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    Modified CMC: part 1- optimized synthesis of carboxymethylcellulose-g-polyacrylonitrile [electronic resource]

    , Article Iranian Polymer Journal ; Vol. 14, No 2, 131-138, 2005 Zohurian Mehr, M. J. (Mohammad Jalal) ; Pourjavadi, A ; Sadeghi, M
    Abstract
    As the first part of a continued research on conversion of carboxymethyl cellulosesodium salt (CMC) to useful biopolymer-based materials, large numbers of cyanide functional groups were introduced onto CMC by grafting with polyacrylonitrile (PAN). The graft copolymerization reactions were carried out under nitrogen atmosphere using ceric ammonium nitrate (CAN) as an initiator. Evidence of grafting was obtained by comparing FTIR spectra of CMC and the graft copolymer as well as solubility characteristics of the products. The synthetic conditions were systematically optimized through studying the effective factors including temperature and concentrations of initiator, acrylonitrile monomer,... 

    Modification of carbohydrate polymers via grafting in air. 1. Ceric-Induced synthesis of starch-g-polyacrylonitrile in presence and absence of oxygen [electronic resource]

    , Article Starch - Starke ; Volume 54, Issue 3-4, pages 140–147, April 2002 Pourjavadi, A. (Ali) ; Zohurian Mehr, Mohammad J
    Abstract
    Monomer grafting, a unique technique for polysaccharide modification, is always performed under inert (e.g., N2) atmosphere. This work is the first report related to evaluating the possibility and efficiency of the grafting of acrylonitrile (AN) onto starch in presence of oxygen. Thus, corn starch (in both granular and gelatinized states) as well as soluble starch were grafted by AN using a ceric-carbohydrate redox initiating system. Graft copolymerizations were performed under nitrogen, air, and oxygen atmospheres at similar conditions. Grafting occurrence was verified using chemical and spectral proofs. The polymerization mechanism and kinetics were investigated by recording the... 

    New polysaccharide-g-polyacrylonitrile copolymers: synthesis and thermal characterization [electronic resource]

    , Article Polymers for Advanced Technologies ; Volume 14, Issue 7, pages 508–516, July 2003 Zohurian Mehr, M. J. (Mohammad Jalal) ; Pourjavadi, Ali ; Sharif University of Technology
    Abstract
    Various natural and modified polysaccharides (i.e. arabic gum, tragacanth gum, xanthan gum, sodium alginate, chitosan, sodium carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose) were modified using ceric-initiated graft polymerization of acrylonitrile under inert atmosphere. Grafting was confirmed using spectral (FT-IR) proofs. The grafting parameters were determined by conventional methods. Thermal characteristics of the homopolymer-free copolymers were studied using differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) under nitrogen atmosphere. The major thermal transitions as well as the activation energy of the major decomposition stages were... 

    Oil-soluble drag-reducing polymers [electronic resource]

    , Article Journal of polymer materials ; December 1994, Volume 11, Number 4; Page(s) 239 To 247 Zohurian Mehr, M. J. (Mohammad Jalal) ; Pourjavadi, A ; Nadali, M ; Sharif University of Technology
    Abstract
    This article reviews the oil-soluble polymeric drag-reducing agents (DRAs) with an outlook to their large-scale application in petroleum industry. A general discussion on mechanism of the DR phenomenon and mechanical degradation of the drag reducers in turbulent flow is offered with an emphasis on the molecular parameters. Furthermore, low charge density associating polymers, as a new class of oil-soluble flow improvers, are described  

    , M.Sc. Thesis Sharif University of Technology Kheirabadi, Malihe (Author) ; Pourjavadi, Ali (Supervisor) ; Zohurian Mehr, Mohammad Jalal (Supervisor)
    Abstract
    Polyampholyte hydrogels are hydrophilic networks that contain both positively- and negatively-charged functional groups on their structure. Polysulfobetaines are the most important type of polyampholytes, which have been extensively studied. However, these hydrogels exhibited poor gel strength causing limitation of their applications. Consequently, much attention has been focused on the preparation of nanocomposite hydrogels with high gel strength and lower cost using organomodified clays. In this project, Novel polyampholytic superabsorbing nanocomposites based on the zwitterionic sulfobetaine monomer [3-(methacrylamido)propyl)]dimethyl(3-sulfopropyl) ammonium hydroxide (MPDSAH) were... 

    Modified CMC.2. Novel carboxymethylcellulose-based poly (amidoxime) chelating resin with high metal sorbtion capacities [electronic resource]

    , Article Reactive and Functional Polymers ; Volume 61, Issue 1, August 2004, Pages 23–31 Zohurian Mehr, M. J. (Mohammad Jalal) ; Pourjavadi, A ; Sadeghi, M ; Sharif University of Technology
    Abstract
    Carboxymethylcellulose sodium salt (CMC) was doubly modified to prepare a novel poly(acrylamidoxime) chelating resin. Acrylonitrile was firstly graft polymerized onto CMC using cerium ammonium nitrate as an initiator. The polyacrylonitrile (PAN) grafted CMC was then amidoximized via treatment with hydroxylamine to prepare the ion exchange resin. The sorption capacity of the resin towards bivalent metal ions was evaluated while varying the pH, the loading of the PAN and the initial metal ion concentration. The adsorption kinetics were investigated for the cupric ion. The chelating resin exhibited very high metal sorption capacity in comparison with either synthetic or polysaccharide-based... 

    Modification of carbohydrate polymers via grafting in Air. 2. Ceric-Initiated graft copolymerization of acrylonitrile onto natural and modified polysaccharides [electronic resource]

    , Article Starch - Stärke ; Volume 54, Issue 10, pages 482–488, October 2002 Pourjavad, A. (Ali) ; Zohuriaan-Mehr, Mohammad J
    Abstract
    Acrylonitrile (AN) was grafted onto various natural and modified polysaccharides (i.e., gum arabic, gum tragacanth, xanthan gum, sodium alginate, chitosan, sodium carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose) by using ceric-carbohydrate redox initiating system. After overcoming practical problems, mainly from the high viscosity of the aqueous solutions of the different substrates, the graft copolymerization reactions were run either in air or in N2 atmosphere under similar conditions. Grafting was confirmed using chemical and spectral (FTIR) proofs. The reactions were kinetically investigated using semi-empirical expressions and time-temperature profiles. An anomalous... 

    Temporal Congestion Games

    , M.Sc. Thesis Sharif University of Technology Mehr, Mehran (Author) ; Ghodsi, Mohammad (Supervisor)
    Abstract
    We consider a special class of Congestion Games enhanced with a notion of time.Network Routing problems, such as road traffic networks, computer neworks, and evacuation problems are some applications of this class of games. Two subclasses of these games, namely atomic and non-atomic is considered in this article, both of them introduced in 2009. Some of the existing results are Nash equilibria existence proof for “single-source single-sink” case, and a mechanism for improving price of anarchy in the non-atomic subclass. There are also some results in the atomic subclass of this game.We extend both models of atomic and non-atomic subclasses to “multi-source,multi-sink” configurations. We call... 

    Geochemical Simulation of Acidizing Sandstone Core Samples

    , M.Sc. Thesis Sharif University of Technology Khojasteh Mehr, Mohammad (Author) ; Bazargan, Mohammad (Supervisor)
    Abstract
    Acidizing is one of the widely used practices of formation damage remediation. The success of this rather expensive job depends on the precise design and operation. Though, improper execution of an acid job, not only does not improve the formation damage but also can contribute to even more damage itself. For this purpose, it is critically important to thoroughly design an acidizing job conducting extensive lab experiments and utilizing numerical tools before operation in order for a successful acidizing. Unlike, carbonate acidizing, the chemistry of sandstone acidizing is very complex and challenging because of the wide variety of minerals and aqueous species present in the system. Hence, a... 

    Effective Action of Non-Local Nambu-Jona-Lasinio Model in a Constant Magnetic Field

    , M.Sc. Thesis Sharif University of Technology Tabatabaee Mehr, Mohammad Ali (Author) ; Sadooghi, Neda (Supervisor)
    Abstract
    In the framework of the Standard Model of Particle Physics, Quantum Chromodynamics (QCD) is known to be the only theory which describes the strong nuclear force. Because of the property of asymptotic freedom, perturbative methods fail to describe QCD at low energies. Here, mesons and baryons build the main degrees of freedom of QCD. To describe the dynamics of mesons at low energies, nonperturbative methods are used. The Nambu–Jona-Lasinio (NJL) model is one of the most important effective models, which is used to study the nonperturbative phenomena of QCD at low energies. The Lagrangian density of this model includes a local four-fermion term,which descibes the interaction between the... 

    The Effect of Magnetization on the Evolution of the Plasma of Quarks and Gluons

    , Ph.D. Dissertation Sharif University of Technology Tabatabaee Mehr, Mohammad Ali (Author) ; Sadooghi, Neda (Supervisor)
    Abstract
    Quantum Chromodynamics (QCD) is the theory of strong interaction. Two main properties of QCD in low energies are chiral symmetry breaking and confinement. At finite temperature, QCD exhibits a certain transition from a chirally broken phase to a chirally restored phase and liberation of color charge. Lattice QCD at finite temperature shows a crossover transition at vanishing or small chemical potential while the model-dependent studies, e.g. the Nambu-Jona--Lasinio model predicts a first-order phase transition at large chemical potentials. The first order and crossover transition lead to the existence of a critical point in the phase diagram of QCD. Determining the nature of the phase... 

    A new homologous series of linear aliphatic unsaturated hydroxypolyesters a polyol soft segments for polyurethanes: Synthesis and characterization [electronic resource]

    , Article Journal of Applied Polymer Science ; Volume 68, Issue 2, pages 173–183, 11 April 1998 Pourdjavadi, A. (Ali) ; Rezai, Nasrin ; Zohurian, M. J ; Sharif University of Technology
    Abstract
    Synthesis and characterization of a new series of low molecular weight (MW = 500–3000) OH-terminated linear aliphatic unsaturated polyesters based on cis-2-butene-1,4-diol and oxalic to sebacic acid were investigated. Direct polycondensation and transesterification methods were used for the syntheses. The latter was recognized to be the preferable method due to its lower reaction temperature and time, lower diol/diacid ratio, absence of decarboxylation, and formation of a product with low polydispersity (Mw/Mn = 1.3–2.7). Elemental analysis, GPC, FTIR, 1H-NMR, DSC, and WAXD were used for the investigations. A segmented polyurethane based on poly (cis-2-butylene adipate) glycol was also... 

    Optimum Camera Position for UAV Vertical Plane Maneuvers

    , M.Sc. Thesis Sharif University of Technology Zarei Jalal Abadi, Mahboube (Author) ; Malaek, Mohammad Bagher (Supervisor)
    Abstract
    This work presents the methodology to investigate Optimum Camera Installation Angle (OCIA)while employing the so called?Vision Based Navigation (VBN)? in urban areas.The approach is suitable for future general aviation aircraft as envisioned in Small Air Transportation System (SATS) as well as Unmanned Aerial Vehicles (UAV).Due to practical constraints, the work is limited to the maneuvers in the vertical plane while conducting Simultaneous Localization and Mapping (SLAM) technique.This technique was originated in robotics and is commonly used to guide both ground based and low speed aerial robots in unknown environments involving different types of obstacles. A variety of camera... 

    Production of Lactic Acid from Glycerol in Microchannel Reactors in the Presence of Copper-Based Catalysts

    , M.Sc. Thesis Sharif University of Technology Jalal Sahandi, Pooya (Author) ; Kazemeini, Mohammad (Supervisor) ; Sadjadi, Samaheh (Supervisor)
    Abstract
    Hand in hand with the flourish of the biodiesel industries, glycerol has turned into an abundant waste chemical posing obstacles to their large-scale implementation. Devising measures for efficient transformation of glycerol into value added products is a promising alternative to its large-scale disposal into the nature that would also increase the competitiveness of biodiesel fuels. In this study, production of lactic acid (LA) as a valuable chemical with wide applicability is studied in a continuous process with glycerol as a cheap and convenient feedstock. In this regard, the state-of-the-art approaches in catalytic conversion of glycerol to LA are reviewed. A catalytic method using... 

    Novel azo-containing polymethacrylates bearing spiroacetal-norbornene moiety and methylene spacers: synthesis and characterization [electronic resource]

    , Article European Polymer Journal ; Volume 37, Issue 10, October 2001, Pages 2111–2121 Pourdjavadi, A. (Ali) ; Mirjalili, Bibi Fatemeh ; Entezami, Ali A ; Zohuriaan-Mehr, Mohammad J ; Sharif University of Technology
    Abstract
    An eight-step synthetic strategy was followed to prepare a series of novel azobenzene-containing methacrylate monomers bearing spiroacetal-norbornene moiety and methylene spacers. Thus, the adduct 2, obtained from cyclopentadiene and acrolein, was converted to 1,3-diol 3. The diol was acetalized with nitrobenzaldehyde 4 under microwave irradiation to obtain nitro compound 5 that was then reduced to amino compound 6. Diazonium salt of 6 was coupled with phenol to produce phenolic compound 7 which was then reacted with n-dibromoalkanes (n=2, 4, 6, 8, 10) to yield bromo compounds 9a–e. Nucleophilic substitution reaction of the bromo compounds with lithium methacrylate produced the methacrylic... 

    Modeling the Solar Heat Pump with an Energy Storage System

    , M.Sc. Thesis Sharif University of Technology Abbasi Godarzi, Ali (Author) ; Samimi , Jalal (Supervisor) ; Vesaghi, Mohammad Ali (Supervisor)
    Abstract
    Purpose of ongoing thesis is providing a tool for suitable modeling, increase efficiency and decrease construction cost of solar absorption heat pump. At first, the solar absorption heat pump is modeled by the thermodynamic laws. Then, this model is converted to the new standard mathematical programming model using exergy and thermodynamic Analysis with considering all technical and economic constrains. This mathematical model is optimized by Genetic algorithm (GA). Because of the nonlinear objective function and the constraint, GA is used as optimization algorithm. After applying GA, optimized parameters of cycle heat exchanger designing and its electricity consumption are calculated.... 

    Study on Very High Energy Cosmic Ray at Tehran Surface

    , Ph.D. Dissertation Sharif University of Technology Sheidaei, Farzaneh (Author) ; Samimi, Jalal (Supervisor)
    Abstract
    The cosmic ray astronomy was born in 1937 when Victor Hess flied with his balloon to the height of 17,500 feet. He found that the cosmic rays come from out of atmosphere. There are three fundamental questions from that time. The goal of all cosmic ray's experimental activities and related theories is finding out the answer of these questions. The first question is about the energy and composition spectrum of cosmic rays. The second one is finding the sources which can product the very high energy particles such as the protons with the energy of 1021eV found in some observatory such as AGASA and Haverah Park. The last question is the process of diffusion of cosmic rays in the galaxy. One of... 

    Designing a Model-Based Process and Architecture for Partial Automation of Software Development

    , M.Sc. Thesis Sharif University of Technology Jalal, Ali (Author) ; Habibi, Jafar (Supervisor)
    Abstract
    Automation of the software development process is the software engineers' final goal, but with the current facilities and knowledge in software engineering, it is not possible to automatically generate the whole software. Usually all the software in a specific domain contain common behaviors, which by careful exploration of these common behaviors and automation of code generation in these sections, the cost and time of projects' execution can be reduced. According to Model Driven Development (MDD), the first step in software development is creating appropriate models. For creating models, metamodel is required; therefore, we need to create a specific motamodel for the chosen domain or use... 

    Travel Mode Choice with High Occupancy Toll Lane

    , M.Sc. Thesis Sharif University of Technology Sadeghi, Hassan (Author) ; Samimi, Jalal (Supervisor)
    Abstract
    With the growth of the urban population and the increase in private car ownership, negative implications of transportation, such as traffic congestion and environmental pollution has increased. A good solution to this problem is development of traffic infrastructures. However, it is not sufficient by itself and better management strategies for solving these problems are needed. One of the related approaches, is high occupancy toll lane. The main purpose of this study is modeling user’s mode choice behavior in the presence of high occupancy toll lane and pricing some highway lanes in Tehran. Another important purpose of this study is to find affective factors that have an influence on users... 

    Experimental Analysis and Simulation of Pollution Distribution in Ground Water and Soil

    , M.Sc. Thesis Sharif University of Technology Ziyari, Afshin (Author) ; Shayegan, Jalal (Supervisor)
    Abstract
    Underground water is one of major resources of drinking water in Iran and thus, its quality (in terms of absence of pollutants) is a matter of great importance. The main goal of this research was to investigate the pollution concentration in underground water and soil in two regions: Dasht-e-naz in Sari and the fields near Sarkhoun gas refinery. The second goal was to determine the source and measure the distribution of the pollutants (in case of presence) and determine potential risks caused by them. The first step was to perform experimental tests in the two regions. In Sari's Dasht-e-naz region, a number of wells were chosen for sampling according to the direction of underground water...