identification of metabolites suggests that strain TSH1 initiates its attack on naphthalene by dioxygenation at its C-1 and C-2 positions to give... 

Aims: The metabolism of phenanthrene and anthracene by a moderate thermophilic Nocardia otitidiscaviarum strain TSH1 was examined. Methods and Results: When strain TSH1 was grown in the presence of anthracene, four metabolites were identified as 1,2-dihydroxy-1,2-dihydroanthracene, 3-(2-carboxyvinyl)naphthalene-2-carboxylic acid, 2,3-dihydroxynaphthalene and benzoic acid using gas chromatography-mass spectrometry (GC-MS), reverse phase-high performance liquid chromatography (RP-HPLC) and thin-layer chromatography (TLC). Degradation studies with phenanthrene revealed 2,2′-diphenic acid, phthalic acid, 4-hydroxyphenylacetic acid, o-hydroxyphenylacetic acid, benzoic acid, a phenanthrene... 

Nonlinear transmission lines (NLTLs) are passive networks with the capability of modulating baseband pulses. These networks are used for generating RF pulses at high-power levels. NLTLs have a unique performance in high-power RF pulse generation among all the generators based on the solid-state technology. A high-power rectangular pulse is injected to the line, gradually evolved into an oscillatory pulse while propagating through the network, and finally, in the form of a high-power RF pulse, is delivered to the load. Properly terminating an NLTL, in order to transfer the maximum available RF power to the load, is an important problem. In this paper, an accurate analysis is presented, which... 

Nonlinear transmission lines (NLTLs) are one of the most prominent solid-state sources of high-power RF pulses. However, there is no integrated mathematical basis, which predicts adequately the generated waveforms on an NLTL and those delivered to the load. This analysis is required for designing and optimizing these transmission lines. Most works in this area are related to experimental studies and results. In this paper, we have developed a theoretical basis, which predicts all the required characteristics of the generated RF pulses on a lossy NLTL. The RF amplitude, the maximum voltage, and the central frequency of the generated pulses at each node of an NLTL are formulated. All the... 

Drift step recovery diodes (DSRDs) have a special place in high-power short-pulse generation. In this paper, a cascaded configuration of two DSRD-based high-power short-pulse generators with gas discharge switches was used. The high-power pulses generated in the first stage feed the second stage in order to generate shorter pulses with higher peak powers. A prototype was implemented based on this idea. In the first stage, 1.2-kV pulses were generated from a 50-V power supply. At the output of the second stage, 2.1-kV pulses with a repetition rate of more than 50 Hz were obtained. The output peak voltage was limited by the breakdown voltage of the used DSRD. Repetitive pulses with 4-ns rise... 

Line generators were attractive structures for high-power radio frequency (RF) pulse generation for two decades. Due to some disadvantages, there has been little attention to this type of generator for a relatively long time. In this paper, a nonuniform line generator is used which resolves some of the main shortcomings of conventional line generators. The considered generator can generate RF pulses at higher frequencies with considerably higher repetition rates. Furthermore, the implementation of nonuniform line generators is significantly easier than that of their conventional counterparts. Measurement results for three nonuniform line generators are presented. The possibility of... 

A high-power short-pulse generator based on the diode step recovery phenomenon and high repetition rate discharges in a two-electrode gas discharge tube is presented. The proposed circuit is simple and low cost and driven by a low-power source. A full analysis of this generator is presented which, considering the nonlinear behavior of the gas tube, predicts the waveform of the output pulse. The proposed method has been shown to work properly by implementation of a kW-range prototype. Experimental measurements of the output pulse characteristics showed a rise time of 3.5 ns, with pulse repetition rate of 2.3 kHz for a 47-Ω load. The input peak power was 2.4 W, which translated to about... 

Electrostatic fiber fabrication technique has evinced more interest and attention in recent years, owing to its versatility, reliability, and potential for applications in diverse fields, particularly separation, extraction, and filtration. The sub-micro fibers are generated by employing strong electric field on polymeric solutions or melt is led to the soft nanometric mats. So far, more than 100 polymers have been Electrospun and this number is gradually increasing. Over recent decades, a remarkable variety of electrospun nanofibers as promising and authentic extracting platforms have been synthesized. They offer various advantages including high surface area-to-volume ratio and tunable... 

Electrostatic fiber fabrication technique has evinced more interest and attention in recent years, owing to its versatility, reliability, and potential for applications in diverse fields, particularly separation, extraction, and filtration. The sub-micro fibers are generated by employing strong electric field on polymeric solutions or melt is led to the soft nanometric mats. So far, more than 100 polymers have been Electrospun and this number is gradually increasing. Over recent decades, a remarkable variety of electrospun nanofibers as promising and authentic extracting platforms have been synthesized. They offer various advantages including high surface area-to-volume ratio and tunable... 

In some well-known passive localization methods, when the number of equations equals the number of unknown object coordinates, there arise finite number of possible solutions. A localization disambiguation technique is required to identify the correct solution in these cases. As an example, the exact solution of time-difference-of-arrival (TDOA) based equations for four receiver sites, leads to a couple of solutions with only one of them being the true target position. This ambiguity, conventionally is resolved by using angle-of-arrival (AOA) measurements or using an additional receiver site which increase the cost and complexity of the system. In this paper a localization disambiguation... 

Passive localisation of non-cooperative targets through their electromagnetic emissions is an attractive issue. This localisation task can be carried out using multitude of receiver sites being linked together. This multiplicity, however, brings about difficulties in organising and coordinating the sites. One can even claim that the method is no longer passive considering the necessary communication links between the sites. On the other hand, single-site localisation methods basically overcome these difficulties eliminating the need for inter-site communications. In this study, a single-site localisation method is presented and analysed. This method is applicable to scenarios with a large... 

In some well-known passive localization methods, when the number of equations equals the number of unknown object coordinates, there arise finite number of possible solutions. A localization disambiguation technique is required to identify the correct solution in these cases. As an example, the exact solution of time-difference-of-arrival (TDOA) based equations for four receiver sites, leads to a couple of solutions with only one of them being the true target position. This ambiguity conventionally is resolved by using angle-of-arrival measurements or using an additional receiver site, which increase the cost and complexity of the system. In this paper, a localization disambiguation... 

Carbon nanotubes are among promising components for a wide range of applications, due to their unique properties; Specifically, They are a new alternative and efficient tool for transporting and translocating therapeutic molecules since they can translocate easily into the cytoplasm or nucleus of a cell through its membrane without generating an immunogenic response and toxic effects. While pristine carbon nanotubes are insoluble in all solvents, the organic functionalisation of carbon nanotubes is the prerequisite for their solubility profiles and their manipulation into biological systems. For this purpose, in this study, we first report the Amide-functionalization of CNTs which a direct... 

Indigenous thermophilic hydrocarbon degraders are of special significance for the bioremediation of oil-contaminated desert soils with ambient temperature of 45-50°C. The first objective of this study was to demonstrate the hydrocarbon-degrading capability of Nocardia otitidiscaviarum TSH1 (DSM 45036) which grows optimally at 50°C. Analysis of the metabolic profile of the strain TSH1 showed that it could metabolize phenol, intermediate-chain-length n-alkanes and some polycyclic aromatic hydrocarbons (PAHs) ranging in size from two to four fused rings efficiently, but not toluene and xylene. N. otitidiscaviarum TSH1 was able to survive and grow at phenol concentrations up to 875 mg l-1. For...