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Fabrication and Characterization of Nickel-Cobalt Catalyst by One-pot Combustion Synthesis Method for Synthesis Gas Production in Dry Reforming Methane Process
, M.Sc. Thesis Sharif University of Technology ; Sadrnezhad, Khatiboleslam (Supervisor)
Abstract
Dry reforming methane is a process during which two greenhouse gases, CH4 and CO2, using Ni-based catalysts, are altered into valuable H2 and CO gases, which are very useful from an economic and environmental point of view. The main problem with Ni-based catalysts is the formation of carbon in the dry methane reforming, which leads to rapid deactivation of the catalyst. In this research, a 10Ni-5Co/Al2O3 bimetallic catalyst was prepared by one-pot microwave-assisted combustion synthesis with a stoichiometric amount of fuel (urea) and without the use of additives. The catalyst was then calcined for 12 h at 550oC. The structure, chemical composition, particle distribution, and morphology of...