Sharif Digital Repository

polyamides have found great attractions in wide variety of applications due to their desirable mechanical and tribological properties and appropriate processability. Pure polymers are not suitable for this kind of application due to their low mechanical strength. High strength materials are needed for abrasive applications. Polytetrafluoroethylene (PTFE) is one of the most popular materials for abrasive applications. In this study the effect of PTFE and surface modification on PA/PTFE composite properties is investigated. duo to modification of PTFE powder, PTFE is exposed to sodium naphtalenide (Na/naphtha) etchant so as to deflurinate the surface for obtaining carbonyl, carboxyl and... 

Pure NanoParticles of TiO2 and Nanocomposite catalysts of TiO2 , activated carbon (TiO2/AC) and multi-walled carbon nanotube (TiO2/MWCNT) were prepared by a sol –Gel method using TetraisoPropylorthotitanat (Tipt) as a precursor. The catalysts were characterized by x-ray diffraction (XRD), scanning electron microscopy (SEM), diffuse reflectance uv-vis spectroscopy (DRS) and N2 adsorption – desorption measurements. The photoactivity of samples was evaluated by Acid Blue 92 (AB 92) degradation. The analysis results show that compared with pure Nanoparticles of TiO2, the spherical – shaped TiO2 particles are well – dispersed in TiO2/AC. In TiO2/MWCNT, the coating has special mechanism that... 

Popular usage of composite materials in aerospace, civil and defense industries in the last decades has been caused more attention to optimization of composite problems. Due to natural complexity of composite problems, i.e. discrete nature, complex dependence between design variables, existence of too much local optimum and etc., traditional methods of optimization are inefficient and it is necessary to use a powerful method to work cost effectively. Genetic algorithm as a technique through evolutionary algorithms is the most popular methods of tackling composite problems. The success of a genetic algorithm can be quantified by estimating the cost, time required and the quality of final... 

In this study, hot extrusion of AA6061-%5 SiCp composite has been predicted and flow behavior of material during deformation process has been investigated. At the first step, hot compression tests have been carried out to obtain the flow behavior of the material at different temperatures and strain rates. In the next step, an FE-based temperature-displacement coupled model by employing ABAQUS software has been proposed in order to solve the energy and heat transfer equations and to determine the required energy and force for the extrusion process. Experimental investigations have also been performed to verify the proposed model. Comparison between the results from the model and the... 

In this research a copper- diamond nanocomposite coating prepared by electrodeposition from a sulfate bath in order to increase the hardness and erosion resistance of cooper without disturbing cooper's specific physical properties as like as electrical and thermal conductivity. The mechanism of electrodeposition was analyzed with the technique of Cyclic Voltammetry, Chronopotentiometry and Chronoamperometry. The morphology, hardness, scratch resistance, elastic modulus and friction factor of coating were investigated by using a scanning electron microscope (SEM) and atomic force microscope(AFM) also the mechanism of co- deposition of diamond particles with copper was corresponded with... 

At this study, nano structure sheet composite produced by1100 and 3004 strips using Accumulative role banding then mechanical and physical properties of the composites were investigated. After surface preparation, primary composite samples produced by putting different layers on each other and then rolling. The rolling was occurred in two steps; thickness reduction at first and second step were about 50% and 34%, respectively. ARB process were done till ninth cycle for Primary composite samples. To investigate mechanical properties of the samples, hardness, micro hardness and tensile strength tests have been done. Furthermore, micro structure of selective samples were studied by light... 

Adding solid lubricant particles such as PTFE, Graphite and MoS2, has major influence on electroless composite nickel coatings in order to make low friction surfaces. Among these lubricants, MoS2 has attracted great attention due to its highest stability under wearing condition. In this work Ni-P-MoS2 composite coatings using MoS2 nano-particles have been made and in the next step, we evaluated tribological properties of these coatings. For exploring these coatings different experiments were utilized, like Scanning Electron Microscope study (SEM), chemical composition analysis exploiting AAS and XRF method, and thickness measurements. Two kinds of surfactants, CTAB and PVP, have been applied... 

Metallic multilayer composites provide remarkable mechanical, electrical and magnetic properties. These kinds of composites are recently processed by severe plastic deformation methods. Accumulative roll bonding (ARB) is one of the SPD processes in which accumulation of strain by repeating cycles, leads to the ultra fine grains structures. The goal of this research is manufacturing of Al/AZ31 composite and investigating the relation between the rolling process parameters and the mechanical and physical properties of the final sheet. The initial composite was carried out by cladding of 1mm thick AZ31 sheet in between two commercially pure aluminum sheets with the same thickness (57%... 

Polyamides have found great attraction in the wide variety of application due to their desireable and tribological properties and appropriate processability. Due to their low mechanical strength reinforcing of these types of polymers has always been one of the important academic and industrial issues. In order to improve mechanical properties of such polymers, different kinds of reinforcement particles such as titaniom diaoxide, Nano clay, glass fibers (Short or long glass fiber), etc were used. Carbon nano tubes have high thermal and electrical conduction and mechanical properties; they are widely used as a reinforcement particle for polymer matrix. In this study, carbon nano tube and... 

Composites are made to obtain several mechanical and physical properties selectively. But joining and manufacturing of complex shapes restricts their usages. Transient liquid phase (TLP) bonding is a novel method for joining of these materials without any defects that occur in other welding methods, such as melting or solid state methods. In this research, temperture gradiant TLP bonding of AA6061/SiC/15p using gallium as interlayer was performed. To obtain the optimum conditions, joining was performed at 260, 310, 360 and 410 ˚C, and pressure of 5 and 10 Mpa with holding time of 5 and 10 minutes, the joined samples then solutionized at 530˚C for 70 minutes. Optical and scanning electron... 

In this thesis, we aim to study the elastic-plastic behavior of short fiber reinforced composites experimentally and analytically. The experimental investigation is applied to glass fiber-polypropylene composites (PP/GF). The samples are produced by injection process with maximum temperature of 190C. Fibers are randomly oriented in this procedure of fabrication. The samples are tested in tension, and the mechanical strength is measured by changes in fiber content. The Young's modulus is also investigated in these experiments.Also in this thesis, an analytical model for calculation of Young’s modulus of fiber reinforced composite materials is proposed. In this analysis a displacement field is... 

In this study nanostructured composite from Al1050 and Al2024 were manufactured via accumulative roll bonding (ARB). Process was conducted in two different ways. In one approach the Al2024 sheets were annealed and in the other they were solution treated (ST). The sheets were degreased by acetone and wire-brushed, and then one Al2024 was placed between two sheets of Al1050, so three pieces of sheets were stacked to be 3 mm in thickness. The stacked sheets were rollbonded to produce the primary composite sandwich with thickness of 1 mm. Then, this sandwich was cut in the half and the two halves were degreased and wire-brushed and stacked to be 2 mm in thickness. Roll-bonding was conducted... 

The feasibility to fabricate Al/SiCp nano-composite with functionally graded structure (FG-Al/SiCp) via friction stir processing was studied successfully in this paper. The distribution of well-dispersed nano-SiCp got a range of 6mm×3mm on the cross-section of nano-composite. A compositionally graded structure of nano-SiCp in thickness direction of the 5083Al plate was obtained via four passes of FSP. The percentage of nano-SiCp over 15%, 9% and 5% was found at the depth of 1.0mm, 2.0mm and 3.0mm, under processed surface of 5083Al rolled plate, respectively. Results show that the microhardness of FG-Al/SiCp nano-composite can reach steady 46%, 34% and 15% higher than the one of the base... 

Taghizadeh Manzari, M. (MehrdadThe main goals of this project are studding the effect of carbon nanotube on the properties of PA6/PA66 matrix and miscibility of PA6/PA66 blend. So PA6/PA66/CNT nanocomposites were compounded by melt mixing method and samples were prepared by injection molding. Due to study miscibility of PA6 and PA66, we used DMTA test and found that PA6 and PA66 are miscible because of existing one pick on DMTA graph. Also DSC test results confirmed that PA6 and PA66 are miscible. Moreover, according to DMTA results, modulus will be rose by increasing CNT content. Mechanical test showed same results in this case. Adding 1%CNT to matrix caused 10% improvement in modulus and... 

This research focused on mechanical properties of Al-TiB2 composite in as cast, heat treated and extruded condition. The composites were produced by mixing Al-Ti and Al-B master alloyes. Since some engineering parts during service are supposed to tolerate severe wear conditions, in this research abrasive wear condition was wxamined using pin on disk method. In a fixed load and abrasive disk, composites showed better resistance against wear in comparison with matrix alloy. Furtheremore, T6 heat treatment made composites more resistant against abrasive wear. Finally the best wear resistance was accompolished when composite was extruded and then heat treated. While increase in reinforcement... 

In the research transient liquid phase bonding of AL6061-SiC composite was performed using copper as interlayer. The joining praocess was performed in various tetemperatures (560c and 580c and 600c) And times (6 and 8 hours). Optimum Joining condition was determined by using optical and of the joint, micro hardness test was performed from the bonding zone to the bulk of the base composite. The fatigue endurance limit of Al6061-SiC composite was determined by several fatigue tests and TLP bonded samples were loaded under achieved endurance limit stress. Finally fatigue fracture surface of both base composite and TLP bonded samples were studied by using of scanning electronic microscope  

In this research we focus on study and fabrication of ZnO composite nanofibers by electrospinning method for photocatalytic application. The most important challenges in the field of photocatalyst are photocatalytic activity under the visible light and efficiency enhancement. ZnO is a wide band gap semiconductor and it is not active under the visible light. In Iran, we have more than 300 sunny days in a year. Therefore fabrication and application of photocatalytic material with activity under the sun light that contained 40% of visible light is so vital in our country. In the first part of this project, ZnO-CNT nanofibers were fabricated and carbon doped in the crystal lattice of the ZnO.... 

In this work, the glassy carbon electrode (GCE) was modified with a thin layer of multi-walled carbon nanotubes (MWCNTs) and consequently, electrochemically deposited poly-pyrrole. The electrochemical behavior of mesalazine was studied on the surface of the modified electrode by applying linear sweep voltammetry (LSV). The electro-polymerization process and the electrochemical response toward mesalazine were investigated in the presence of different aromatic anion dopants including, benzenesulfonic acid (BSA), 1,3-benzenedisulfonic acid (1,3-BDSA), 1,5-naphthalenedisulfonic acid (1,5-NDSA) and new coccine (NC). By using 1,5-NDSA as dopant, a significant increase (∼418 times) was observed in... 

In this thesis, Fe3O4 magnetic nanoparticles were produced using co-precipitation method. The surface of these magnetic nanoparticles is modified by ionic-liquid groups, and then coated with Cu, Au and Ag metals. These nanoparticles were unstable before their surface modification, so that they were easily agglomerated. However, after their surface is modified with ionic-liquid, they become very stable and are easily solved in polar and non-polar solvents. This solubility depends on the alkyls groups connected to the ionic-liquid. Magnetic nano composites Fe3O4/X (X=Ag, Cu, Au) modified by ionic-liquid are prepared by absorbing Cu(NO3)2, HAuClO4 and AgNO3 salts on the surface of modified... 

In the first part, preparation of different kinds of polypyrrole/carbon composites and their application for drug analysis are described. In the first work, A very sensitive electrochemical sensor constructed from a glassy carbon electrode modified with a layer-by-layer MWCNT/doped overoxidized polypyrrole (oppy/MWCNT /GCE) was used for the determination of acetaminophen (AC) in the presence of codeine and ascorbic acid (AA). In comparison to the bare glassy carbon electrode, a considerable shift in the peak potential together with an increase in the peak current was observed for AC on the surface of oppy/MWCNT/GCE, which can be related to the enlarged microscopic surface area of the...