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Physical Modeling of Bioremediation of Gasoline Spill in the Vadose Zone
, M.Sc. Thesis Sharif University of Technology ; Sadeghi, Hamed (Supervisor) ; Moghimi, Hamid (Co-Supervisor)
Abstract
Oil pollutants are among the important sources of pollution in countries with oil and gas industries such as Iran. Soil pollution by these pollutants is one of the environmental issues and hazards. All kinds of organic and inorganic pollutants in the soil may penetrate the underground water or enter the atmosphere in the form of gas, which respectively enters the food chain through absorption by plants or enter the body of living organisms through breathing. They include humans, which are a threat to the health and life of living beings. For example, many of these pollutions cause diseases such as cancer, suppression of the body's immune system, or even obesity; therefore, it is necessary to...
Preparation of Herbal Biomass as Extractive Phases for Trace Determination of Pesticides
, Ph.D. Dissertation Sharif University of Technology ; Bagheri, Habib (Supervisor) ; Mahdavi, Vahideh (Supervisor)
Abstract
The main approach of this thesis is to study the performance and efficiency of agricultural biomass derived extractive phases in sample preparation methods. In this regard, different types of agricultural biomasses and various important factors in the production of biochar from biomass were studied by two physical and chemical methods. Accordingly, different types of biochars have been made and applied in different extraction setups along with ultra-high performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS) and gas chromatography-electron capture (GC-ECD) to detect agricultural pesticides. Also, validated developed methods were used to investigate the safety of some highly...
Reduction of Organic Dyes in Water Using MOFS and Their Composites
, M.Sc. Thesis Sharif University of Technology ; Kazemeini, Mohammad (Supervisor) ; Sadjadi, Samahe (Co-Supervisor) ; Khorasheh, Farhad (Co-Supervisor)
Abstract
A triple photocatalytic composite of biochar, metal-organic framework and phosphomolybdic acid was prepared through solvothermal treatment of iron (III) chloride hexahydrate, terephthalic acid, lavandulifolia-derived biochar and phosphomolybdic acid. The composite was thoroughly characterized and utilized for photodegradation of organic dyes under visible light irradiation. Investigations of reaction variables confirmed that, the highest yield of 96.2% for a cationic Rhodamine-B (RhB) dye was achieved at ambient temperature when using 0.07 g of catalyst at pH of 7 and a dye concentration of 10 ppm. The activity of the composite was superior compared to its individual components implying...