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    Preparation and Property Investigation of Propylene/Ethylene/ 1-Butene Co&terpolymers Modified by Nano Graphene Oxid

    , M.Sc. Thesis Sharif University of Technology Dehdab, Ali (Author) ; Ramazani Saadat, Ahmad (Supervisor)
    Abstract
    Propylene Copolymers and terpolymers with small amount of 1-butene& ethylene can greatly improve the properties of polypropylene material such as low temperature toughness, printing performance, transparency, process ability and so on, leading to expanding of its application. Poly(propylene-co-1-butene) performance intensely relies on its composition and chain structure. The copolymerization catalyzed by Ziegler-Natta catalyst, which is a multy-active central system. The Ziegler-Natta catalyst TiCl4/ Mg(OEt)2/ DIBP was used for copolymerization. The microstructure of copolymers were characterized by FTIR. The influence of different comonomer ratios on the copolymerization has been...