Sharif Digital Repository

In this project, a model which had been suggested for a lithium battery is used with the assumption of using C.N.T instead of activated carbon for the cathode. This battery include lithium foil, C.N.T and solution as anode, cathode and electrolyte. The electrolyte solution consist of lithium salt and a separator. The mathematical solving of the model consisted of using two CPM and DFM methods. In DFM method, a concentration gradient was considered as the driving force for diffusion and in the CPM method chemical potential as the driving force. Furthermore CPM method considered energy interaction between ions. Changing physical parameters of cathode and modification of model parameters... 

Microbial electrolysis cell is a novel technology for hydrogen production. The biggest challenges for this new technology are low rate of hydrogen production and high investment cost.
In this research, catholite condition was investigated for increasing the rate of hydrogen production. Low price stainless steel was used as cathode electrod. The microbial electrolysis cell operated applying 1.3 v external voltage. Basic pH was found to be the best condition for maximum rate of hydrogen production, where the average rate of hydrogen production was 100.006 1.866 L/m3.d. However, the hydrogen production rate for the acidic and neutral cathodic condition, were 92.89 1.13 and 91.845 1.485... 

In many previous Polymer Electrolyte Membrane Fuel Cell (PEMFC) models,the catalyst distribution in Catalyst Layer (CL) was assumed to be uniform and there are just a few models which consider variation of catalyst loading across the CL. In this research, a half-cell PEMFC cathode model is applied to investigate the effect of catalyst loading in CL plane under the land and channels of bipolar plates. In addition, the agglomerate model which has been shown to be more complete representation of the fuel cell CL is used. It is necessary to mention, in many previous PEMFC models, the catalyst layer was treated as a pseudohomogenous layer. In both models, the micro structure of CL and its effect... 

In this study, orthosilicate materials with chemical formula of Li2MSiO4 (M one or two transition metal/metals) were investigated experimentally and theoretically as cathode material of Li-ion batteries. The most important material in this category i.e. Li2FeSiO4 was synthesized by three methods including nitrate-based sol-gel, oxalate-based solid state reaction and oxide-based solid state reaction. Based on XRD and SEM evaluations, grain size of synthesized powders was estimated to be between 15 to 100 nanometers. Of these three methods, oxide-based solid state reaction was employed in this study for the first time. This syntheses method is very important due to the significant lower... 

Sodium-ion batteries are cost-effective rechargeable batteries which have attracted considerable interest in recent years due to the low cost and abundance of sodium resources on the earth. Na3MnCO3PO4 (NMCP) has been identified as a potential cathode material with a high theoretical capacity of 191 mAh g-1. In order to improve the conductivity and electrochemical properties of NMCP, fabrication of NMCP/reduced graphene oxide (rGO) composite is a novel and interesting research goal. Therefore, in the current study, rGO was produced by using modified Hummers method. Then, the kinetics of NMCP formation through hydrothermal process was investigated. Results indicate that the optimum... 

Solid oxide fuel cells as high temperature electrochemical devices draw much attention in the last decades due to their fuel flexibility, high efficiency and low pollution. However, lowering operating temperature from about 850°C to around 650°C without significant overpotential loss, in order to lower costs and increase cells life time has remained a challenge. Recently, a new family of mixed ionic and electronic conducting ceramics (MIECs) which are formulated Ln2NiO4+δ (Ln= La,Nd,Pr) and crystallized in Ruddlesden–Popper structure, have been regarded as appropriate cathode materials for the low or intermediate temperature solid oxide fuel cells (IT-SOFC). Amongst these compounds,... 

Nowadays, one of the most important research goals is to develop intermediate-temperature solid oxide fuel cells (IT-SOFC) operated at 500–800 °C. However, the large cathode polarization resistance caused by the reduced temperature is a major barrier against such an urgent demand for commercialization. In this regard, it is necessary to select a proper material as a cathode working efficiently at reduced temperatures without losing its desired performance. Various mixed ionic electron conductors (MIECs), especially Ruddlesden–Popper-type oxides, are used to improve the cathode performance at intermediate temperatures. Among these layered oxides, Pr2NiO4 has been reported to possess the... 

For improving cost competitiveness of both SOEC and SOFC technology, it is desirable to reduce the temperature of operation preferably down towards 500 oC – 600 oC, as this will slow down the rate of various degradation processes and allow use of much cheaper materials for auxiliary components. In this range, the oxygen electrode typically dominates the cell resistance, and hence there is a need to develop cost effective electrodes with improved performance at low temperature. Whereas the oxygen exchange on Ruddlesden-Popper type Ni based compounds like Pr2NiO4 with interstitial oxygen defects is known to be very fast, reported electrode performance of micron-sized composites based on these... 

This research is divided in three parts. In the first part of this research, we report the one-pot synthesis of carbonate-coated nanostructured LLO (Li2CO3@LLO) through a polyol-assisted method as a Li-ion battery cathode. Carbonate protects the cathode from adverse reactions with the electrolyte, also reduces the layered-to-spinel phase transition, thereby stabilizing the cathode structure. LLO nanostructure provides a fast Li+ diffusion. The target material exhibits excellent long-term stability with 77% capacity retention after 1000 cycles at 0.2C-rate. In the second part of research, Li(Na-doped)-Mn-Ni-O oxides were synthesized by different LiOH.H2O amount, type and amount of reducing...